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친환경 페로브스카이트 태양전지 최신 기술 동향

Recent Research Progress on Eco-Friendly Perovskite Solar Cells

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주제분류화학

초록

금속 할로겐 페로브스카이트 (perovskite)는 우수한 전기적, 광학적 특성으로 인해 차세대 태양전지의 핵심 소재로 큰 주목을 받고 있다. 페로브스카이트 태양전지는 등장 이후 전례 없는 단기간 효율 향상을 보이며 현재 24% 이상의 인증된 광전 변환 효율을 달성하였지만, 대부분의 고성능 페로브스카이트 태양전지는 유독성 납 (Pb)을 기반으로 한 페로브스카이트를 사용한 것으로, 향후 상용화를 위해서는 납을 쓰지 않는 친환경 페로브스카이트 개발이 필수적이다. 본 글에서는비납 페로브스카이트 물질 및 연구 동향에 대해서 소개하고자 한다.

Abstract

Metal halide perovskite materials are considered as promising semiconducting materials for next-generation solar cells due to their unique electrical and optical properties. Intensive progress in perovskite solar cell yielded a certified power conversion efficiency over 24%. However, most of highly efficient perovskite solar cells required Pb-based perovskite materials, which is a critical obstacle for their commercialization, and development of Pb-free perovskite materials is one of recent urgent issues in this field. In this paper, we will introduce recent research progress on Pb-free perovskite solar cells.

참고문헌 (26)

  1. A. K. Jena, "Halide Perovskite Photovoltaics: Background, Status, and Future Prospects", Chem. Rev, 119, pp.3036~ (2019)
  2. S. Rühle, "Tabulated values of the Shockley–Queisser Limit for Single Junction Solar Cells", Solar Energy, 130, pp.139~ (2016)
  3. S. D. Stranks, "Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber", Science, 342, pp.341~ (2013)
  4. W. -J. Yin, "Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance", Adv. Mater, 26, pp.4653~ (2014)
  5. C. C. Stoumpos, "Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties", Inorg. Chem., 52, pp.9019~ (2013)
  6. Z. Chen, "Schottky Solar Cells based on CsSnI3 Thin-Films", Appl. Phys. Lett, 101, pp.093901~ (2012)
  7. N. K. Noel, "Lead-Free Organic-Inorganic Tin Halide Perovskites for Photovoltaic Applications", Energy Environ. Sci, 7, pp.3061~ (2014)
  8. F. Hao, "Lead-Free Solid-State Organic-Inorganic Halide Perovskite Solar Cells", Nature Photon, 8, pp.489~ (2014)
  9. F. Hao, "Solvent-Mediated Crystallization of CH3NH3SnI3 Films for Heterojunction Depleted Perovskite Solar Cells", J. Am. Chem. Soc, 137, pp.11445~ (2015)
  10. T. M. Koh, "Formamidinium Tin-based Perovskite with Low Eg for Photovoltaic Applications", J. Mater. Chem. A, 3, pp.14996~ (2015)
  11. S. J. Lee, "Fabrication of Efficient Formamidinium Tin Iodide Perovskite Solar Cells through SnF2-Pyrazine Complex", J. Am. Chem. Soc, 138, pp.3974~ (2016)
  12. K. P. Marshall, "Enhanced Stability and Efficiency in Hole-Transport-Layer-Free CsSnI3 Perovskite Photovoltaics", Nat. Energy, 1, pp.178~ (2016)
  13. T. -B. Song, "Importance of Reducing Vapor Atmosphere in the Fabrication of Tin-based Perovskite Solar Cells", J. Am. Chem. Soc, 139, pp.836~ (2017)
  14. D. H. Cao, "Thin Films and Solar Cells Based on Semiconducting Two-Dimensional Ruddlesden–Popper (CH3(CH2)3NH3)2(CH3NH3)n−1SnnI3n+1 Perovskites", ACS Energy Lett, 2, pp.982~ (2017)
  15. Y. Liao, "Highly Oriented Low-Dimensional Tin Halide Perovskites with Enhanced Stability and Photovoltaic Performance", J. Am. Chem. Soc, 139, pp.6693~ (2017)
  16. S. Shao, "Highly Reproducible Sn-Based Hybrid Perovskite Solar Cells with 9% Efficiency", Adv. Energy Mater, 8, pp.1702019~ (2018)
  17. C. C. Stoumpos, "Hybrid Germanium Iodide Perovskite Semiconductors: Active Lone Pairs, Structural Distortions, Direct and Indirect Energy Gaps and Strong Nonlinear Optical Properties", J. Am. Chem. Soc, 137, pp.6804~ (2015)
  18. T. Krishnamoorthy, "Lead-Free Germanium Iodide Perovskite Materials for Photovoltaic Applications", J. Mater. Chem. A, 3, pp.23829~ (2015)
  19. B. -W. Park, "Bismuth based Hybrid Perovskites A3Bi2I9(A : methylammonium or cesium)for Solar Cell Application", Adv. Mater, 27, pp.6806~ (2015)
  20. R. L. Z. Hoye, "Methylammonium Bismuth Iodide as a Lead-free, Stable Hybrid Organic-Inorganic Solar Absorber", Chem. Eur. J, 22, pp.2605~ (2016)
  21. Z. Zhang, "High-Quality(CH3NH3)3Bi2I9 Film-Based Solar Cells : Pushing Efficiency up to 1. 64%", J. Phys. Chem. Lett, 8, pp.4300~ (2017)
  22. B. Saparov, "Thin-Film Preparation and Characterization of Cs3Sb2I9: A Lead-Free Layered Perovskite Semiconductor", Chem. Mater, 27, pp.5622~ (2015)
  23. P. C. Harikesh, "Rb as an Alternative Cation for Templating Inorganic Lead-Free Perovskites for Solution Processed Photovoltaics", Chem. Mater, 28, pp.7496~ (2016)
  24. F. Jiang, "Chlorine-Incorporation-Induced Formation of the Layered Phase for Antimony-Based Lead-Free Perovskite Solar Cells", J. Am. Chem. Soc, 140, pp.1019~ (2018)
  25. A. H. Slavney, "A Bismuth-Halide Double Perovskite with Long Carrier Recombination Lifetime for Photovoltaic Applications", J. Am. Chem. Soc, 138, pp.2138~ (2016)

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