헥사메틸렌테트라민 농도에 따른 수산화니켈 입자의 특성 분석 및 의사커패시터 응용
The Effects of Hexamethylenetetramine Concentration on the Structural and Electrochemical Performances of Ni(OH)2 Powder for Pseudocapacitor Applications
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Ni hydroxides (Ni(OH)2) are synthesized on Ni foam by varying the hexamethylenetetramine (HMT) concentration using an electrodeposition process for pseudocapacitor (PC) applications. In addition, the effects of HMT concentration on the Ni(OH)2 structure and the electrochemical properties of the PCs are investigated. HMT is the source of amine-based OH− in the solution; thus, the growth rate and morphological structure of Ni(OH)2 are influenced by HMT concentration. When Ni(OH)2 is electrodeposited at a constant voltage mode of -0.85 V vs. Ag/AgCl, the cathodic current and the number of nucleations are significantly reduced with increasing concentration of HMT from 0 to 10 mM. Therefore, Ni(OH)2 is sparsely formed on the Ni foam with increasing HMT concentration, showing a layered double-hydroxide structure. However, loosely packed Ni(OH)2 grains that are spread on Ni foam maintain a much greater surface area for reaction and result in the effective utilization of the electrode material due to the steric hindrance effect. It is suggested that the Ni(OH)2 electrodes with HMT concentration of 7.5 mM have the maximum specific capacitance (1023 F/g), which is attributed to the facile electrolyte penetration and fast proton exchange via optimized surface areas.
Abstract
Ni hydroxides (Ni(OH)2) are synthesized on Ni foam by varying the hexamethylenetetramine (HMT) concentration using an electrodeposition process for pseudocapacitor (PC) applications. In addition, the effects of HMT concentration on the Ni(OH)2 structure and the electrochemical properties of the PCs are investigated. HMT is the source of amine-based OH− in the solution; thus, the growth rate and morphological structure of Ni(OH)2 are influenced by HMT concentration. When Ni(OH)2 is electrodeposited at a constant voltage mode of -0.85 V vs. Ag/AgCl, the cathodic current and the number of nucleations are significantly reduced with increasing concentration of HMT from 0 to 10 mM. Therefore, Ni(OH)2 is sparsely formed on the Ni foam with increasing HMT concentration, showing a layered double-hydroxide structure. However, loosely packed Ni(OH)2 grains that are spread on Ni foam maintain a much greater surface area for reaction and result in the effective utilization of the electrode material due to the steric hindrance effect. It is suggested that the Ni(OH)2 electrodes with HMT concentration of 7.5 mM have the maximum specific capacitance (1023 F/g), which is attributed to the facile electrolyte penetration and fast proton exchange via optimized surface areas.
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