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난연성 폴리아크릴로니트릴 고분자 섬유 및 복합소재 연구 동향

A Review of Flame Retarding Polyacrylonitrile (PAN) Fibers and Composites

구본철|김종호
한국복합재료학회 (The Korean Society For Composite Materials)|2019.12|Composites Research|제32권 제6호|pp. 342-348

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참고문헌

키워드

Stabilization난연성안정화Flame Retardant폴리아크릴로니트릴유/무기 복합재료한계산소지수Polyacrylonitrile (PAN)Organic/Inorganic Composite MaterialsLimiting Oxygen Index
주제분류재료공학

초록

고분자 재료의 사용이 늘어남에 따라 난연성 고분자 재료에 대한 연구가 더욱 활발히 진행되고 있다. 고분자 재료의 난연성 향상을 위한 방법으로 제조된 섬유의 후처리 또는 섬유내 난연제의 도입에 관한 연구가 진행되고 있다. 많은 고분자들 중 탄소섬유 전구체인 폴리아크릴로니트릴(PAN)은 의류용으로도 많이 사용되고 있어서 낮은 난연성을 지닌 PAN으로 이루어진 소재의 난연성 향상이 절실히 요구되고 있다. 본 총설 논문에서는 PAN 섬유의 후처리(안정화 또는 화학반응)을 통한 난연성 PAN 섬유와, 유/무기 소재(실리카, 2차원 소재, 탄소나노튜브)과 함께 혼합하여 섬유로 제조하는 난연성 PAN 복합소재의 제조에 대한 연구를 소개하고자 한다.

Abstract

Development of flame retarding polymer based materials has been studied actively due to the increase in use of polymers. The post treatment of manufactured fibers or the introduction of flame retardant into fibers is representative method for the way to improve the flame retardancy. Among the polymers, polyacrylonitrile (PAN), which is a precursor of carbon fiber, has been widely used for clothes. Due to low flame retardancy of PAN fiber (LOI value: 17~18%), the improvement of flame retardancy of PAN fiber is needed. In this review paper, we report preparation methods for the fabrication of post-treated (oxidization or chemical reaction) flame-retarding PAN fibers and composites composed of PAN and organic/inorganic materials (SiO2, 2D materials or CNT)

참고문헌 (56)

  1. Lu, S. Y., "Recent Developments in the Chemistry of Halogen-Free Flame Retardant Polymers", Progress in Polymer Science, 27(8), pp.1661~1712 (2002)
  2. Willard, J. J., "Quantitative Evaluation of Flame-Retardant Cotton Finishes by the Limiting-Oxygen Index(LOI)Technique", Textile Research Journal, 40(3), pp.203~210 (1970)
  3. Yu, Z. ‐Z., "Impact Fracture Morphology of Nylon 6 Toughened with a Maleated Polyethylene–Octene Elastomer", Journal of Applied Polymer Science, 76(6), pp.1285~1295 (2000)
  4. FÁvila, A., "A Mechanical Analysis on Recycled PET", HDPE Composites, 2003, pp.80(2), 373~382
  5. Iwata, T., "Biodegradable and Bio-Based Polymers: Future Prospects of Eco-Friendly Plastics", Angewandte Chemie International Edition, 54(11), pp.3210~3215 (2015)
  6. Leu, T. -S., "Synergistic Effect of a Phosphorus–Nitrogen Flame Retardant on Engineering Plastics", Journal of Applied Polymer Science, 92(1), pp.410~417 (2004)
  7. Xu, S., "Layered Double Hydroxides used as Flame Retardant for Engineering Plastic Acrylonitrile–Butadiene–Styrene(ABS)", Journal of Physics and Chemistry of Solids, 73(12), pp.1514~1517 (2012)
  8. Levchik, S. V., "New Halogen-Free Fire Retardant for Engineering Plastic Applications", Journal of Vinyl and Additive Technology, 7(2), pp.98~103 (2001)
  9. Hu, Y., "Preparation and Combustion Properties of Flame Retardant Nylon 6", Montmorillonite Nanocomposite, 2003, pp.288(3), 272~276
  10. Blum, A., "The Fire Retardant Dilemma", Science, 318(5848), pp.194~195 (2007)
  11. Kennedy, D., "Toxic Dilemmas", Science, 318(5854), pp.1217~ (2007)
  12. Ravichandran, S., "Halogen-Free Ultra-High Flame Retardant Polymers through Enzyme Catalysis", Green Chemistry, 14(3), pp.819~824 (2017)
  13. Ranganthan, T., "Poly(Arylate‐Phosphonate)Copolymers with Deoxybenzoin in the Backbone : Synthesis, Characterization, and Thermal Properties", Journal of Polymer Science Part A : Polymer Chemistry, 45(20), pp.4573~4580 (2017)
  14. Moon, S. C., "Flame Resistant Electrospun Polymer Nanofibers from Deoxybenzoin‐based Polymers", Journal of Applied Polymer Science, 111(1), pp.301~307 (2009)
  15. Yang, H., "Surface-Coating Engineering for Flame Retardant Flexible Polyurethane Foams a Critical Review", Composites Part B, 176, pp.107185~ (2019)
  16. Lee, S., "Structural Evolution of Polyacrylonitrile Fibers in Stabilization and Carbonization", Advances in Chemical Engineering and Science, 2(2), pp.275~282 (2012)
  17. Rahaman, M. S. A., "A Review of Heat Treatment on Polyacrylonitrile Fiber", Polymer Degradation and Stability, 92(8), pp.1421~1432 (2007)
  18. Fu, Z., "Study on the Thermal Oxidative Stabilization Reactions and the Formed Structures in Polyacrylonitrile during Thermal Treatment", Polymer Degradation and Stability, 140, pp.104~113 (2017)
  19. Arbab, S., "A Procedure for Precise Determination of Thermal Stabilization Reactions in Carbon Fiber Precursors", Polymer Degradation and Stability, 98, pp.2537~2545 (2013)
  20. 이현재, "PAN계 탄소섬유의 제조 및 탄화 조건에 따른 특성 분석", 한국섬유공학회지, 53(2), pp.103~108 (2016), 한국섬유공학회
  21. Xue, Y., "Correlative Study of Critical Reactions in Polyacrylonitrile Based Carbon Fiber Precursors during Thermal-Oxidative Stabilization", Polymer Degradation and Stability, 98, pp.219~229 (2013)
  22. Hall, M. E., "The Flammability of Polyacryionitrile and Its Copolymers", Polymer Degradation and Stability, 44(3), pp.379~386 (1994)
  23. Arbab, S., "Quantitative Analysis of the Effects of Comonomers and Heating Conditions on the Stabilization Reactions of Polyacrylonitrile Fibers as Carbon Fiber Precursors", Polymer Degradation and Stability, 139, pp.107~116 (2017)
  24. Park, O. K., "Effect of Functional Groups of Carbon Nanotubes on the Cyclization Mechanism of Polyacrylonitrile (PAN)", Polymer, 53(11), pp.2169~2174 (2012)
  25. 이재혁, "Melt processable polyacrylonitrile copolymer precursors for carbon fibers: Rheological, thermal, and mechanical properties", Journal of Industrial and Engineering Chemistry, 71, pp.112~118 (2019), 한국공업화학회[DOI]
  26. Fu, Z., "Structure Evolution and Mechanism of Polyacrylonitrile and Related Copolymers during the Stabilization", Journal of Materials Science, 49(7), pp.2864~2874 (2014)
  27. Ju, A., "Mechanism and Kinetics of Stabilization Reactions of Poly(acrylonitrile-co-β-methylhydrogen itaconate)", Journal of Materials Research, 27(20), pp.2668~2676 (2012)
  28. Nguyen-Thai, N. U., "Structural Evolution of Poly(acrylonitrile-co-itaconic acid)during Thermal Oxidative Stabilization for Carbon Materials", Macromolecules, 46(15), pp.5882~5889 (2013)
  29. Nguyen-Thai, N. U., "Controlled Architectures of Poly(acrylonitrile-co-itaconic acid)for Efficient Structural Transformation into Carbon Materials", Carbon, 69, pp.571~581 (2014)
  30. Ghorpade, R. V., "Effect of Controlled Tacticity of Polyacrylonitrile(co)Polymers on their Thermal Oxidative Stabilization Behaviors and the Properties of Resulting Carbon Films", Carbon, 121, pp.502~511 (2017)
  31. Hobbs, C. E., "Recent Advances in Bio-Based Flame Retardant Additives for Synthetic Polymeric Materials", Polymers, 11(2), pp.224~ (2019)
  32. Cho, J. H., "Bioinspired Catecholic Flame Retardant Nanocoating for Flexible Polyurethane Foams", Chemistry of Materials, 27(19), pp.6784~6790 (2015)
  33. Kim, H., "Polydopamine-Graphene Oxide Flame Retardant Nanocoatings Applied via an Aqueous Liquid Crystalline Scaffold", Advanced Functional Materials, 28(39), pp.1803172~ (2018)
  34. Nam, K. -H., "Highly Efficient Thermal Oxidation and Cross-Linking Reaction of Catechol Functionalized Polyacrylonitrile Copolymer Composites for Halogen-Free Flame Retardant", Composites Part B, 184, pp.107687~ (2020)
  35. Sayed, U., "Oxidised Polyacrylonitrile Fibre as a Flame Retardant Material", International Journal of Advanced Science and Engineering, 2(3), pp.155~158 (2016)
  39. Ren, Y., "Durable Flame Retardant Polyacrylonitrile Fabric via UV-Induced Grafting Polymerization and Surface Chemical Modification", RSC Advances, 8(72), pp.41389~41396 (2018)
  40. Ren, Y., "Preparation of Phosphorus‐containing and Nitrogen‐containing durable Flame Retardant Polyacrylonitrile Fabric via Surface Chemical Modification", Fire and Materials, 42(8), pp.925~932 (2018)
  41. Zhang, Y., "Preparation of Durable Flame Retardant PAN Fabrics based on Amidoximation and Phosphorylation", Applied Surface Science, 428, pp.395~403 (2018)
  42. Ren, Y., "UV-induced Surface Grafting Polymerization for Preparing Phosphoruscontaining Flame Retardant Polyacrylonitrile Fabric", European Polymer Journal, 94, pp.1~10 (2017)
  43. Ren, Y., "Polyvinyl Alcohol reinforced Flame-Retardant Polyacrylonitrile Composite Fiber prepared by Boric Acid Cross-Linking and Phosphorylation", Materials, 11(12), pp.2391~ (2018)
  44. Wu, Q., "A Novel and Facile Strategy for Highly Flame Retardant Polymer Foam Composite Materials : Transforming Silicone Resin Coating into Silica Self-Extinguishing Layer", Journal of Hazardous Materials, 336, pp.222~231 (2017)
  45. Kim, Y. G., "Thermally Insulating, Fire-Retardant, Smokeless and Flexible Polyvinylidene Fluoride Nanofibers filled with Silica Aerogels", Chemical Engineering Journal, 351, pp.473~481 (2018)
  46. Xu, W., "Zeolitic Imidazolate Framework-8 Was Coated with Silica and Investigated as a Flame Retardant to Improve the Flame Retardancy and Smoke Suppression of Epoxy Resin", RSC Advances, 8(5), pp.2575~2585 (2018)
  47. Ren, Y., "Flame Retardant Polyacrylonitrile Fabrics prepared by Organic-Inorganic Hybrid Silica Coating via Sol-gel Technique", Progress in Organic Coatings, 112, pp.225~233 (2017)
  48. Jiang, S. -D., "Surface Functionalization of MoS2 with POSS for Enhancing Thermal, Flame-Retardant and Mechanical Properties in PVA Composites", RSC Advances, 4(7), pp.3253~3262 (2014)
  49. Chen, H. -B., "Flammability of Polymer", Clay Aerogel Composites : An Overview, 2019, pp.59(1), 1~24
  50. Kiliaris, P., "Polymer", Layered Silicate(Clay)Nanocomposites : An Overview of Flame Retardancy, 2010, pp.35(7), 902~958
  51. Yang, Z. -W., "PGS@B–N: An Efficient Flame Retardant to Improve Simultaneously the Interfacial Interaction and the Flame Retardancy of EVA", RSC Advances, 6(70), pp.65921~65929 (2016)
  52. Snag, B., "Graphene-based Flame Retardants : A Review", Journal of Materials Science, 51(18), pp.8271~8295 (2016)
  53. Lee, S., "Synthesis and Properties of Thermally Reduced Graphene Oxide", Polyacrylonitrile Composites, 2012, pp.73(6), 741~743
  54. Yuan, B., "The Effects of Graphene on The Flammability and Fire Behavior of Intumescent Flame Retardant Polypropylene Composites at Different Flame Scenarios", Polymer Degradation and Stability, 143, pp.42~56 (2017)
  55. Peng, H., "NP-Zn-containing 2D Supermolecular Networks grown on MoS2Nanosheets for Mechanical and Flame-Retardant Reinforcements of Polyacrylonitrile Fiber", Chemical Engineering Journal, 372, pp.873~885 (2019)
  56. Moon, S., "High Flame Resistant and Strong Electrospun Polyacrylonitrile–Carbon Nanotubes–Ochre Nanofibers", Polymer, 54(7), pp.1813~1819 (2013)

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