본문 바로가기
KERD
논문KCI 등재

BaTiO3 압전나노입자와 폴리머로 제작된 비납계 압전복합체의 스트레쳐블 압전 센서 어레이로의 적용 연구

Stretchable Sensor Array Based on Lead-Free Piezoelectric Composites Made of BaTiO3 Nanoparticles and Polymeric Matrix

2

조회

0

다운로드

1

인용

0

참고문헌

키워드

주제분류공학일반

초록

Piezoelectric energy harvesting has attracted increasing attention over the last decade as a means for generating sustainable and longlasting energy from wasted mechanical energy. To develop self-powered wearable devices, piezoelectric materials should be flexible, stretchable, and bio-eco-friendly. This study proposed the fabrication of stretchable piezoelectric composites via dispersing perovskitestructured BaTiO3 nanoparticles inside an Ecoflex polymeric matrix. In particular, the stretchable piezoelectric sensor array was fabricated via a simple and cost-effective spin-coating process by exploiting the piezoelectric composite comprising of BaTiO3 nanoparticles, Ecoflex matrix, and stretchable Ag coated textile electrodes. The fabricated sensor generated an output voltage of ~4.3 V under repeated compressing deformations. Moreover, the piezoelectric sensor array exhibited robust mechanical stability during mechanical pushing of ~5,000 cycles. Finite element method with multiphysics COMSOL simulation program was employed to support the experimental output performance of the fabricated device. Finally, the stretchable piezoelectric sensor array can be used as a self-powered touch sensor that can effectively detect and distinguish mechanical stimuli, such as pressing by a human finger. The fabricated sensordemonstrated potential to be used in a stretchable, lead-free, and scalable piezoelectric sensor array.

Abstract

Piezoelectric energy harvesting has attracted increasing attention over the last decade as a means for generating sustainable and longlasting energy from wasted mechanical energy. To develop self-powered wearable devices, piezoelectric materials should be flexible, stretchable, and bio-eco-friendly. This study proposed the fabrication of stretchable piezoelectric composites via dispersing perovskitestructured BaTiO3 nanoparticles inside an Ecoflex polymeric matrix. In particular, the stretchable piezoelectric sensor array was fabricated via a simple and cost-effective spin-coating process by exploiting the piezoelectric composite comprising of BaTiO3 nanoparticles, Ecoflex matrix, and stretchable Ag coated textile electrodes. The fabricated sensor generated an output voltage of ~4.3 V under repeated compressing deformations. Moreover, the piezoelectric sensor array exhibited robust mechanical stability during mechanical pushing of ~5,000 cycles. Finite element method with multiphysics COMSOL simulation program was employed to support the experimental output performance of the fabricated device. Finally, the stretchable piezoelectric sensor array can be used as a self-powered touch sensor that can effectively detect and distinguish mechanical stimuli, such as pressing by a human finger. The fabricated sensordemonstrated potential to be used in a stretchable, lead-free, and scalable piezoelectric sensor array.

참고문헌 (21)

  1. L. M. Swallow, "A piezoelectric fibre composite based energy harvesting device for potential wearable applications", Smart Mater. Struct, 17(2), pp.025017~ (2008)
  2. 김태환, "Skin-interfaced Wearable Biosensors: A Mini-Review", 센서학회지, 31(2), pp.71~78 (2022), 한국센서학회
  3. C. Erdmier, "Wearable device implications in the healthcare industry", J. Med. Eng. Technol, 40(4), pp.141~148 (2016)
  4. 정영, "Flexible Pressure Sensors Based on Three-dimensional Structure for High Sensitivity", 센서학회지, 31(3), pp.145~150 (2022), 한국센서학회
  5. C. K. Jeong, "A hyper-stretchable elastic-composite energy harvester", Adv Mater, 27(18), pp.2866~2875 (2015)
  6. H. -T. Deng, "Superstretchable multi-sensing triboelectric nanogenerator based on liquid conductive composite", Nano Energy, 83, pp.103948~ (2021)
  7. B. -U. Hwang, "A transparent stretchable sensor for distinguishable detection of touch and pressure by capacitive and piezoresistive signal transduction", NPG Asia Mater, 11(1), pp.1~12 (2019)
  8. G. -T. Hwang, "Selfpowered wireless sensor node enabled by an aerosol-deposited PZT flexible energy harvester", Adv Energy Mater, 6(13), pp.1600237~ (2016)
  9. S. S. Ham, "Kinetic motion sensors based on flexible and lead-free hybrid piezoelectric composite energy harvesters with nanowires-embedded electrodes for detecting articular movements", Composites Part B, 212, pp.108705~ (2021)
  10. S. Y. Lee, "Piezoelectric energy harvesting principles and materials", Polym. Sci. Technol, 31(6), pp.484~489 (2020)
  11. J. H. Han, "Dual-structured flexible piezoelectric film energy harvesters for effectively integrated performance", Sensors, 19(6), pp.1444~ (2019)
  12. C. K. Jeong, "Nanowire-percolated piezoelectric copolymer-based highly transparent and flexible self-powerd sensors", J. Mater. Chem. A, 7(44), pp.25481~25489 (2019)
  13. D. Y. Hyeon, "Piezoelectric flexible energy harvester based on BaTiO3 thin film enabled by exfoliating the Mica substrate", Energy Technol, 7(10), pp.1900638~ (2019)
  14. K. -I. Park, "Highly-efficient, flexible piezoelectric PZT thin film nanogenerator on plastic substrates", Adv. Mater, 26(16), pp.2514~2520 (2014)
  15. K. -I. Park, "Piezoelectric BaTiO3 thin film nanogenerator on plastic substrates", Nano Lett, 10(12), pp.4939~4943 (2010)
  16. 박성철, "비납계 BCTZ 압전세라믹과 압전폴리머로 제작된 하이브리드 나노복합체 기반의 플렉서블 에너지 하베스팅 소자", 전기전자재료학회논문지, 35(1), pp.72~79 (2022), 한국전기전자재료학회
  17. 권유정, "유기-무기 하이브리드 압전 나노복합체 기반의 플렉서블 에너지 하베스터 제작 및 발전성능 평가", 한국재료학회지, 29(6), pp.371~377 (2019), 한국재료학회[DOI]
  18. K. -I. Park, "Flexible nanocomposite generator made of batio3 nanoparticles and graphitic carbons", Adv. Mater, 24(22), pp.2999~3004 (2012)
  19. 이원재, "PDMS-Ecoflex 하이브리드 소재를 이용한 투명 신축성 기판의 기계적 및 광학적 특성", 마이크로전자 및 패키징학회지, 25(4), pp.129~135 (2018), 한국마이크로전자및패키징학회
  20. 현동열, "압전 및 비압전 폴리머와 BaTiO3 나노입자로 제조된 유-무기 압전 나노복합체의 발전성능 비교연구", 한국분말재료학회지, 26(2), pp.119~125 (2019), 한국분말재료학회[DOI]
  21. I. Pasuk, "Structural details of BaTiO3 Nanopowders deduced from the anisotropic XRD peak broadening", Nanomaterials, 11(5), pp.1121~ (2021)

관련 논문AI추천

이 간행물의 다른 논문 (12건)