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Crystallinity of silicon/carbon composite materials for rechargeable battery

Jinsuk Lee|Yujeong Ahn|Sihyun Lee
청정에너지연구소 (Clean-Energy Research Institute)|2023.12|Journal of Ceramic Processing Research|제24권 제6호|pp. 1010-1024|DOI 10.36410/jcpr.2023.24.6.1010

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CrystallinityGraphiteSiliconCarbonRechargeable battery
주제분류재료공학

초록

The silicon battery’s uncontrollable volume change during the lithiation process leads to a severely decreased battery life. Despite such a critical drawback of the material, the unparalleled capacity potential of silicon (Si) batteries is what makesit the next generation’s most anticipated battery anode material. The first part of determining the capacity of a Si anodeis the Si core itself. Our research indicated that the higher the purity of Si results in a naturally higher crystallinity status. When the purity of the sample was identical, monocrystalline Si proved to have higher crystallinity than polycrystalline andamorphous. The second part that determines the capacity is the graphite used in the composite. Natural Graphite (NG) havehigher crystallinity values than Artificial Graphite (AG) and show more resistant properties to the crystallinity breakingdown by milling time, which inspected by particle size analyzer, optical transmission and microscope. We reached a millingmethod of getting small particle sizes yet high crystallinity and graphene presence, which expect to improve the robustnessof anode materials and electrochemical performances. The third part that determines coated carbon layers accommodate thevolume change and prevents the quick loss of capacity, indicating higher crystallinity. Finally, the composites prepared withthis method showed that higher X-ray Diffraction (XRD) and Raman Spectroscopy peaks than commercial references. Weconcluded how high crystallinity used in silicon carbon composite materials show high capacity potential with integrity inrechargeable battery.

Abstract

The silicon battery’s uncontrollable volume change during the lithiation process leads to a severely decreased battery life. Despite such a critical drawback of the material, the unparalleled capacity potential of silicon (Si) batteries is what makesit the next generation’s most anticipated battery anode material. The first part of determining the capacity of a Si anodeis the Si core itself. Our research indicated that the higher the purity of Si results in a naturally higher crystallinity status. When the purity of the sample was identical, monocrystalline Si proved to have higher crystallinity than polycrystalline andamorphous. The second part that determines the capacity is the graphite used in the composite. Natural Graphite (NG) havehigher crystallinity values than Artificial Graphite (AG) and show more resistant properties to the crystallinity breakingdown by milling time, which inspected by particle size analyzer, optical transmission and microscope. We reached a millingmethod of getting small particle sizes yet high crystallinity and graphene presence, which expect to improve the robustnessof anode materials and electrochemical performances. The third part that determines coated carbon layers accommodate thevolume change and prevents the quick loss of capacity, indicating higher crystallinity. Finally, the composites prepared withthis method showed that higher X-ray Diffraction (XRD) and Raman Spectroscopy peaks than commercial references. Weconcluded how high crystallinity used in silicon carbon composite materials show high capacity potential with integrity inrechargeable battery.

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