본문 바로가기
KERD
논문KCI 등재

투명 박막 리튬이차전지를 위한 LiNiPO4 박막의 광학 및 전기화학적 특성

Optical and Electrochemical Properties of LiNiPO4 Thin Film for Transparent Thin Film Lithium Secondary Battery

0

조회

0

다운로드

0

인용

0

참고문헌

키워드

주제분류공학일반

초록

Transparent olivine LiNiPO4 thin films on sapphire substrates were fabricated by radio frequency (RF) magnetron sputtering. The X- ray diffraction patterns show these thin films have the phase of LiNiPO4 with an ordered olivine structure indexed to the orthorhombic Pmna space group. LiNiPO4 thin films deposited on sapphire substrates exhibit transmittance of about 83 %. It was confirmed that the LiNiPO4 thin film exhibits a high potential of 5 V-class.

Abstract

Transparent olivine LiNiPO4 thin films on sapphire substrates were fabricated by radio frequency (RF) magnetron sputtering. The X- ray diffraction patterns show these thin films have the phase of LiNiPO4 with an ordered olivine structure indexed to the orthorhombic Pmna space group. LiNiPO4 thin films deposited on sapphire substrates exhibit transmittance of about 83 %. It was confirmed that the LiNiPO4 thin film exhibits a high potential of 5 V-class.

참고문헌 (17)

  1. P. Gorrn, "Towards seethrough displays: Fully transparent thin-film transistors driving transparent organic light-emitting diodes", Adv. Mater., 18(6), pp.738~741 (2006)[DOI]
  2. S.H. Ju, "Transparent active matrix organic light-emitting diode displays driven by nanowire transistor circuitry", Nano Lett., 8(4), pp.997~1004 (2008)[DOI]
  3. S.H. Ko Park, "Transparent ZnO thin film transistor array for the application of transparent AMOLED display", SID Symp. Dig. Tech. Pap., 37, pp.25~28 (2012)
  4. Y. Yang, "Transparent lithium-ion batteries", PNAS, 108(32), pp.13013~13018 (2011)[DOI]
  5. Y. Xu, "Comparative studies of the electronic structure of <TEX>$LiFePO_4$<", TEX>, <TEX>$FePO_4$<, TEX>, LiMn- PO4, <TEX>$LiCoPO_4$<, pp.TEX>, and <TEX>$LiNiPO_4$<, TEX>[DOI]
  6. A.K. Padhi, "Phospho-olivines as positive-electrode materials for rechargeable lithium batteries", J. Electrochem. Soc., 144(4), pp.1188~1194 (1997)[DOI]
  7. B. Zhang, "Electrochemical performances of <TEX>$LiFe_{1−x}Mn_xPO_4$<", TEX> with high Mn content, 2011, pp.196(16), 6992~6996
  8. M.R. Roberts, "High throughput electrochemical observation of structural phase changes in <TEX>$LiFe_{1−x}Mn_xPO_4$<", TEX> during charge and discharge, 2010, pp.154(4), A381~A386
  9. G. Kobayashi, "Shift of redox potential and kinetics in <TEX>$Li_x(MnyFe_{1−y})PO_4$<", TEX>, 2009, pp.189(1), 397~401
  10. J. Wolfenstine, "<TEX>$Ni^{3+}", Ni^2$<, TEX>, pp.J. power sources, 2005[DOI]
  11. M. Piana, "Characterization of Phospho- olivines as Materials for Li-ion Cell Cathodes", Ionics, 8(1), pp.17~26 (2002)[DOI]
  12. M. Minakshia, "Synthesis and characterization of olivine LiNiPO4 for aqueous rechargeable battery", Electrochim. Acta, 56(11), pp.4356~4360 (2011)[DOI]
  13. S.P. Ong, "Comparison of small polaron migration and phase separation in olivine <TEX>$LiMnPO_4$<", TEX> and <TEX>$LiFePO_4$<, Phys. Rev. B, pp.2011, 83(7)[DOI]
  14. L. Wang, "Preparation and characterization of nano-sized <TEX>$LiFePO_4$<", TEX> by low heating solidstate coordination method and microwave heating, 2007, pp.52(24), 6778~6783
  15. Y. Ge, "An optimized Ni doped <TEX>$LiFePO_4$<", TEX>, Electrochim. Acta, pp.2010, 55(20)[DOI]
  16. J. Yang, "Synthesis and characterization of carbon- coated lithium transition metal phosphates <TEX>$LiMPO_4$<", TEX> (M = Fe, Mn, Co, Ni) prepared via a nonaqueous sol-gel route, 2006, pp.153(4), A716~A723
  17. X. Rui, "Olivine-type nanosheets for lithium ion battery cathodes", ACS Nano, 7(6), pp.5637~5646 (2013)[DOI]

관련 논문AI추천

이 간행물의 다른 논문 (11건)