Structural and electrical properties of La(Sr,Ca)MnO3 ceramics for NTC thermistors
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La0.7(Sr0.3-xCax)MnO3 (0.1≤x≤0.25) ceramics were prepared using solid-state sintering. XRD measurements showed that allspecimens showed rhombohedral polycrystalline structures. As the amount of Ca increased from 0.1 mol to 0.25 mol, sintereddensities decreased from 5.8888 g/cm3 to 5.5829 g/cm3. All specimens exhibited excellent NTCR properties of approximately0.445-0.421 %/oC. The TCR property, B25/65 constant, and resistivity at room temperature of the LSMO specimen doped with0.2 mol Ca were 0.439 %/oC, 469 K, and 3.94 104 Ω-cm, respectively.
Abstract
La0.7(Sr0.3-xCax)MnO3 (0.1≤x≤0.25) ceramics were prepared using solid-state sintering. XRD measurements showed that allspecimens showed rhombohedral polycrystalline structures. As the amount of Ca increased from 0.1 mol to 0.25 mol, sintereddensities decreased from 5.8888 g/cm3 to 5.5829 g/cm3. All specimens exhibited excellent NTCR properties of approximately0.445-0.421 %/oC. The TCR property, B25/65 constant, and resistivity at room temperature of the LSMO specimen doped with0.2 mol Ca were 0.439 %/oC, 469 K, and 3.94 104 Ω-cm, respectively.
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