본문 바로가기
KERD
논문KCI 등재

유연 염료감응 태양전지 소재 및 요소기술 동향

Materials and Compartments for Flexible Dye Sensitized Solar Cell

박병욱|이재준|정인수
한국전기화학회 (The Korean Electrochemical Society)|2015.05|전기화학회지 (Journal of the Korean Electrochemical Society)|제18권 제2호|pp. 86-94

0

조회

0

다운로드

0

인용

0

참고문헌

키워드

FlexibleDye sensitized solar celllow temperature fabrication techniquesTCO free counter electrodetake placing the liquid electrolyte
주제분류화학

초록

전세계적으로 화석에너지의 고갈로 인한 환경문제의 도래와 에너지 부족문제를 해결하기 위하여, 다양한 각도에서 태양전지의 개발이 추진되고 있다. 그 중에서도 유연염료감응태양전지의 개발은그 활용도가 높고, 낮은 생산단가로 인하여 그 상용화에 더욱 가까운 연구 테마라고 하겠다. 여기서는 유연태양전지 분야의 연구 동향 및 최신 기술 및 재료들을 소개함으로써 앞으로의 연구방향을 제시하고자 한다.

Abstract

In order to solve incoming environmental crisis and an energy crunch caused by the consumption of fossil fuels, lots of investigations and developments for solar cell application are getting a spotlight in various aspects. Amongst many solar cells, a flexible dye sensitized solar cell is an attractive research field from fundamentals to commercialization. In this manuscript, we introduce materials and available techniques for the future scientific research and technical developments in commercialization.

참고문헌 (69)

  1. G. Smestad, "Nanocrystalline Solar Cell Kit", Institute for Chemical Education in the University of Wisconsin, 17~ (1998)
  2. M. K. Nazeeruddin, "Engineering of Efficient Panchromatic Sensitizers for Nanocrystalline TiO 2 -Based Solar Cells", J. Am. Chem. Soc, 123, pp.1613~ (2001)
  3. G. Schlichthorl, "Band Edge Movement and Recombination Kinetics in Dye-Sensitized Nanocrystalline TiO 2 Solar Cells: A Study by Intensity Modulated Photovoltage Spectroscopy", J. Phys. Chem. B, 101, pp.8141~ (1997)
  4. K. Okada, "100mm × 100mm large-sized dye sensitized solar cells", J. Photochem. and Photobio. A : Chem, 164, pp.193~ (2004)
  5. S. Takenaka, "Layer-by-layer self-assembly replication technique:application to photoelectrode of dye-sensitized solar cell", Thin Solid Films, 346, pp.438~439 (2003)
  6. M. Grätzel, "Dye-sensitized solar cells", J. Photochem. and Photobio. C: Photochem., Reviews, 4, pp.145~ (2003)
  7. S. Ito, "Facile fabrication of mesoporous TiO2 electrodes for dye solar cells:chemical modification and repetitive coating Original Research Article", S. Solar Energy Mater. & Solar Cells, 76, pp.3~13 (2003)
  8. D. M. Chapin, , J. Appl. Phys, 25, pp.676~ (1954)
  9. J. S. Connolly, "Notiz uber Verstarkung photoelectrischer Strome durch potische Sensibilisirung" (1981), Academic press
  10. H. Tsubomura, "Dye sensitised zinc oxide: aqueous electrolyte:platinum photocell", Nature, 261 (1976)
  11. S. Mathew, "Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers", Nature Chemistry, 6, pp.242~247 (2014)
  12. J. Kalowekamo, "Estimating the manufacturing cost of purely organic solar cells", Solar Energy, 83, pp.1224~1231 (2009)
  13. Murakami, "Counter electrodes for application of functional materials as catalysts", Inorg Chim Acta, 361, pp.572~580 (2008)
  14. M. Ikegami, "Improvement in durability of flexible plastic dye-sensitized solar cell modules", Sol. Energy Mater. Sol. Cells, 93, pp.836~839 (2009)
  15. K. Onoda, "The superiority of Ti plate as the substrate of dye-sensitized solar cells", Sol Energy Mater Sol Cells, 91, pp.1176~1181 (2007)
  16. T. Ma, "Properties of several types of novel counter electrodes for dye-sensitized solar cells", J. Electroanal Chem, 574(1), pp.77~83 (2004)
  17. X. Fang, "Flexible counter electrodes based on metal sheet and polymer film for dye-sensitized solar cells", Thin Solid Films, 472, pp.242~245 (2005)
  18. M. Toivola, "Industrial sheet metals for nanocrystalline dye-sensitized solar cell structures", Sol. Energy Mater. Sol. Cells, 90, pp.2881~2893 (2006)
  19. K. Miettunen, "Initial performance of dye solar cells on stainless steel substrates", J. Phys Chem. C, 112, pp.4011~4017 (2008)
  20. S. Ngamsinlapasathian, , Meeting Abstracts, 1001, pp.473~ (2010)
  21. H. Wang, "An investigation on the novel structure of dye-sensitized solar cell with integrated photoanode", Renewable Energy, 34, pp.1635~1638 (2009)
  22. A. D. Pasquier, "Aqueous coating of effcient flexible TiO2 dye solar cell photoanodes", Sol. Energy Mater. Sol. Cells, 93, pp.528~535 (2009)
  23. M. Toivola, "Nanostructured dye solar cells on flexible substrates - review", Int. J. Energy Res, 33, pp.1145~1160 (2009)
  24. K. Miettunen, "Segmented cell design for improved factoring of aging effects in dye solar cells", J. Phys Chem. C, 113, pp.10297~10302 (2009)
  25. G. Gruner, "Carbon nanotube films for transparent and plastic electronics", J. Mater. Chem, 16, pp.3533~3539 (2006)
  26. B. G. Lewis, "Transparent conductive oxides", MRS Bull, 25, pp.22~ (2000)
  27. S. Ito, "High-efficiency (7.2%) flexible dye-sensitized solar cells with Ti-metal substrate for nanocrystalline-TiO2 photoanode", Chem. Commun (Cambridge, UK), 38, pp.4004~4006 (2006)
  28. J. H. Park, "Fabrication of an efficient dye sensitized solar cell with stainless steel substrate", J. Electrochem. Soc, 155(7), pp.F145~F149 (2008)
  29. M. G. Kang, "4.2% efficient flexible dye-sensitized TiO2 solar cells using stainless steel substrate", Sol. Energy Mater Sol. Cells, 903, pp.574~581 (2006)
  30. K. Miettunen, "Stability of dye solar cells with photoelectrode on metal substrates", J. Elec trochem. Soc, 157, pp.B814~B819 (2010)
  31. N. G. Park, "Chemical Sintering of Nanoparticles: A Methodology for Low-Temperature Fabrication of Dye-Sensitized TiO 2 Films", Adv. Mater, 17, pp.2349~ (2005)
  32. Y. Kijitori, "Highly Efficient Plastic Dye-sensitized Photoelectrodes Prepared by Low-temperature Binder-free Coating of Mesoscopic Titania Pastes", Chem. Lett, 36, pp.190~ (2007)
  33. Y. I. Li, "Pure anatase TiO 2 “nanoglue”: An inorganic binding agent to improve nanoparticle interconnections in the low-temperature sintering of dye-sensitized solar cells", Applied Physics Letters, 98, pp.103301~ (2011)
  34. T. Yamaguchi, "Highly efficient plastic substrate dye-sensitized solar cells using a compression method for preparation of TiO 2photoelectrodes", Chem. Commun. Camb, 45, pp.4767~ (2007)
  35. D. Zhang, "Low-temperature fabrication of efficient porous titania photoelectrodes by hydrothermal crystallization at the solid", gas interface, 2003, pp.15(10), 814~817
  36. T. Oekermann, "Electron Transport and Back Reaction in Nanocrystalline TiO 2 Films Prepared by Hydrothermal Crystallization", J. Phys. Chem. B, 108, pp.2227~ (2004)
  37. D. S. Zhang, "Room-Temperature Synthesis of Porous Nanoparticulate TiO 2 Films for Flexible Dye-Sensitized Solar Cells", Adv. Funct. Mater, 16, pp.1228~ (2006)
  38. T. Miyasaka, "Low-Temperature Fabrication of Dye-Sensitized Plastic Electrodes by Electrophoretic Preparation of Mesoporous TiO 2 Layers", J. Electrochem. Soc, 151, pp.A1767~ (2004)
  39. J. H. Yum, "Electrophoretically deposited TiO 2 photo-electrodes for use in flexible dye-sensitized solar cells", J. Photochem. Photobiol.A, 173, pp.1~ (2005)
  40. S. Uchida, "Flexible dye-sensitized solar cells by 28GHz microwave irradiation", J. Photochem. Photobiol. A, 164, pp.93~ (2004)
  41. D. Gutiérrez-Tauste, "New low-temperature preparation method of the TiO 2porous photoelectrode for dye-sensitized solar cells using UV irradiation", J. Photochem. Photobiol. A, 175, pp.165~ (2005)
  42. Y. L. Li, "Effect of Oxygen Concentration on Properties of Indium Zinc Oxide Thin Films for Flexible Dye-Sensitized Solar Cell", Jpn. J. Appl. Phys, 47, pp.6896~ (2008)
  43. M. Dürr, "Low-temperature fabrication of dye-sensitized solar cells by transfer of composite porous layers", Nature Mater, 4, pp.607~ (2005)
  44. D. Zhang, "Low temperature synthesis of porous nanocrystalline TiO 2thick film for dye-sensitized solar cells by hydrothermal crystallization", Chem. Lett, 9, pp.874~875 (2002)
  45. T. N. Murakami, "UV light-assisted chemical vapor deposition of TiO 2 for efficiency development at dye-sensitized mesoporous layers on plastic film electrodes", Chem. Lett, 32, pp.1076~1077 (2003)
  46. H. Kim, "Dye sensitized solar cells using laser processing techniques", Proc SPIE-Int Soc Opt Eng (Photon Processing in Microelectronics and Photonics III), 5339, pp.348~356 (2004)
  47. H. Pan, "Laser annealed composite titanium dioxide electrodes for dye-sensitized solar cells on glass and plastics", Appl. Phys. Lett, 94, pp.071117 (2009), 1-3~
  48. T. Yamaguchi, "Highly efficient plastic-substrate dye-sensitized solar cells with validated conversion effciency of 7.6%", Sol. Energy Mater. Sol. Cells, 94, pp.812~816 (2010)
  49. F. Pichot, "Low-temperature sintering of TiO 2 colloids: application to flexible dye-sensitized solar cells", Langmuir, 16(13), pp.5626~5630 (2000)
  50. T. Miyasaka, "Photovoltaic performance of plastic dye sensitized electrodes prepared by low-temperature binder-free coating of mesoscopic titania", J. Electrochem. Soc, 154, pp.A455-61.49~ (2007)
  51. P. Wang, "A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte", Nature Materials, 2, pp.402~407 (2003)
  52. S. J. Park, "Water-Based Thixotropic Polymer Gel Electrolyte for Dye-Sensitized Solar Cells", ACS Nano, 7, pp.4050~4056 (2013)
  53. C. -L. Chen, "In Situ Gelation of Electrolytes for Highly Efficient Gel-State Dye-Sensitized Solar Cells", Advanced Materials, 23(36), pp.4199~4204 (2011)
  54. D. K. Roh, "High Efficiency Solid-State Dye-Sensitized Solar Cells Assembled with Hierarchical Anatase Pine Tree-like TiO 2 Nanotubes", 24(3), pp.379~386 (2014)
  55. U. Bach, "Solid-state dye-sensitized mesoporous TiO 2 solar cells with high photon-to-electron conversion efficiencies", Nature, 395, pp.583~585 (1998)
  56. N. Cai, "An Organic D- π -A Dye for Record Efficiency Solid-State Sensitized Heterojunction Solar Cells", Nano Lett, 11(4), pp.1452~1456 (2011)
  57. E. Johansson, "Interfacial Properties of Photovoltaic TiO 2", dye, Synthetic metals, pp.2005, 149[DOI]
  58. L. Yang, "Comparing spiro-OMeTAD and P3HT hole conductors in efficient solid state dye-sensitized solar cells", Physical Chemistry, Chemical Physics, 14, pp.779~789 (2012)
  59. B. -W. Park, "Neutral, Polaron and Bipolaron States in PEDOT Prepared by Photo-electrochemical Polymerization and the Effect on Charge Generation Mechanism in the Solid State Dye Sensitized Solar Cell", The Journal of Physical Chemistry C, 117, pp.22484~22491 (2013)
  60. J. Zhang, "Hole transporting material poly (3, 4-ethylenedioxyothiophene) generated from organic and aqueous photoelectrochemical polymerization for an all-solid state dye sensitized solar cell", The Journal of Physical Chemistry C, 118, pp.16591~16601 (2014)
  61. L. Yang, "New Approach for Preparation of Efficient Solid-State Dye-Sensitized Solar Cells by Photoelectrochemical Polymerization in Aqueous Micellar Solution", Journal of Physical Chemistry Letter, 4, pp.4026~4031 (2013)
  62. Q. -B. Meng, "Fabrication of an Efficient Solid-State Dye-Sensitized Solar Cell", Langmuir, 19, pp.3572~3574 (2003)
  63. B. O'Regan, "A Solid-State Dye-Sensitized Solar Cell Fabricated with Pressure-Treated P25TiO 2 and CuSCN: Analysis of Pore Filling and IV Characteristics", Chem. Mater, 14, pp.5023~5029 (2002)
  64. Z. Lan, "Morphology controllable fabrication of Pt counter electrodes for highly efficient dye-sensitized solar cells", J. Mater. Chem, 22, pp.3948~3954 (2012)
  65. Y. Wang, "Transparent flexible Pt counter electrodes for high performance dye-sensitized solar cells", J. Mater. Chem, 22, pp.22155~22159 (2012)
  66. J. D. Roy-Mayhew, "Functionalized Graphene as a Catalytic Counter Electrode in Dye-Sensitized Solar Cells", ACS Nano, 4(10), pp.6203~6211 (2010)
  67. W. J. Lee, "Efficient Dye-Sensitized Solar Cells with Catalytic Multiwall Carbon Nanotube Counter Electrodes", ACS Appl. Mater. Interfaces, 1, pp.1145~1149 (2009)
  68. T. N. Murakami, "Highly Efficient Dye-Sensitized Solar Cells Based on Carbon Black Counter Electrodes", J. Electrochem. Soc., 153, pp.A2255~A2261 (2006)
  69. B. -W. Park, "Understanding Interfacial Charge Transfer between Metallic PEDOT Counter Electrodes and a Cobalt Redox Shuttle in Dye-Sensitized Solar Cells", ACS Appl. Mater. Interfaces, 6, pp.2074~2079 (2014)

관련 논문AI추천

유기태양전지 저비용 광활성층 재료의 개발 동향김소영, 이원호한국접착및계면학회 · 접착 및 계면2024 · 제25권 제1호저온 소성용 TiO2 페이스트를 이용한 유연 염료감응 태양전지 제작김동우, 문병무, 성창현, 송상우, 이혁수, 조만식, 조슬기한국신·재생에너지학회 · 신재생에너지2017 · 제13권 제1호차세대 박막 태양전지 기술 동향 및 미래 기술에 대한 연구김무진중소기업융합학회 · 산업과 과학2024 · 제3권 제4호차세대 태양전지 하이브리드 기술의 전망이재관, 이재준한국전기화학회 · 전기화학회지2010 · 제13권 제1호염료감응 태양전지의 전기화학적 접근을 통한 해석남희진, 임정민, 전용석, 조임현한국전기화학회 · 전기화학회지2009 · 제12권 제4호유기태양전지 계면 기술 동향김기환한국접착및계면학회 · 접착 및 계면2021 · 제22권 제4호

이 간행물의 다른 논문 (6건)

질화 처리된 LATP 고체전해질의 알칼라인 용액내에서의 내화학특성 개선 연구이종원, 성지영, 임원빈, 정규남, 김성수pp. 45-50고전압 리튬이차전지를 위한 LiNi0.5Mn1.5O4 양극용전해질로써 상온 이온성 액체 전해질의 불순물 효과에 관한 연구문준영, 임태은, Tron Artur V, 김지용pp. 51-57LiBOB 전해액 첨가제 도입에 따른Li(Ni1/3Co1/3Mn1/3)O2/graphite 전지의 고온특성이혜원, 유명현, 이용민, 정지선, 이후길pp. 58-67리튬이차전지용 Si-M (M : Cr, Ni) 합금 음극의 미세구조와 전기화학적 특성김성수, 성재욱, 이성현pp. 68-74서로 다른 친수성구조를 가지는 고분자전해질 연료전지용 멀티블록형 술폰산화 폴리아릴렌에테르술폰 전해질막의 합성 및 특성 분석육진옥, 이소정, 배병찬, 양태현pp. 75-80
원문 보기