리튬이차전지용 고체 전해질의 최근 진전과 전망
Recent Progress and Perspectives of Solid Electrolytes for Lithium Rechargeable Batteries
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초록
현재 상용화되어 있는 리튬이온전지에 사용하고 있는 비수계 유기 전해액은 가연성, 부식성, 고휘발성, 열적 불안정성 등의 단점 때문에 더욱 안전하고 장수명을 보이는 고체 전해질로 대체하는 연구가 진행되고 있으며, 이것은 전기자동차 및 에너지저장 시스템과 같은 중대형 이차전지에도 효율적으로 활용될 수 있다. 다양한 형태의 고체 전해질 중에서 현재 고분자 매트릭스에 활성 무기 충진재가 포함되어 있는 복합 고체 전해질이 고이온전도도와 전극과의 탁월한 계면접촉을 이루는데 가장 유리한 것으로 알려졌다. 본 총설에서는 우선 고체 전해질의 종류와 연혁에관해 간단히 소개하고, 고분자 및 무기 충진재 (불활성 및 활성)로 구성되는 고체 고분자 전해질 및 무기 고체 전해질의 기본적 물성 및 전기화학적 특성을 개괄한다. 또한 이 소재들의 형상을 기준으로 입자형 (0D), 섬유형 (1D), 평판형 (2D), 입체형 (3D)의 형식으로 구성된 복합고체 전해질과 이에 따른 전고체 전지의 전기화학적 특성을 논의한다. 특히 리튬금속 음전극을사용하는 전고체 전지에 있어서 양전극-전해질 계면, 음전극-전해질 계면, 입자간 계면의 특성에관해 소개하고, 마지막으로 현재까지 보고된 관련 총설들을 참조하여 복합 고체 전해질 기술의현재 요구조건 및 미래 전망을 알아본다.
Abstract
Nonaqueous organic electrolyte solution in commercially available lithium-ion batteries, due to its flammability, corrosiveness, high volatility, and thermal instability, is demanding to be substituted by safer solid electrolyte with higher cycle stability, which will be utilized effectively in large-scale power sources such as electric vehicles and energy storage system. Of various types of solid electrolytes, composite solid electrolytes with polymer matrix and active inorganic fillers are now most promising in achieving higher ionic conductivity and excellent interface contact. In this review, some kinds and brief history of solid electrolyte are at first introduced and consequent explanations of polymer solid electrolytes and inorganic solid electrolytes (including active and inactive fillers) are comprehensively carried out. Composite solid electrolytes including these polymer and inorganic materials are also described with their electrochemical properties in terms of filler shapes, such as particle (0D), fiber (1D), plane (2D), and solid body (3D). In particular, in all-solid-state lithium batteries using lithium metal anode, the interface characteristics are discussed in terms of cathode-electrolyte interface, anode-electrolyte interface, and interparticle interface. Finally, current requisites and future perspectives for the composite solid electrolytes are suggested by help of some decent reviews recently reported.
참고문헌 (48)
- E. Quartarone, "Electrolytes for Solid-State Lithium Rechargeable Batteries: Recent Advances and Perspectives", Chem. Soc. Rev., 40, pp.2525~2540 (2011)
- A. Varzi, "Challenges and Prospects of the Role of Solid Electrolytes in the Revitalization of Lithium Metal Batteries", J. Mater. Chem. A, 4, pp.17251~17259 (2016)
- M. Keller, "Hybrid Electrolytes for Lithium Metal Batteries", J. Power Sources, 392, pp.206~225 (2018)
- H. Yang, "Recent Progress and Perspective on Lithium Metal Anode Protection", Energy Storage Mater., 14, pp.199~221 (2018)
- X. -B. Cheng, "Recent Advances in Energy Chemistry between Solid-State Electrolyte and Safe Lithium-Metal Anodes", Chem, 5, pp.74~96 (2019)
- M. Dirican, "Composite Solid Electrolytes for All-Solid-State Lithium Batteries", Mater. Sci. Eng. R, 136, pp.27~46 (2019)
- S. Xia, "Practical Challenges and Future Perspectives of All-Solid-State Lithium-Metal Batteries", Chem, 5, pp.753~785 (2019)
- M. Shoji, "Recent Progress for All Solid State Battery Using Sulfide and Oxide Solid Electrolytes", J. Phys. D: Appl. Phys., 52, pp.103001~ (2018)
- A. Miura, "Liquid-Phase Synthesis of Sulfide Electrolytes for All-Solid-State Lithium Battery", Nature Rev. Chem, 3, pp.189~198 (2019)
- J. C. Bachman, "Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanism and Properties Governing Ion Conduction", Chem. Rev., 116, pp.140~162 (2016)
- X. Chen, "Solid and Solid-like Composite Electrolyte for Lithium Ion Batteries:Engineering the Ion Conductivity at Interfaces", Adv. Mater. Interf., 6, pp.1800899~ (2019)
- Y. S. Jung, "Issues and Challenges for Bulk-Type All-Solid-State Rechargeable Batteries Using Sulfide Solid Electrolytes", Israel J. Chem., 50, pp.472~485 (2015)
- L. Xu, "Interfaces in Solid-State Lithium Batteries", Joule, 2, pp.1991~2015 (2018)
- Z. Wu, "Utmost Limits of Various Solid Electrolytes in All-Solid-State Lithium Batteries: A Critical Review", Renewable Sustain. Energy Rev., 109, pp.367~385 (2019)
- Y. Tateyama, "Theoretical Picture of Positive Electrode-Solid Electrolyte Interface in All-Solid-State Battery from Electrochemistry and Semiconductor Physics Viewpoints", Curr. Op. Electrochem., 17, pp.149~157 (2019)
- L. Liang, "Sur-", Interfacial Regulation in All-Solid-State Rechargeable Li-ion Batteries Based on Inorganic Solid-State Electrolytes: Advances and Perspectives, 2019, pp.6, 871~910
- Z. Jiang, "Reducing the Interfacial Resistance in All-Solid-State Lithium Batteries Based on Oxide Ceramic Electrolytes", ChemElectroChem, 6, pp.2970~2983 (2019)
- M. Du, "Recent advances in the Interface Engineering of Solid-State Li-ion Batteries with Artificial Buffer Layers: Challenges, Materials, Construction, and Characterization", Energy Environ. Sci., 12, pp.1780~1804 (2019)
- Q. Wang, "Progress of Enhancing the Safety of Lithium Ion Battery from the Electrolyte Aspect", Nano Energy, 55, pp.93~114 (2019)
- G. -L. Zhu, "Fast Charging Lithium Batteries: Recent Progress and Future Prospects", Small, 15, pp.1805389~ (2019)
- H. Shen, "Solid-State Electrolyte Considerations for Electric Vehicle Batteries", Sustainable Energy Fuels, 3, pp.1647~1659 (2019)
- M. Zhu, "Recent Advances in Gel Polymer Electrolyte for High-Performance Lithium Batteries", J. Energy Chem., 37, pp.126~142 (2019)
- F. Baskoro, "Strategic Structural Design of a Gel Polymer Electrolyte toward a High Efficiency Lithium-ion Battery", ACS Energy Mater., 2, pp.3937~3971 (2019)
- J.B. Bates, "Electrical Properties of Amorphous Lithium Electrolyte Thin Films", Solid State Ionics, 53-56, pp.647~654 (1992)
- N.J. Dudney, "Sputtering of Lithium Compounds for Preparation of Electrolyte Thin Films", Solid State Ionics, 53-56, pp.655~661 (1992)
- Y. Inaguma, "High Ionic Conductivity in Lithium Lanthanum Titanate", Solid State Commun., 86, pp.689~693 (1993)
- J. Fu, "Fast Li+ Ion Conducting Glass-Ceramics in the System Li2O-Al2O3-GeO2-P2O5", Solid State Ionics, 104, pp.191~194 (1997)
- J. Fu, "Superionic Conductivity of Glass-Ceramics in the System Li2O-Al2O3-TiO2-P2O5", Solid State Ionics, 96, pp.195~200 (1997)
- R. Murugan, "Fast Lithium Ion Conduction in Garnet-Yype Li7La3Zr2O12", Angew. Chem. Intern. Ed., 46, pp.7778~7781 (2007)
- N. Kamaya, "A Lithium Superionic Conductor", Nature Mater., 10, pp.682~686 (2011)
- Y. Seino, "A Sulphide Lithium Super-Ion Conductor is Superior to Liquid Ion Conductors for Use in Rechargeable Batteries", Energy Environ. Sci., 7, pp.627~631 (2014)
- Y. Kato, "High-Power All-Solid-State Batteries Using Sulfide Superionic Conductors", Nature Energy, 1, pp.16030~ (2016)
- D. C. Lin, "High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO2 Nanospheres in Poly(ethylene oxide)", Nano Lett., 16, pp.459~465 (2016)
- X. Zhang, "Synergistic Coupling between Li6.25La3Zr1.75Ta0.25O12 and Poly(vinylidene fluoride) Induces High Ionic Conductivity, Mechanical Strength, and Thermal Stability of Solid Composite Electrolytes", J. Am. Chem. Soc., 139, pp.13779~13785 (2017)
- W. Liu, "Ionic Conductivity Enhancement of Polymer Electrolytes with Ceramic Nanowire Fillers", Nano Lett., 15, pp.2740~2745 (2015)
- T. Tang, "Composite Polymer Electrolytes with Li7La3Zr2O12Garnet-Type Nanowire as Ceramic Fillers: Mechanism of Conductivity Enhancement and Role of Doping and Morphology", ACS Appl. Mater. Interf., 9, pp.21773~21780 (2017)
- Y. Zhao, "A Chemistry and Material Perspective on Lithium Redox Flow Batteries towards High-Density Electrical Energy Storage", Chem. Soc. Rev., 44, pp.7968~7996 (2015)
- J. Zheng, "Lithium Ion Pathway within Li7La3Zr2O12-Polyethylene Oxide Composite Electrolytes", Angew. Chem. Intern. Ed., 55, pp.12538~12542 (2016)
- W. Liu, "Enhancing Ionic Conductivity in Composite Polymer Electrolytes with Well-Aligned Ceramic Nanowires", Nature Energy, 2, pp.17035~ (2017)
- K. (K. )Fu, "Flexible, Solid-State, Ion-Conducting Membrane with 3D Garnet Nanofiber Networks for Lithium Batteries", Proc. Natl. Acad. Sci., 113, pp.7094~7099 (2016)
- D. Lin, "A Silica-Aerogel-Reinforced Composite Polymer Electrolyte with High Ionic Conductivity and High Modulus", Adv. Mater., 30, pp.1802661~ (2018)
- S. Wang, "Polymeric Ionic Liquid-Functionalized Mesoporous Silica Nanoplates: A New High-Performance Composite Polymer Electrolyte for Lithium Batteries", Electrochim. Acta, 245, pp.1010~1022 (2017)
- W. Liu, "Improved Lithium Ionic Conductivity in Composite Polymer Electrolytes with Oxide-Ion Conducting Nanowires", ACS Nano, 10, pp.11407~11413 (2016)
- X. Zhang, "Vertically Aligned and Continuous Nanoscale Ceramic-Polymer Interfaces in Composite Solid Polymer Electrolytes for Enhanced Ionic Conductivity", Nano Lett., 18, pp.3829~3838 (2018)
- X. Tao, "Solid-State Lithium-Sulfur Batteries Operated at 37oC with Composites of Nanostructured Li7La3Zr2O12", Carbon Foam and Polymer, 2017, pp.17, 2967~2972
- K. Takeda, "Progress and Perspective of Solid-State Lithium Batteries", Acta Mater., 61, pp.759~770 (2013)
- J. Haruyama, "Space-Charge Layer Effect at Interface between Oxide Cathode and Sulfide Electrolyte in All-Solid-State Lithium-ion Battery", Chem. Mater., 26, pp.4248~4255 (2014)
- X. -B. Cheng, "Towards Safe Lithium Metal Anode in Rechargeable Lithium Batteries: A Review", Chem. Rev., 117, pp.10403~10473 (2017)