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수열합성법으로 제조된 니켈코발트산화물(NiCo2O4) 나노시트 전극의 특성

Characteristics of nickel cobalt oxide (NiCo2O4) nanosheet electrodes prepared by hydrothermal synthesis and heat treatment

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주제분류기계공학

초록

In a carbon-zero social atmospher, research is underway to reduce the use of fossil fuels. Interest in cleaner energy sources and their storage system is growing, and among them, research on effective energy storage is being actively conducted. Energy storage system(ESS) can be divided into secondary batteries, fuel cells, and capacitors, and the superiority of energy density of secondary batteries has a dominent influence on the ESS market. However, as problems with secondary batteries, charge/discharge speed, safety, and deterioration of electrodes are being highlighted. In this study, an electrode for supercapacitor with superior charge/discharge speed and specific capacitance is manufactured. The manufactured spinel nickel cobalt electrodes had specific capacitances of 1018.8 F/g, 690.8 F/g, and 475.1 F/g at 1 A/g in 1 M KOH electrolyte, and shows a performance retention rate of 77.48%, 63.30%, and 58.16% after 2000cycles at 7 A/g.

Abstract

In a carbon-zero social atmospher, research is underway to reduce the use of fossil fuels. Interest in cleaner energy sources and their storage system is growing, and among them, research on effective energy storage is being actively conducted. Energy storage system(ESS) can be divided into secondary batteries, fuel cells, and capacitors, and the superiority of energy density of secondary batteries has a dominent influence on the ESS market. However, as problems with secondary batteries, charge/discharge speed, safety, and deterioration of electrodes are being highlighted. In this study, an electrode for supercapacitor with superior charge/discharge speed and specific capacitance is manufactured. The manufactured spinel nickel cobalt electrodes had specific capacitances of 1018.8 F/g, 690.8 F/g, and 475.1 F/g at 1 A/g in 1 M KOH electrolyte, and shows a performance retention rate of 77.48%, 63.30%, and 58.16% after 2000cycles at 7 A/g.

참고문헌 (10)

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  3. D. Lee, "Improvement of electrical performance by surface structure of Ni-material as a high-performance asymmetric supercapacitor electrode", Ceram. Int, 46, pp.11189~11197 (2020)
  4. X. Zhang, "In Situ Growth of 2D Ultrathin NiCo2 O4 Nanosheet Arrays on Ni Foam for High Performance and Flexible Solid-State Supercapacitors", Small, 16, pp.2004188~ (2020)
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  8. X. Wang, "Nickel Cobalt Oxide-Single Wall Carbon Nanotube Composite Material for Superior Cycling Stability and High-Performance Supercapacitor Application", J. Phys. Chem. C, 116, pp.12448~12454 (2012)
  9. 정우준, "슈퍼커패시터용 그래핀볼 - 그래핀옥사이드 복합전극의 전기화학적 특성", 한국표면공학회지, 53(5), pp.213~218 (2020), 한국표면공학회
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