본문 바로가기
KERD
논문KCI 등재

담지 방법을 통해 유리 기판 위에 형성된 탄소나노튜브 네트워크의 전기적 및 광학적 특성

Electrical and Optical Properties of Carbon Nanotube Networks Formed on Glass Substrate by Dip-Coating Method

0

조회

0

다운로드

0

인용

0

참고문헌

키워드

주제분류재료공학

초록

The cure behavior of epoxy resin with a conventional amide-type hardener(HD) was investigated in the presence of castor oil(CO), cashew nut shell liquid(CNSL) and CNSL-formaldehyde resin(CFR) by using a dynamic differential scanning calorimetry(DSC). The activation energy of curing reaction was also calculated based on the non-isothermal DSC thermograms at various heating rates. An one-stage curing was noted in the case of epoxy resin filled with CO, while the epoxy resin with CNSL and CFR showed a two-stage curing process. A competitive cure reaction was noted for the epoxy resin/CNSL(or CFR)/HD blends. In the absence of HD, the CFR showed lower values of curing enthalpy than that of CNSL. The activation energy of epoxy resin curing increased with increasing the CNSL and CFR loading.

Abstract

The cure behavior of epoxy resin with a conventional amide-type hardener(HD) was investigated in the presence of castor oil(CO), cashew nut shell liquid(CNSL) and CNSL-formaldehyde resin(CFR) by using a dynamic differential scanning calorimetry(DSC). The activation energy of curing reaction was also calculated based on the non-isothermal DSC thermograms at various heating rates. An one-stage curing was noted in the case of epoxy resin filled with CO, while the epoxy resin with CNSL and CFR showed a two-stage curing process. A competitive cure reaction was noted for the epoxy resin/CNSL(or CFR)/HD blends. In the absence of HD, the CFR showed lower values of curing enthalpy than that of CNSL. The activation energy of epoxy resin curing increased with increasing the CNSL and CFR loading.

참고문헌 (22)

  1. J. Hone, "Thermal properties of carbon nanotubes and nanotube-based materials", Appl. Phys. A: Mater. Sci. Process, 74, pp.339~343 (2002)
  2. A. Krishnan, "Young’s modulus of single-walled nanotubes", Phys. Rev. B, 58, pp.14013~14019 (1998)
  3. B.G. Demczyk, "Direct mechanical measurement of the tensile strength and elastic modulus of multi-walled carbon nanotubes", Mater. Sci. Eng. A, 334, pp.173~178 (2002)
  4. B.Q. Wei, "Reliability and current carrying capacity of carbon nanotubes", Appl. Phys. Lett, 79, pp.1172~1174 (2001)
  5. T. Durkop, "Extraordinary mobility in semiconducting carbon nanotubes", Nano Lett, 4, pp.35~39 (2004)
  6. C.T. White, "Carbon nanotubes as long ballistic conductors", Nature, 393, pp.240~242 (1998)
  7. Z. W, "Transparent, conductive carbon nanotube films", Science, 305, pp.1273~1276 (2004)
  8. G. Grüner, "Carbon nanotube films for transparent and plastic electronics", J. Mater. Chem, 16, pp.3533~3539 (2006)
  9. Y. Zhou, "A method of printing carbon nanotube thin films", Appl. Phys. Lett, 88, pp.123109(1)~123109(3) (2006)
  10. D. S. Hecht, "Conductivity scaling with bundle length and diameter in single walled carbon nanotube networks", Appl. Phys. Lett, 89, pp.133112(1)~133112(3) (2006)
  11. L. Hu, "Percolation in transparentand conducting carbon nanotube networks", Nano Lett, 4, pp.2513~2517 (2004)
  12. M. Meitl, "Solution Casting and Transfer Printing Single-Walled Carbon Nanotube Films", J. Nano Lett, 4, pp.1643~1647 (2004)
  13. S. Soliveres, "1", f noise and percolation in carbon nanotube random networks, 2007, pp.90, 082107(1)~082107(3)
  14. M. Kaempgen, "Transparent carbon nanotube coatings", Appl. Surf. Sci, 252, pp.425~429 (2005)
  15. Y. Kim, "Langmuir–Blodgett Films of Single-Wall Carbon Nanotubes: Layer-by-layer Deposition and In-plane Orientation of Tubes", Jpn. J. Appl. Phys, 42, pp.7629~7634 (2003)
  16. J. Liu, "Fullerene pipes", Science, 280, pp.1253~1256 (1998)
  17. M. A. Hamon, "Dissolution of single-walled carbon nanotubes", Adv. Mater, 11, pp.834~840 (1999)
  18. S. B. Fagan, "1,2-dichlorobenzene interacting with carbon nanotubes", Nano Lett, 4, pp.1285~1288 (2004)
  19. J. Bahr, "Dissolution of small diameter single-wall carbon nanotubes in organic solvents?", Chem. Commun, pp.193~194 (2001)
  20. S. G. Rao, "Large-scale assembly of carbon nanotubes", Nature, 425, pp.36~37 (2003)
  21. F. Borondics, "Charge dynamics in transparent single-walled carbon nanotube films from optical transmission measurements", Phys. Rev. B, 74, pp.045431(1)~045431(6) (2006)
  22. R. Krupke, "Separation of metallic from semiconducting single-walled carbon nanotubes", Science, 301, pp.344~347 (2003)

관련 논문AI추천

이 간행물의 다른 논문 (5건)