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Hf 도핑된 BaTiO3 나노입자 기반의 플렉서블 압전 소자 개발 및 특성평가

Development and Characterization of Hafnium-Doped BaTiO3 Nanoparticle-Based Flexible Piezoelectric Devices

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초록

Energy harvesting technology that converts the wasted energy resources into electrical energy is emerging as a semipermanentpower source for self-powered electronics and wireless low-power sensor systems. Among the various energy conversiontechniques, flexible piezoelectric energy harvesters (f-PEHs), using materials with piezoelectric effects, have attractedsignificant interest because they can harvest a small mechanical energy into electrical signals without constraints of time andspace in various environments. In this study, we used a flexible piezoelectric composite film fabricated by dispersing BaHfxTi(1-x)O3 (x = 0, 0.01, 0.05, 0.1) piezoelectric powders inside a polymeric matrix to facilitate f-PEHs. The fabricated f-PEH withoptimal Hf contents (x = 0.05) generated a maximum output voltage of 0.95 V and current signal of 130 nA with stable electrical/mechanical disabilities under periodically bending deformations. In addition, we demonstrated a cantilever-type f-PEHand investigated its potential as a sensor by characterizing the output performance under mechanical vibrations at various frequencies. This study provides the breakthrough for realizing self-powered energy harvesting and sensing systems by adoptingthe lead-free piezoelectric composites under vibrational environments.

Abstract

Energy harvesting technology that converts the wasted energy resources into electrical energy is emerging as a semipermanentpower source for self-powered electronics and wireless low-power sensor systems. Among the various energy conversiontechniques, flexible piezoelectric energy harvesters (f-PEHs), using materials with piezoelectric effects, have attractedsignificant interest because they can harvest a small mechanical energy into electrical signals without constraints of time andspace in various environments. In this study, we used a flexible piezoelectric composite film fabricated by dispersing BaHfxTi(1-x)O3 (x = 0, 0.01, 0.05, 0.1) piezoelectric powders inside a polymeric matrix to facilitate f-PEHs. The fabricated f-PEH withoptimal Hf contents (x = 0.05) generated a maximum output voltage of 0.95 V and current signal of 130 nA with stable electrical/mechanical disabilities under periodically bending deformations. In addition, we demonstrated a cantilever-type f-PEHand investigated its potential as a sensor by characterizing the output performance under mechanical vibrations at various frequencies. This study provides the breakthrough for realizing self-powered energy harvesting and sensing systems by adoptingthe lead-free piezoelectric composites under vibrational environments.

참고문헌 (32)

  1. L. Swallow, "A piezoelectric fibre composite based energy harvesting device for potential wearable applications", Smart Mater Struct., 17(2), pp.025017~ (2008)
  2. Y. Wu, "Piezoelectric materials for flexible and wearable electronics : A review", Mater. Des., 211, pp.110164~ (2021)
  3. C. Zhang, "Recent progress of wearable piezoelectric nanogenerators", ACS Appl. Electron. Mater., 3(6), pp.2449~2467 (2021)
  4. R. Hesham, "Energy harvesting schemes for wearable devices", Int. J. Electron. Commun., 138, pp.153888~ (2021)
  5. K. I. Park, "Flexible nanocomposite generator made of BaTiO3 nanoparticles and graphitic carbons", Adv. Mater., 24(22), pp.2999~3004 (2012)
  6. K. -I. Park, "Piezoelectric BaTiO3 thin film nanogenerator on plastic substrates", Nano Lett., 10(12), pp.4939~4943 (2010)
  7. J. Lu, "A biodegradable and recyclable piezoelectric sensor based on a molecular ferroelectric embedded in a bacterial cellulose hydrogel", ACS Nano, 16(3), pp.3744~3755 (2022)
  8. N. Sezer, "A comprehensive review on the state-of-the-art of piezoelectric energy harvesting", Nano Energy, 80, pp.105567~ (2021)
  9. S. D. Mahapatra, "Piezoelectric materials for energy harvesting and sensing applications : Roadmap for future smart materials", Adv. Sci., 8(17), pp.2100864~ (2021)
  10. J. Wu, "Perovskite lead-free piezoelectric ceramics", J. Appl. Phys., 127(19), pp.190901~ (2020)
  11. K. I. Park, "Recent Progress in Flexible Energy Harvesting Devices based on Piezoelectric Nanomaterials", J. Kor. Powder Metall. Inst., 25(3), pp.263~272 (2018)
  12. M. Smith, "Piezoelectric polymers : Theory, challenges and opportunities", Int. Mater. Rev., 67(1), pp.65~88 (2022)
  13. G. H. Haertling, "Ferroelectric ceramics : history and technology", J. Am. Ceram. Soc., 82(4), pp.797~818 (1999)
  14. M. Habib, "A review of ceramic, polymer and composite piezoelectric materials", J. Phys. D Appl. Phys., 55(42), pp.423002~ (2022)
  15. N. Yan, "Piezoelectric ceramic for energy harvesting system : a review", ARPN J. Eng. Appl. Sci., 13(22), pp.8755~8775 (2018)
  16. A. Veved, "Review of emerging materials for PVDF-based energy harvesting", Energy Rep., 8, pp.12853~12870 (2022)
  17. S. Banerjee, "A critical review on lead-free hybrid materials for next generation piezoelectric energy harvesting and conversion", Ceram. Int., 47(12), pp.16402~16421 (2021)
  18. P. Panda, "PZT to lead free piezo ceramics : a review", Ferroelectrics, 474(1), pp.128~143 (2015)
  19. S. More, "The review of various synthesis methods of barium titanate with the enhanced dielectric properties", Proc. of International conference on condensed matter and applied physics (ICC 2015), pp.020560~ (2016)
  20. C. -T. Xia, "Preparation of BaTiO3 by the hydrothermal method", J. Eur. Ceram. Soc., 15(12), pp.1171~1176 (1995)
  21. W. Wang, "Low-temperature synthesis of BaTiO3 powders by the sol–gel-hydrothermal method", Ceram. Int., 39(6), pp.7127~7134 (2013)
  22. D. Y. Hyeon, "A Comparison Study of Output Performance of Organic-Inorganic Piezoelectric Nanocomposite Made of Piezoelectric", Non-piezoelectric Polymers and BaTiO3 Nanoparticles, 2019, pp.26(2), 119~125
  23. K. -I. Park, "Lead-free BaTiO 3 nanowires-based flexible nanocomposite generator", Nanoscale, 6(15), pp.8962~8968 (2014)
  24. S. C. Park, "Enhanced piezoelectric performance of composite fibers based on lead-free BCTZ ceramics and P (VDFTrFE) piezopolymer for self-powered wearable sensors", ACS Sustain. Chem. Eng., 10(43), pp.14370~14380 (2022)
  25. R. Mbarki, "Piezoelectricity above the Curie temperature? Combining flexoelectricity and functional grading to enable hightemperature electromechanical coupling", Appl. Phys. Lett., 104(12), pp.122904~ (2014)
  26. Y. Li, "Significant increase of Curie temperature in nano-scale BaTiO3", Appl. Phys. Lett., 105(18), pp.182901~ (2014)
  27. H. Tian, "Preparation and characterization of hafnium doped barium titanate ceramics", J. Alloys Compd., 431(1-2), pp.197~202 (2007)
  28. J. Chen, "Microstructures, dielectric and ferroelectric properties of BaHfxTi1-xO3 ceramics", J. Alloys Compd., 544, pp.82~86 (2012)
  29. J. Li, "Large room-temperature electrocaloric effect in lead-free BaHfxTi1-xO3 ceramics under low electric field", Acta Mater., 115, pp.58~67 (2016)
  30. A. K. Kalyani, "Orthorhombic-tetragonal phase coexistence and enhanced piezo-response at room temperature in Zr, Sn, and Hf modified BaTiO3", Appl. Phys. Lett., 104(25), pp.252906~ (2014)
  31. D. Hyeon, "High-temperature workable flexible piezoelectric energy harvester comprising thermally stable (K, Na) NbO3-based ceramic and polyimide composites", Compos. B Eng., 234, pp.109671~ (2022)
  32. S. Anwar, "Crossover from classical to relaxor ferroelectrics in BaTi1-xHfxO3 ceramics", J. Phys. Condens. Matter., 18(13), pp.3455~ (2006)

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