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2次 資源으로부터 濕式方法에 의한 인듐의 回收

Recovery of Indium from Secondary Resources by Hydrometallurgical Method

이만승|왕릉운
한국자원리싸이클링학회|2013.04|자원리싸이클링 (Resources Recycling)|제22권 제2호|pp. 3-10|DOI http://dx.doi.org/10.7844/kirr.2013.22.2.3

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키워드

Recovery회수Solvent extractionIndium용매추출이온교환Ion exchange2차 자원인듐Secondary resources
주제분류자원공학

초록

인듐은 희유금속으로 주로 ITO제조에 사용된다. 본 총설에서는 인듐을 함유한 2차자원을 침출한 용액으로부터 인듐을 분리하기위한 용매추출, 이온교환 및 석출법에 대한 공정 조건 및 장단점을 조사했다. 보통 정도의 산성용액에서 인듐의 추출제로 D2EHPA 가 가장 많이 사용되고 있으며, 매우 강한 염산용액에서는 아민계 추출제가 사용된다. 일반적으로 이온교환수지의 인듐 흡착량이 낮으므로, 인듐의 농도가 낮은 경우에 한해 이온교환은 용매추출보다 장점이 있다.

Abstract

Indium is one of the rare metals, and it has been used mainly for preparation of indium tin oxide (ITO). This review investigated the process parameters and the merits and demerits of several methods to recover indium from the leaching solution of secondary resources, such as solvent extraction, ion exchange, and precipitation. D2EHPA has been used mostly as a cationic extractant for indium extraction in moderate acid solutions, while amine extractants are used in strong hydrochloric acid solution. Since the loading capacity of resins for indium is generally small, ion exchange has some advantage over solvent extraction only when the concentration of indium is low.

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