암모니아 浸出工程 技術開發 動向
Development of Ammoniacal Leaching Processes; A Review
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초록
암모니아 습식제련공정은 철과 칼슘의 용해를 억제하며 구리 등의 금속을 선택적으로 침출이 가능한 장점이 있어 구리, 금, 니켈및 코발트 등의 금속을 선택적으로 침출하기 위한 연구가 수행되어왔다. 이 글에서는 모터스크랩과 폐인쇄회로기판으로부터 구리의선택적 침출, 티오황산염 사용 등 시안의 대체 및 저감을 위한 금의 암모니아침출, 산화니켈광 및 망간단괴처리공정 중간산물로부터 니켈과 코발트를 회수하기 위한 암모니아침출 기술개발동향을 정리하고 국내 연구개발방향을 제시하고자 하였다.
Abstract
Selective leaching processes for copper, gold, nickel, and cobalt have been investigated because there is an advantage of ammoniacal hydrometallurgy that metal such as copper could be selectively extracted restricting the dissolution of iron or calcium. In the present article, the studies for selective ammoniacal leaching of copper from motor scraps and waste printed circuit boards (PCBs), for ammoniacal leaching of gold to decrease the amount of cyanide used or to substitute cyanide by thiosulfate,and for ammoniacal leaching to recover nickel and cobalt from nickel oxide ore and intermidiate obtained from manganese nodule treatment process were summarized and further studies were proposed for domestic technology development for ammoniacal hydrometallurgy processes.
참고문헌 (69)
- Peacy, J., "Copper Hydrometallurgy Current Status, Preliminary Economics, Future Direction and Positionin verus Smelting", Transactions of Nonferrous Metals Society of China, 14(3), pp.560~568 (2004)
- Meng, X., "The Principles and Applications of Ammonia Leaching of Metals A Review", Mineral Processing and Extractive Metallurgy Review, 16, pp.23~61 (1996)
- 김수경, "環境部『廢金屬資源 再活用 對策』의主要 內容", 자원리싸이클링, 19(4), pp.3~12 (2010), 한국자원리싸이클링학회
- Kim, E.-y., "Effect of cuprous ions on Cu leaching in the recycling of waste PCBs, using electro-generated chlorine in hydrochloric acid solution", MINERALS ENGINEERING, 21, pp.121~128, PERGAMON-ELSEVIER SCIENCE LTD
- Long Hoang Le, "핸드폰 基板으로부터 구리와 은의 窒酸 浸出 硏究", 자원리싸이클링, 17(3), pp.48~55 (2008), 한국자원리싸이클링학회
- Lee, J. -c., "Development of Commercial Technology for Recovering Precious Metals", pp.2003, MOST
- Lee, J. -c., "Development of Recycling Technique for Waste Electric anc Eletronic Equipments", pp.2010, MOST(Ministry of Science and Technology)
- 김종화, "습식제련공정에 의한 석유화학 폐촉매로부터 니켈의 회수", 韓國油化學會誌, 27(3), pp.273~281 (2010), 한국유화학회
- 김지혜, "WC-Co 超硬合金 슬러지로부터 王水處理를 이용한 텅스텐의 回收", 자원리싸이클링, 19(4), pp.41~50 (2010), 한국자원리싸이클링학회
- 박경호, "암모니아 溶液中에서 바나듐의 溶解와 沈澱擧動", 자원리싸이클링, 17(1), pp.38~42 (2008), 한국자원리싸이클링학회
- 박경호, "오리멀젼灰로부터 製造된 中間 生成物로부터 바나듐과 니켈의 選擇的 浸出", 자원리싸이클링, 15(6), pp.10~15 (2006), 한국자원리싸이클링학회
- Kim, J.-H., "Recovery of Valuable Metals from the Desulfurizing Spent Catalyst Used in Domestic Petrochemical Industry", J. of Korean Inst. of Resources Recycling, 4(3), pp.2~9 (1995)
- Kim, D. S., "Aqueous Oxidation of Sulfide Ore (Part 1) Aqueous Oxidation of Marmatite in Ammonia Solution", Journal of the Korean Chemical Society, 10(2), pp.54~58 (1966)
- Lee, U. J., "A Study on the Development of Hydrometallurgical Processes of Electric Arc Furnace Dust" (1998), Ministry of Science and Technology
- Lee, D. H., "Extraction of Nickel from Indonesian Low Grade Laterites: Electrochemical Leaching & Purification of Leach Liquors" (1985), Ministry of Science and Technology
- Kim, H. J., "New Dictionary of Chemistry", pp.715~ (1983), Bub-kyung
- Luo, R., "Overall Equilibrium Diagrams for Hydrometallurgical Systems: Copper -Ammonia -Water System", Hydrometallurgy, 17, pp.177~199 (1987)
- Bard, A. J., "Standard Potentials in Aqueous Solution", pp.250~340 (1985), Marcel Dekker, Inc
- Pourbaix, M., "Atlas of Electrochemical Equilibria in Aqueous Solutions", pp.323~ (1974), National Association of Corrosion Engineers
- Koyama, K., "Copper Leaching Behavior from Waste Printed Circuit Board in Ammoniacal Alkaline Solution", Materials Transactions, 47(7), pp.1788~1792 (2006)
- Koyama, K., "Electrolytic Copper Deposition from AmmoniacalAlkaline Solution Containing Cu(I)", MaterialsTransactions, 47(8), pp.2076~2080 (2006)
- Majima, H., "Dissolution of Copper with Aqueous Cupric Ammine Solution Studies on the Selective Recovery of Copper and Iron from Motor Scrap (1st Report)", MMIJ, 109(3), pp.191~194 (1993)
- Zhou, K., "Dissolution Rate of Copper in Aqueous Ammonia Solution Removal of Copper from Ferrous Scrap with Ammonia Leaching Method (1st Report)", MMIJ, 111(1), pp.49~53 (1995)
- Zhou, K., "Removal of Copper from Automobile Scrap Removal of Copper from Ferrous Scrap with Ammonia Leaching Method (2nd Report)", MMIJ, 111(1), pp.55~58 (1995)
- Zhou, K., "Measurment of Copper Dissolution Rates in Aqueous Ammonia Solutions with Oxygen Circulating Ammonia Leaching Method", Metallurgical Review of MMIJ, 13(1), pp.62~75 (1996)
- Zhou, K., "Copper Removal from Junk Automobile Scraps with Oxygen Circulating Ammonia Leaching Method", Metallurgical Review of MMIJ, 13(1), pp.76~85 (1996)
- Oishi, T., "Recovery of High Purity Copper Cathode from Printed Circuit Boards Using Ammoniacal Sulfate or Chloride Solutions", Hydrometallurgy, 89, pp.82~88 (2007)
- Sedzimir, J., "Kinetics of Leaching of Copper Metal in Copper(II)-Ammonium Sulphate Solutions as Determined by the Rotating Disc Method", Hydrometallurgy, 3, pp.233~248 (1978)
- Mironov, V. E., "Thermodynamics of Formation Reactions and Hydrometallurgical Application of Metal - Ammonia Complexes in Aqueous Solutions", Russian Chemical Reviews, 61(9), pp.944~958 (1992)
- Nigo, S., "Recovery of Copper from Motor Scrap Utilizing Ammonia Leaching Technique Studies on the Selective Recovery of Copper and Iron from Motor Scrap (2nd Report)", MMIJ, 109(5), pp.337~340 (1993)
- Oishi, T., "Influence of Ammonium Salt on Electrowinning of Copper from Ammoniacal Alkaline Solutions", Electrochimica Acta, 53, pp.127~132 (2007)
- Oishi, T., "Hydrometallurgy Process for the Recycling of Copper Using Anodic Oxidation of Cuprous Ammine Complexes and Flow-Through Electrolysis", Electrochimica Acta, 53, pp.2585~2592 (2008)
- Oishi, T., "Effect of Phosphate on Lead Removal during a Copper Recycling Process from Waste Using Ammoniacal Chloride Solution", Hydrometallurgy, 90, pp.161~167 (2008)
- Bari, F., "Selective Leaching for the Recovery of Copper fromPCB", Proceedings of the Malaysian MetallurgicalConference ‘09 (MMC09), pp.1~4 (2009)
- Chang, C.-J., "Feasibility of Copper Leaching from an Industrial Sludge Using Ammonia Solutions", Journal of Hazardous Materials, 58, pp.121~132 (1998)
- Aylmore, M. G., "Alternative Lixiviants to Cyanide for Leaching Gold Ores, In Advances in Gold Ore Processing", pp.501~560 (2005), Elsevier B. V.
- Marsden, J. O., "The Chemistry of Gold Extraction", pp.233~295 (2006), Society for Mining, Metallurgy, and Exploration, Inc.
- Aylmore, M. G., "Thiosulfate Leaching of Gold A Review", Minerals Engineering, 14(2), pp.135~174 (2001)
- Jeffrey, M. I., "Kinetic Aspects of Gold and Silver Leaching in Ammonia-Thiosulfate Solutions", Hydro metallurgy, 60, pp.7~16 (2001)
- Breuer, P. L., "An Electrochemical Study of Gold Leaching in Thiosulfate Solutions Containing Copper and Ammonia", Hydrometallurgy, 65, pp.145~157 (2002)
- Breuer, P. L., "Thiosulfate Leaching Kinetics of Gold in the Presence of Copper and Ammonia", Minerals Engineering, 13(10), pp.1071~1081 (2000)
- Senanayake, G., "Part I: A Review of the Effect of Hard-Soft and Lewis Acid-Base Properties and Interactions of Ions", Hydrometallurgy, 115, pp.1~20 (2012)
- Senanayake, G., "Gold Leaching by Copper (II) in Ammoniacal Thiosulphate Solutions in the Presence of Additives. Part II: Effect of Residual Cu (II), pH and Redox Potentials on Reactivity of Colloidal Gold", Hydrometallurgy, 115, pp.21~19 (2012)
- Feng, D., "Ammoniacal Thiosulphate Leaching of Gold in the Presence of Pyrite", Hydrometallurgy, pp.126~132 (2006)
- Feng, D., "Effect of Thiosulphate Salts on Ammoniacal Thiosulphate Leaching of Gold", Hydrometallurgy, pp.120~126 (2010)
- Alonso-Gomez, A. R., "Inhibition of Lead Solubilization during the Leaching of Gold and Silver in Ammoniacal Thiosulfate Solutions (Effect of Phosphate Addition)", Hydrometallurgy, 99, pp.89~96 (2009)
- Arima, H., "Using Nickel as a Catalyst in Ammonium Thiosulfate Leaching for Gold Extraction", Materials Transactions, 45(2), pp.516~526 (2004)
- Zipperian, D., "Gold and Silver Extraction by Ammoniacal Thiosulfate Leaching from a Rhyolite Ore", Hydrometallurgy, 19, pp.361~375 (1988)
- Zheng, J., "Study of Gold Leaching in Oxygenated SolutionsContaining Cyanide-Copper-Ammonia Using a RotatingQuartz Crystal Microbalance", Hydrometallurgy, 39, pp.277~292 (1995)
- Jeffrey, M. I., "A kinetic and Electrochemical Study of theAmmonia Cyanide Process for Leaching Gold in SolutionsContaining Copper", Minerals Engineering, 15, pp.1173~1180 (2002)
- Muir, D. M., "A Review of the Selective Leaching of Gold frome Oxidised Copper-Gold Ores with Ammonia- Cyanide and New Insights for Plant Control and Operation", Minerals Engineering, 24, pp.576~582 (2011)
- Meng, X., "The Dissolution Behavior of Gold in Ammoniacal Solutions, In HydrometallurgyFundamentals, Technology and Innovation", pp.205~221 (1993), SME Littleton, Co
- Dasgupta, R., "The Electrochemical Behavior of Gold in Ammoniacal Solutions at 75°C", Metallurgical and Materials Transactions B, 28, pp.5~12 (1997)
- 한국남, "Factors influencing the rate of dissolution of gold in ammoniacal solutions", INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 58(1-4), pp.369~381, ELSEVIER SCIENCE BV
- Peri, K., "Dissolution Behavior of Gold in Ammoniacal Solutions with Iodine as an Oxidant", Minerals & Metallurgical Processing, 18(1), pp.13~17 (2001)
- Bhuntumkomol, K., "The Leaching Behavior of Nickel Oxides in Acid and in Ammoniacal Solutions", Hydrometallurgy, 8, pp.147~160 (1982)
- Nikoloski, A. N., "The Electrochemistry of the Leaching Reactions in the Caron Process II. Cathodic Processes", Hydrometallurgy, 105, pp.54~59 (2010)
- Senanayake, G., "Effect of Thiosulfate, Sulfide, Copper(II), Cobalt(II)", (III) and Iron Oxides on the Ammonical Carbonate Leaching of Nickel and Ferronickel in the Caron Process, 2010, pp.105, 60~68
- Jandova, J., "Leaching Behaviour of Iron-Nickel Alloys in Ammoniacal Solution", Hydrometallurgy, 35, pp.123~128 (1994)
- Chander, S., "Reduction Roasting", Ammonia Leaching of Nickeliferous Laterites, 1981, pp.7, 315~327
- Han, K. N., "The Leaching Kinetics of Cobalt and Nickel form Aluminum- Coprecipitated Products", Metallurgical Transactions B, 18, pp.635~640 (1987)
- Katsiapi, A., "Agatzini- Leonardou, S., 2010: Cobalt Recovery from Mixed Co-Mn Hydroxide Precipitates by Ammonia-Ammonium Carbonate Leaching", Minerals Engineering, 23, pp.643~651 (2010)
- Yoo, K., "Mineral Processing Technologies for Deep-Seabed Resources", J. KSGE, 48(6), pp.821~828 (2011)
- Park, K.-H., "A Study on the Oxidative Ammonia", AmmoniumSulphate Leaching of a Complex (Cu-Ni-Co-Fe) Matte, 2007, pp.86, 164~171
- Niinae, M., "Preferential Leaching of Cobalt, Nickel and Copper from Cobalt-Rich Ferromanganese Crusts with Ammoniacal Solutions Using Ammonium Thiosulfate and Ammonium Sulfite as Reducing Agents", 40, pp.111~121 (1996)
- Jana, R. K., "Ammoniacal Leaching of Roast Reduced Deep-sea Manganese Nodules", Hydrometallurgy, 53, pp.45~56 (1999)
- Mishra, D., "Leaching of Roast-reduced Manganese Nodules in NH3-(NH4)2CO3 Medium", Hydrometallurgy, 109, pp.215~220 (2011)
- Demidov, A. I., "Kinetics of Leaching of Nickel Compounds from Spent Electrodes of Nickel-Iron Batteries in Ammonia Solutions", Russian Journal of Applied Chemistry, 74(5), pp.737~741 (2001)
- Salhi, R., "Recovery of Nickel and Copper from Metal Finishing Hydroxide Sludges by Ammoniacal Leaching", Mineral Processing and Extractive Metallurgy, 119(3), pp.147~152 (2010)
