二次電池 製造工程스크랩으로부터 高效率 親環境 코발트(Co)와 리튬(Li)의 回收에 關한 硏究
A Study on the Cobalt and Lithium Recovery from the Production Scraps of Lithium Secondary Battery by High Efficient and Eco-friendly Method
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리튬이차전지 양극스크랩으로부터 코발트와 리튬을 회수하기위해 물리적 전처리, 침출, 용매추출 및 회수실험을 행하였다. 실험재료로 제조공정에서 발생되는 코발트계 양극스크랩을 사용하여 단위공정별 최적조건을 구하였다. 물리적전처리 최적조건은 온도 500~550oC, 파쇄날 회전속도 1000 rpm이었으며, 침출 최적조건은 300 rpm, 2M H2SO4, 2.5M H2O2, 95oC이었다. D2EHPA(bis(2-ethylhexyl) phosphoric acid) 와 PC88A를 각각 알루미늄과 코발트의 추출제로 사용하여 분리•정제하였으며, 코발트는 염기성시약을 사용하여 Co(OH)2로, 리튬은 탄산나트륨 및 LiOH를 사용하여 탄산리튬(LiCO3)으로 회수하였다. Co(OH)2는 열처리를 하여 삼산화코발트(Co3O4)로 만들고 분쇄기를 사용하여 10 mm정도의 입자를 만들었다. 최적조건에서 코발트와 리튬 회수율은 99%이상, 리튬회수율은 99%이상이었으며, 삼산화코발트의 순도는 99.98%이상이었다
Abstract
A study on the recovery of cobalt and lithium from Lithium Ion Battery(LIB) scraps has been carried out by a physical treatment - leaching - solvent extraction process. The cathode scraps of LIB in production were used as a material of this experiment. The best condition for recovering cobalt from the anode scraps was acquired in each process. The cathode scraps are dissolved in 2M sulfuric acid solution with hydrogen peroxide at 95oC, 700 rpm. The cobalt is cencentrated from the leaching solution by means of a solvent extraction circuit with bis(2-ethylhexyl) phosphoric acid(D2EHPA) and PC88A in kerosene, and then cobalt and lithium are recovered as cobalt hydroxide and lithium carbonate by precipitation technology. The purity of cobalt oxide powder was over 99.98% and the average particle size after milling was about 10 mm. The over all recoveries are over 95% for cobalt and lithium. The pilot test of mechanical separation was carried out for the recovery of cobalt from the scraps. The Co3O4 powder was made by the heat treatment of Co(OH)2 and the average particle size was about 10 mm after grinding. The recovery was over 99% for cobalt and lithium each other and the purity of cobalt oxide was over 99.98%.
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