고효율의 리튬/공기 이차전지 공기전극용 Mn1+XCo2-XO4 고용체 촉매 합성 및 분석
Synthesis and Characterizations of Mn1+XCo2-XO4 Solid Solution Catalysts for Highly Efficient Li/Air Secondary Battery
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Mn1+XCo2-XO4 solid solutions with various Mn/Co ratios were synthesized by a combustion method, and used as cathode catalysts for lithium/air secondary battery. Their electrochemical and physicochemical properties were investigated. The morphology was examined by transmission electron microscopy (TEM), and the crystallinity was confirmed by X-ray diffraction (XRD) analyses. For the measurement of electrochemical properties, charge and discharge measurements were carried out at a constant current density of 0.2 mA/ cm2, monitoring the voltage change. Electrochemical impedance spectroscopy (EIS) analyses were also employed to examine the change in charge transfer resistance during charge-discharge process. Mn1+XCo2-XO4 solid solutions showed enhanced cycleability as a cathode of Li/air secondary battery, and the performance was found to be strongly dependent on Mn/ Co ratio. Among synthesized catalysts, Mn1.5Co1.5O4 exhibited the best performance and cycleability, due to high charge transfer rate.
Abstract
Mn1+XCo2-XO4 solid solutions with various Mn/Co ratios were synthesized by a combustion method, and used as cathode catalysts for lithium/air secondary battery. Their electrochemical and physicochemical properties were investigated. The morphology was examined by transmission electron microscopy (TEM), and the crystallinity was confirmed by X-ray diffraction (XRD) analyses. For the measurement of electrochemical properties, charge and discharge measurements were carried out at a constant current density of 0.2 mA/ cm2, monitoring the voltage change. Electrochemical impedance spectroscopy (EIS) analyses were also employed to examine the change in charge transfer resistance during charge-discharge process. Mn1+XCo2-XO4 solid solutions showed enhanced cycleability as a cathode of Li/air secondary battery, and the performance was found to be strongly dependent on Mn/ Co ratio. Among synthesized catalysts, Mn1.5Co1.5O4 exhibited the best performance and cycleability, due to high charge transfer rate.
참고문헌 (14)
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