Self-activated Graphene Gas Sensors: A Mini Review
0
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Graphene has been widely considered a promising candidate for high-quality chemical sensors, owing to its outstanding characteristics, such as sensitive gas adsorption at room temperature, high conductivity, high flexibility, and high transparency. However, the main drawback of a graphene-based gas sensor is the necessity for external heaters due to its slow response, incomplete recovery, and low selectivity at room temperature. Conventional heating devices have limitations such as large volume, thermal safety issues, and high power consumption. Moreover, metal-based heating systems cannot be applied to transparent and flexible devices. Thus, to solve this problem, a method of supplying the thermal energy necessary for gas sensing via the self-heating of graphene by utilizing its high carrier mobility has been studied. Herein, we provide a brief review of recent studies on self-activated graphene-based gas sensors. This review also describes various strategies for the self-activation of graphene sensors and the enhancement of their sensing properties.
Abstract
Graphene has been widely considered a promising candidate for high-quality chemical sensors, owing to its outstanding characteristics, such as sensitive gas adsorption at room temperature, high conductivity, high flexibility, and high transparency. However, the main drawback of a graphene-based gas sensor is the necessity for external heaters due to its slow response, incomplete recovery, and low selectivity at room temperature. Conventional heating devices have limitations such as large volume, thermal safety issues, and high power consumption. Moreover, metal-based heating systems cannot be applied to transparent and flexible devices. Thus, to solve this problem, a method of supplying the thermal energy necessary for gas sensing via the self-heating of graphene by utilizing its high carrier mobility has been studied. Herein, we provide a brief review of recent studies on self-activated graphene-based gas sensors. This review also describes various strategies for the self-activation of graphene sensors and the enhancement of their sensing properties.
참고문헌 (34)
- K. S. Novoselov, "A roadmap for graphene", Nature, 490(7419), pp.192~200 (2012)
- Y. H. Kim, "Chemically fluorinated graphene oxide for room temperature ammonia detection at ppb levels", J. Mater. Chem. A, 5(36), pp.19116~19125 (2017)
- Y. Kim, "Au decoration of a graphene microchannel for self-activated chemoresistive flexible gas sensors with substantially enhanced response to hydrogen", Nanoscale, 11(6), pp.2966~2973 (2019)
- K. S. Kim, "Large-scale pattern growth of graphene films for stretchable transparent electrodes", Nature, 457(7230), pp.706~710 (2009)
- A. K. Geim, "Van der Waals heterostructures", Nature, 499(7459), pp.419~425 (2013)
- S. Bae, "Roll-to-roll production of 30-inch graphene films for transparent electrodes", Nat. Nanotechnol, 5(8), pp.574~578 (2010)
- J. Ahn, "Graphene for displays that bend", Nat. Nanotechnol, 9(10), pp.737~738 (2014)
- F. Schedin, "Detection of Individual Gas Molecules Adsorbed on Graphene", Nat. Mater, 6(9), pp.652~655 (2007)
- G. Lu, "Toward Practical Gas Sensing with Highly Reduced Graphene Oxide : A New Signal Processing Method to Circumvent Run-to-Run and Device-to-Device Variations", ACS Nano, 5(2), pp.1154~1164 (2011)
- Y. Dan, "Intrinsic Response of Graphene Vapor Sensors", Nano Lett, 9(4), pp.1472~1475 (2009)
- J. T. Robinson, "Reduced Graphene Oxide Molecular Sensors", Nano Lett, 8(10), pp.3137~3140 (2008)
- G. Lu, "Gas Detection Using Low-Temperature Reduced Graphene Oxide Sheets", Appl. Phys. Lett., 94(8), pp.083111(1)~083111(3) (2009)
- Q. He, "Centimeter-Long and Large-Scale Micropatterns of Reduced Graphene Oxide Films : Fabrication and Sensing Applications", ACS Nano, 4(6), pp.3201~3208 (2010)
- A. Lipatov, "Highly Selective Gas Sensor Arrays Based on Thermally Reduced Graphene Oxide", Nanoscale, 5(12), pp.5426~5434 (2013)
- S. Cui, "Ultrasensitive Chemical Sensing through Facile Tuning Defects and Functional Groups in Reduced Graphene Oxide", Anal. Chem, 86(15), pp.7516~7522 (2014)
- W. Li, "Reduced Graphene Oxide Electrically Contacted Graphene Sensor for Highly Sensitive Nitric Oxide Detection", ACS Nano, 5(9), pp.6955~6961 (2011)
- M. W. Nomani, "Highly Sensitive and Selective Detection of NO2 Using Epitaxial Graphene on 6H-SiC", Sens. Actuators B, 150(1), pp.301~307 (2010)
- K. Yu, "Patterning Vertically Oriented Graphene Sheets for Nanodevice Applications", J. Phys. Chem. Lett, 2(6), pp.537~542 (2011)
- S. Jonda, "Temperature Control of Semiconductor Metal-Oxide Gas Sensors by Means of Fuzzy Logic", Sens. Actuators B, 34(1-3), pp.396~400 (1996)
- H. G. Moon, "Self-activated ultrahigh chemosensitivity of oxide thin film nanostructures for transparent sensors", Sci. Rep, 2(1), pp.1~7 (2012)
- S. Capone, "Solid state gas sensors : State of the art and future activities", J. Optoelectron. Adv. Mater, 5(5), pp.1335~1348 (2003)
- G. Eranna, "Oxide materials for development of integrated gas sensors-A comprehensive review", Crit. Rev. Solid State Mater. Sci., 29(3-4), pp.111~188 (2004)
- J. Mizsei, "How can Sensitive Semiconductor Gas Sensors be Made?", Sens. Actuators B, 23(2-3), pp.173~176 (1995)
- J. D. Fowler, "Practical Chemical Sensors from Chemically Derived Graphene", ACS Nano, 3(2), pp.301~306 (2009)
- M. Penza, "Classification of food, beverages and perfumes by WO3 thinfilm sensors array and pattern recognition techniques", Sens. Actuators B, 73(1), pp.76~87 (2001)
- J. -H. Ahn, "Self-heated silicon nanowires for high performance hydrogen gas detection", Nanotechnology, 26(9), pp.095501(1)~095501(10) (2015)
- M. G. Stanford, "Laser-Induced Graphene for Flexible and Embeddable Gas Sensors", ACS Nano, 13(3), pp.3474~3482 (2019)
- D. Wu, "A Simple Graphene NH3Gas Sensor via Laser Direct Writing", Sensors, 18(12), pp.4405(1)~4405(10) (2018)
- M. R. Bobinger, "Flexible and robust laser-induced graphene heaters photothermally scribed on bare polyimide substrates", Carbon, 144, pp.116~126 (2019)
- H. Choi, "Flexible and transparent gas molecule sensor integrated with sensing and heating graphene layers", Small, 10(18), pp.3685~3691 (2014)
- Y. H. Kim, "Self-activated transparent allgraphene gas sensor with endurance to humidity and mechanical bending", ACS Nano, 9(10), pp.10453~10460 (2015)
- T. Yokoyama, "Pd-functionalized, suspended graphene nanosheet for fast, low-energy multimolecular sensors", ACS Appl. Nano Mater, 1(8), pp.3886~3894 (2018)
- Y. Kim, "Au decoration of a graphene microchannel for self-activated chemoresistive flexible gas sensors with substantially enhanced response to hydrogen", Nanoscale, 11(6), pp.2966~2973 (2019)
- L. Yang, "Novel gas sensing platform based on a stretchable laser-induced graphene pattern with self-heating capabilities", J. Mater. Chem. A, 8(14), pp.6487~6500 (2020)
