Hf 도핑된 BaTiO3 나노입자 기반의 플렉서블 압전 소자 개발 및 특성평가
Development and Characterization of Hafnium-Doped BaTiO3 Nanoparticle-Based Flexible Piezoelectric Devices
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Energy harvesting technology that converts the wasted energy resources into electrical energy is emerging as a semipermanentpower source for self-powered electronics and wireless low-power sensor systems. Among the various energy conversiontechniques, flexible piezoelectric energy harvesters (f-PEHs), using materials with piezoelectric effects, have attractedsignificant interest because they can harvest a small mechanical energy into electrical signals without constraints of time andspace in various environments. In this study, we used a flexible piezoelectric composite film fabricated by dispersing BaHfxTi(1-x)O3 (x = 0, 0.01, 0.05, 0.1) piezoelectric powders inside a polymeric matrix to facilitate f-PEHs. The fabricated f-PEH withoptimal Hf contents (x = 0.05) generated a maximum output voltage of 0.95 V and current signal of 130 nA with stable electrical/mechanical disabilities under periodically bending deformations. In addition, we demonstrated a cantilever-type f-PEHand investigated its potential as a sensor by characterizing the output performance under mechanical vibrations at various frequencies. This study provides the breakthrough for realizing self-powered energy harvesting and sensing systems by adoptingthe lead-free piezoelectric composites under vibrational environments.
Abstract
Energy harvesting technology that converts the wasted energy resources into electrical energy is emerging as a semipermanentpower source for self-powered electronics and wireless low-power sensor systems. Among the various energy conversiontechniques, flexible piezoelectric energy harvesters (f-PEHs), using materials with piezoelectric effects, have attractedsignificant interest because they can harvest a small mechanical energy into electrical signals without constraints of time andspace in various environments. In this study, we used a flexible piezoelectric composite film fabricated by dispersing BaHfxTi(1-x)O3 (x = 0, 0.01, 0.05, 0.1) piezoelectric powders inside a polymeric matrix to facilitate f-PEHs. The fabricated f-PEH withoptimal Hf contents (x = 0.05) generated a maximum output voltage of 0.95 V and current signal of 130 nA with stable electrical/mechanical disabilities under periodically bending deformations. In addition, we demonstrated a cantilever-type f-PEHand investigated its potential as a sensor by characterizing the output performance under mechanical vibrations at various frequencies. This study provides the breakthrough for realizing self-powered energy harvesting and sensing systems by adoptingthe lead-free piezoelectric composites under vibrational environments.
참고문헌 (32)
- L. Swallow, "A piezoelectric fibre composite based energy harvesting device for potential wearable applications", Smart Mater Struct., 17(2), pp.025017~ (2008)
- Y. Wu, "Piezoelectric materials for flexible and wearable electronics : A review", Mater. Des., 211, pp.110164~ (2021)
- C. Zhang, "Recent progress of wearable piezoelectric nanogenerators", ACS Appl. Electron. Mater., 3(6), pp.2449~2467 (2021)
- R. Hesham, "Energy harvesting schemes for wearable devices", Int. J. Electron. Commun., 138, pp.153888~ (2021)
- K. I. Park, "Flexible nanocomposite generator made of BaTiO3 nanoparticles and graphitic carbons", Adv. Mater., 24(22), pp.2999~3004 (2012)
- K. -I. Park, "Piezoelectric BaTiO3 thin film nanogenerator on plastic substrates", Nano Lett., 10(12), pp.4939~4943 (2010)
- J. Lu, "A biodegradable and recyclable piezoelectric sensor based on a molecular ferroelectric embedded in a bacterial cellulose hydrogel", ACS Nano, 16(3), pp.3744~3755 (2022)
- N. Sezer, "A comprehensive review on the state-of-the-art of piezoelectric energy harvesting", Nano Energy, 80, pp.105567~ (2021)
- S. D. Mahapatra, "Piezoelectric materials for energy harvesting and sensing applications : Roadmap for future smart materials", Adv. Sci., 8(17), pp.2100864~ (2021)
- J. Wu, "Perovskite lead-free piezoelectric ceramics", J. Appl. Phys., 127(19), pp.190901~ (2020)
- K. I. Park, "Recent Progress in Flexible Energy Harvesting Devices based on Piezoelectric Nanomaterials", J. Kor. Powder Metall. Inst., 25(3), pp.263~272 (2018)
- M. Smith, "Piezoelectric polymers : Theory, challenges and opportunities", Int. Mater. Rev., 67(1), pp.65~88 (2022)
- G. H. Haertling, "Ferroelectric ceramics : history and technology", J. Am. Ceram. Soc., 82(4), pp.797~818 (1999)
- M. Habib, "A review of ceramic, polymer and composite piezoelectric materials", J. Phys. D Appl. Phys., 55(42), pp.423002~ (2022)
- N. Yan, "Piezoelectric ceramic for energy harvesting system : a review", ARPN J. Eng. Appl. Sci., 13(22), pp.8755~8775 (2018)
- A. Veved, "Review of emerging materials for PVDF-based energy harvesting", Energy Rep., 8, pp.12853~12870 (2022)
- S. Banerjee, "A critical review on lead-free hybrid materials for next generation piezoelectric energy harvesting and conversion", Ceram. Int., 47(12), pp.16402~16421 (2021)
- P. Panda, "PZT to lead free piezo ceramics : a review", Ferroelectrics, 474(1), pp.128~143 (2015)
- S. More, "The review of various synthesis methods of barium titanate with the enhanced dielectric properties", Proc. of International conference on condensed matter and applied physics (ICC 2015), pp.020560~ (2016)
- C. -T. Xia, "Preparation of BaTiO3 by the hydrothermal method", J. Eur. Ceram. Soc., 15(12), pp.1171~1176 (1995)
- W. Wang, "Low-temperature synthesis of BaTiO3 powders by the sol–gel-hydrothermal method", Ceram. Int., 39(6), pp.7127~7134 (2013)
- D. Y. Hyeon, "A Comparison Study of Output Performance of Organic-Inorganic Piezoelectric Nanocomposite Made of Piezoelectric", Non-piezoelectric Polymers and BaTiO3 Nanoparticles, 2019, pp.26(2), 119~125
- K. -I. Park, "Lead-free BaTiO 3 nanowires-based flexible nanocomposite generator", Nanoscale, 6(15), pp.8962~8968 (2014)
- S. C. Park, "Enhanced piezoelectric performance of composite fibers based on lead-free BCTZ ceramics and P (VDFTrFE) piezopolymer for self-powered wearable sensors", ACS Sustain. Chem. Eng., 10(43), pp.14370~14380 (2022)
- R. Mbarki, "Piezoelectricity above the Curie temperature? Combining flexoelectricity and functional grading to enable hightemperature electromechanical coupling", Appl. Phys. Lett., 104(12), pp.122904~ (2014)
- Y. Li, "Significant increase of Curie temperature in nano-scale BaTiO3", Appl. Phys. Lett., 105(18), pp.182901~ (2014)
- H. Tian, "Preparation and characterization of hafnium doped barium titanate ceramics", J. Alloys Compd., 431(1-2), pp.197~202 (2007)
- J. Chen, "Microstructures, dielectric and ferroelectric properties of BaHfxTi1-xO3 ceramics", J. Alloys Compd., 544, pp.82~86 (2012)
- J. Li, "Large room-temperature electrocaloric effect in lead-free BaHfxTi1-xO3 ceramics under low electric field", Acta Mater., 115, pp.58~67 (2016)
- A. K. Kalyani, "Orthorhombic-tetragonal phase coexistence and enhanced piezo-response at room temperature in Zr, Sn, and Hf modified BaTiO3", Appl. Phys. Lett., 104(25), pp.252906~ (2014)
- D. Hyeon, "High-temperature workable flexible piezoelectric energy harvester comprising thermally stable (K, Na) NbO3-based ceramic and polyimide composites", Compos. B Eng., 234, pp.109671~ (2022)
- S. Anwar, "Crossover from classical to relaxor ferroelectrics in BaTi1-xHfxO3 ceramics", J. Phys. Condens. Matter., 18(13), pp.3455~ (2006)
