본문 바로가기
KERD
논문KCI 등재

탄소 강화 탄소나노튜브 섬유 복합소재 연구 동향

A review of Carbon-Reinforced Carbon Nanotube Fibers Composites

구본철|이동주|류성우
한국복합재료학회 (The Korean Society For Composite Materials)|2019.06|Composites Research|제32권 제3호|pp. 127-133|DOI http://dx.doi.org/10.7234/composres.2019.32.3.127

2

조회

0

다운로드

2

인용

0

참고문헌

키워드

PolydopamineMechanical strengthElectrical conductivity전기전도도Polyacrylonitrile폴리아크릴로니트릴탄소나노튜브 섬유탄소강화 복합재료기계적강도폴리도파민Carbon nanotube fibersCarbon-reinforced composites
주제분류재료공학

초록

탄소나노튜브는 이론적인 기계적, 전기적 물성이 우수함에도 불구하고 아직까지 그 수준에 도달하고 있지 않다. 특히나 인장 강도는 10% 미만의 수준 정도에 그치고 있어 이를 보안하기 위한 연구가 활발히 진행되고 있다. 기계적 강도를 향상하기 위한 방법으로는 긴 탄소나노튜브의 합성, 배향 외에 화학적 가교, 수소결합, 고분자 함침 등의 방법이 연구되고 있다. 본 총설 논문에서는 탄소소재의 전구체인 폴리아크릴로니트릴(PAN), 폴리도파민(PDA)을 탄소나노튜브 섬유에 코팅 또는 함침하여 탄화 공정을 거쳐 고강도 고전도성 탄소나노튜브 섬유/탄소 복합소재를 제조하는 연구를 소개하고자 한다.

Abstract

Although carbon nanotubes(CNTs) have outstanding theoretical mechanical and electrical properties, CNT fibers(CNTFs) have not yet reached that level. Particularly, tensile strength is only about 10% or less, so studies for making up for it are being actively conducted. As a way for improving mechanical strength, methods such as synthesizing long CNT, orientation, chemical crosslinking, hydrogen bonding and polymer infiltration are being studied. In this review paper, we report preparation methods for highly conductive and strong CNTF/Carbon composites through coating and infiltration followed by carbonization of carbon precursor polymers such as polyacrylonitrile (PAN) and polydopamine (PDA) on CNTFs.

참고문헌 (48)

  1. Ian, A. K., "Composites with Carbon Nanotubes and Graphene : An Outlook", Science, 362(6414), pp.547~553 (2018)
  2. Sobia, I., "A Review Featuring Fabrication, Properties and Applications of Carbon Nanotubes(CNTs)Reinforced Polymer and Epoxy Nanocomposites", Nature, 358, pp.220~222 (1992)
  3. Brigitte, V., "Macroscopic Fibers and Ribbons of Oriented Carbon Nanotubes", Science, 290(5495), pp.1331~1334 (2000)
  4. Lars, M. E., "Macroscopic, Neat, Single-Walled Carbon Nanotube Fibers", Science, 305, pp.1447~1450 (2004)
  5. Mei, Z., "Multifunctional Carbon Nanotube Yarns by Downsizing an Ancient Technology", Science, 306, pp.1358~1361 (2004)
  6. Li, Y. L., "Direct Spinning of Carbon Nanotube Fibers from Chemical Vapor Deposition Synthesis", Science, 304, pp.276~278 (2004)
  7. Natnael B., "Strong, Light, Multifunctional Fibers of Carbon Nanotubes with Ultrahigh Conductivity", Science, 339, pp.182~186 (2013)
  8. Krzysztof, K., "High-Performance Carbon Nanotube Fiber", Science, 318, pp.1892~1895 (2007)
  9. Manishkumar, D. Y., "High Performance Fibers from Carbon Nanotubes : Synthesis, Characterization and Applications in Composites-A Review", Industrial and Engineering Chemistry Research, 56(44), pp.12407~12437 (2017)
  10. Jiangtao, D., "Carbon‐Nanotube Fibers for Wearable Devices and Smart Textiles", Advanced Materials, 28(47), pp.10529~10538 (2016)
  11. Weibang, L., "State of the Art of Carbon Nanotube Fibers : Opportunities and Challenges", Advanced Materials, 24(14), pp.1805~1833 (2012)
  12. Hungo Choo, "Fabrication and Applications of Carbon Nanotube Fibers", Carbon Letters, 13(4), pp.191~204 (2012), 한국탄소학회[DOI]
  13. 최용문, "Advances in liquid crystalline nano-carbon materials: preparation of nano-carbon based lyotropic liquid crystal and their fabrication of nano-carbon fibers with liquid crystalline spinning", Carbon Letters, 16(4), pp.223~232 (2015), 한국탄소학회
  14. Enlai, G., "Strength Loss of Carbon Nanotube Fibers Explained in a Three-level Hierarchical Model", Carbon, 138, pp.134~142 (2018)
  15. Im, Y. O., "Utilization of Carboxylic Functional Groups Generated during Purification of Carbon Nanotube Fiber for Its Strength Improvement", Applied Surface Science, 392, pp.342~349 (2017)
  16. Park, O. K., "Effect of Oxygen Plasma Treatment on the Mechanical Properties of Carbon Nanotube Fibers", Material Letters, 156, pp.17~20 (2015)
  17. Yunxiang, G., "Direct Intertube Cross-Linking of Carbon Nanotubes at Room Temperature", Nano Letters, 16(10), pp.6541~6547 (2016)
  18. Slawomir, B., "Enhancement of the Mechanical Properties of Directly Spun CNT Fibers by Chemical Treatment", ACS Nano, 5(12), pp.9339~9344 (2011)
  19. Park, O. K., "High-modulus and Strength Carbon Nanotube Fibers Using Molecular Cross-linking", Carbon, 118, pp.413~421 (2017)
  20. Park, O. K., "Mechanical and Electrical Properties of Thermochemically Cross-linked Polymer Carbon Nanotube Fibers", Composites Part A, 91, pp.222~228 (2016)
  21. Kim, H. J., "Mechanical and Electrical Properties of Carbon Nanotube Fibers from Impregnation with Poly(vinyl alcohol)", Poly(acrylic acid)and Subsequent Thermal Condensation, 2018, pp.39(3), 971~977
  22. Xinyi, L., "Improving Mechanical Properties of Carbon Nanotube Fibers Through Simultaneous Solid-state Cycloaddition and Crosslinking", Nanotechnology, 28(14), pp.145603~145612 (2017)
  23. Cho, H., "Effects of Wet-Pressing and Cross-Linking on the Tensile Properties of Carbon Nanotube Fibers", Materials, 11(11), pp.2170~2181 (2018)
  24. Nam, K. H., "Photoacoustic Effect on the Electrical and Mechanical Properties of Polymer-infiltrated Carbon Nanotube Fiber", graphene Oxide Composites, 2017, pp.153, 136~144
  25. Shan, L., "Enhancement of Carbon Nanotube Fibres Using Different Solvents and Polymers", Composites Science and Technology, 72(12), pp.1402~1407 (2012)
  26. Xia, L., "Self-densified Microstructure and Enhanced Properties of Carbon Nanotube Fiber by Infiltrating Polymer", Carbon, 106, pp.188~194 (2016)
  27. Jialin, L., "Strengthening Carbon Nanotube Fibers with Semi-crystallized Polyvinyl Alcohol and Hot-stretching", Composite Science and Technology, 164, pp.290~295 (2018)
  28. Pirlot, C., "Preparation and Characterization of Carbon Nanotube", Polyacrylonitrile Composites, 2002, pp.4(3), 109~114
  29. Biao, W., "Rheological Behavior of Spinning Dope of Multiwalled Carbon Nanotube", Polyacrylonitrile Composites, 2004, pp.216(1), 189~194
  30. Lee, J., "Highstrength Carbon Nanotube", carbon Composite Fibers via Chemical Vapor Infiltration, 2016, pp.8(45), 18972~18979
  31. Ryu, S. W., "High‐Strength Carbon Nanotube Fibers Fabricated by Infiltration and Curing of Mussel‐Inspired Catecholamine Polymer", Advanced Materials, 23(17), pp.1971~1975 (2011)
  32. Jeong, Y.G., "Method for Preparing Carbon Nanotube Fiber Reinforced wtih Carbon Precursor", US Patent, 2015
  33. Park, O.K., "Effects of Functional Group of Carbon Nanotubes on Mechanical Properties of Carbon Fibers", Composites Part B: Engineering, 76, pp.159~166 (2015)
  34. Chae, H. G., "High Strength and High Modulus Carbon Fibers", Carbon, 93, pp.81~87 (2015)
  35. Lee, H. S., "Mussel-Inspired Surface Chemistry for Multifunctional Coatings", Science, 318, pp.426~430 (2007)
  36. Lee, H. S., "Polydopamine Surface Chemistry : A Decade of Discovery", ACS Applied Materials Interfaces, 10, pp.7523~7540 (2018)
  37. Ryu, S. W., "Direct Insulation-to-Conduction Transformation of Adhesive Catecholamine for Simultaneous Increases of Electrical Conductivity and Mechanical Strength of CNT Fibers", Advanced Materials, 27, pp.3250~3255 (2015)
  38. Sijie, W., "Strong, Conductive, Foldable Graphene Sheets by Sequential Ionic and π Bridging", Advanced Materials, 30(36), pp.1802733~ (2018)
  39. Yuanyuan, Z., "Bioinspired Supertough Graphene Fiber through Sequential Interfacial Interactions", ACS Nano, 12(9), pp.8901~8908 (2018)
  40. Kim, H., "Highstrength Graphene and Polyacrylonitrile Composite Fiber Enhanced by Surface Coating with Polydopamine", Composites Science and Technology, 149(8), pp.280~285 (2017)
  41. Songlin, Z., "Carbon Nanotube", carbon Composite Fiber with Improved Strength and Electrical Conductivity via Interface Engineering, 2019, pp.144, 628~638
  42. Zhou, Z., "Mechanical and Electrical Properties of Aligned Carbon Nanotube", carbon Matrix Composites, 2014, pp.75, 307~313
  43. Thiagarajan, V., "Stabilizing Carbon Nanotube Yarns Using Chemical Vapor Infiltration", Composite Science and Technology, 90(10), pp.82~87 (2014)
  44. Xiaoyang, L., "Epitaxial Growth of Aligned and Continuous Carbon Nanofibers from Carbon Nanotubes", ACS Nano, 11(2), pp.1257~1263 (2017)
  45. Wei, H., "Polydopamine as Sizing on Carbon Fiber Surfaces for Enhancement of Epoxy Laminated Composites", Composites Part A, 107, pp.626~632 (2018)
  46. Tao, M., "A Bioinspired Interface Design for Improving the Strength and Electrical Conductivity of Graphene-Based Fibers", Advanced Materials, 30(15), pp.1706435~ (2018)
  47. Kim, I. H., "Mussel-Inspired Defect Engineering of Graphene Liquid Crystalline Fibers for Synergistic Enhancement of Mechanical Strength and Electrical Conductivity", Advanced Materials, 30(40), pp.1803267~ (2018)
  48. Kim, Y. J., "Simultaneous Enhancement of Mechanical and Electrical Properties of Carbon Nanotube Fiber by Infiltration and Subsequent Carbonization of Resorcinol-formaldehyde Resin", Composite Part B, 163, pp.431~437 (2019)

관련 논문AI추천

나노탄소 고분자 복합재료최철림한국복합재료학회 · Composites Research2013 · 제26권 제3호직접 방사법으로 합성된 탄소나노튜브 섬유의 기계적 특성 향상곽이구, 김승민, 김진석, 박준범, 황준연한국복합재료학회 · Composites Research2015 · 제28권 제4호난연성 폴리아크릴로니트릴 고분자 섬유 및 복합소재 연구 동향구본철, 김종호한국복합재료학회 · Composites Research2019 · 제32권 제6호탄소나노튜브로 보강된 탄소섬유복합재의 제조 공정과 모드 1 파괴인성김한상한국복합재료학회 · Composites Research2011 · 제24권 제5호카본나노튜브를 이용한 고성능 나노복합재료의 개발 동향박종규, 배수빈, 이민경, 이승걸한국염색가공학회 · 한국염색가공학회지2014 · 제26권 제2호탄소나노튜브로 표면처리 된 탄소섬유/에폭시 수지 복합재료의기계적 특성 연구김양도, 이규환, 임동찬, 홍은미한국표면공학회 · 한국표면공학회지2013 · 제46권 제5호

이 간행물의 다른 논문 (5건)

염석법을 이용한 비공유 기능기화된 그래핀 나노플레이트렛의 분리 공정 연구류호진, 차재민, 홍순형, 김준희, 유승찬pp. 134-140Cold Compaction behavior of nano and micro aluminum powder under high박광재, 김경주, 조승찬, 권한상, 김다솜, Yusuke hirayama, Kenta Takagipp. 141-147탄화규소섬유와 탄소섬유 하이브리드 직물을 강화재로 한 SiC 매트릭스 세라믹복합재의 기계적물성, 산화 및 삭마 저항성 개선 연구권향주, 김명주, 김정일, 김재성, 윤성태, 윤병일pp. 148-157용융가압함침 공정으로 제조된 고체적률 TiC–Inconel 718 금속복합재료의 미세조직 및 특성이상복, 신상민, 이영환, 이동현, 고성민, 조일국, 이상관, 조승찬, 박현재pp. 158-162무정형 열가소성 고분자의 자유 라디칼 중합 분자동역학 시뮬레이션 알고리즘윤군진, 정지원, 박찬욱pp. 163-169
원문 보기