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정전분무 장치를 이용한 C축 일방향 바륨페라이트(BaFe12O19)박막형성

Preparation of C-plane oriented BaFe12O19 film by electrospray deposition of colloidal precursor particles

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초록

New process consisting of electrospray and epitaxial crystal growth processes was applied to the preparation of c-plane oriented barium ferrite (BaFe12O19) thin film for high density magnetic recording media. Sodium citrate aided process was proper to preparation of amorphous BaFe12O19 nanoparticles with geometric mean diameter of 3 nm and geometric standard deviation of 1.1. The electrospray was applicable to the prepare of amorphous BaFe12O19 thin film on a substrate, and the film thickness could be controlled by adjusting the electrospray deposition time. The c-plane oriented BaFe12O19 thin film was successfully prepared by 3 step annealing process of the BaFe12O19 amorphous film on a sapphire(Al2O3) substrate; annealing at 350℃ for 30 min, annealing at 500℃ for 30 min, and annealing at 700℃for 60 min.

Abstract

New process consisting of electrospray and epitaxial crystal growth processes was applied to the preparation of c-plane oriented barium ferrite (BaFe12O19) thin film for high density magnetic recording media. Sodium citrate aided process was proper to preparation of amorphous BaFe12O19 nanoparticles with geometric mean diameter of 3 nm and geometric standard deviation of 1.1. The electrospray was applicable to the prepare of amorphous BaFe12O19 thin film on a substrate, and the film thickness could be controlled by adjusting the electrospray deposition time. The c-plane oriented BaFe12O19 thin film was successfully prepared by 3 step annealing process of the BaFe12O19 amorphous film on a sapphire(Al2O3) substrate; annealing at 350℃ for 30 min, annealing at 500℃ for 30 min, and annealing at 700℃for 60 min.

참고문헌 (9)

  1. Fu, L., "Nanopatterning of"hard"magnetic nanostructures via dip-pen nanolithography and sol-based ink", Nanoletters, 3(6), pp.757~760 (2003)
  2. Hylton, T. L., "Properties of epitaxial Ba-hexaferrite thin films sapphire substrates", Journal of Applied Physics, 73(10), pp.6257~6259 (1993)
  3. Kim, S. -G., "Crystallization of barium ferrite nanoparticles by a sodium citrate-aided synthetic process", The Journal of Physics and Chemicstry C, 111(28), pp.10175~10180 (2007)
  4. Lee, H. M., "of unsintered spherical BaFe12O19 nanoparticles via an alcohol-assisted spray-pyrolysis route", Journal of The American Ceramic Society, 91(9), pp.2856~2861 (2008)
  5. Lee, H. M., "Monolayer deposition of L10 FePt nanoparticles via electrospray route", Journal of Magnetism and Magnetic Materials, 313(1), pp.62~68 (2007)
  6. Lenggoro, I. W., "Nanoparticles assembly in patterned"plus", minus"surface from electrospray of colloidal dis persion, 2006, pp.303(1), 124~130
  7. Liu, X. H., "Barium ferrite(BaFe12O19)thin films prepared by pulsed laser deposition on MgO buffered Si substrates", Applied Physics A, 80(3), pp.611~614 (2005)
  8. Rafique, M. S., "Effect of external magnetic field on the deposition of BaFe12O19", Vacuum, 82, pp.1233~1237 (2008)
  9. Yu, H.-F, "Preparation and thermal behavior of aerosol derived BaFe12O19 nanoparticles", Journal of Magnetism and Magnetic Materials, 283(1-2), pp.190~198 (2004)

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