본문 바로가기
KERD
논문

Si 변성 유/무기 하이브리드 코팅액에 의한 아연도금강판의 내식특성

Corrosion Resistance of Galvanized Steel by Treating Modified Si Organic/Inorganic Hybrid Coating Solution

안석환|김종순|서현수|문희준|남기우|김정량|문창권
한국해양공학회 (The Korean Society of Ocean Engineers (KSOE))|2011.02|한국해양공학회지 (Journal of Ocean Engineering and Technology)|제25권 제1호|pp. 32-38

2

조회

0

다운로드

9

인용

0

참고문헌

키워드

Salt spray test 염수분무시험Organic/inorganic hybrid 유/무기 하이브리드Coating solution 코팅액Electrolytic galvanized 전기아연도금Hot-dip galvanized 용융아연도금White rust 백청
주제분류해양공학

초록

Galvanized steel has gone through a chemical process to keep it from corroding. The steel gets coated in layers of zinc because rust will not attack this protective metal. For countless outdoor, marine, or industrial applications, galvanized steel is an essential fabrication component. The reduction of the corrosion rate of zinc is an important topic. In the past, a very popular way to reduce the corrosion rate of zinc was to use chemical conversion layers based on Cr^+6. However, a significant problem that has arisen is that the use of chromium salts is now restricted because of environmental protection legislation. Therefore, it is very important to develop new zinc surface treatments that are environmentally friendly to improve the corrosion resistance of zinc and adhesion with a final organic protective layer. In this study, a Urethane solution (only Urethane 20 wt.%;S-700) and an organic/inorganic solution with Si (Si polysilicate 10 wt.% + Urethane 10 wt.%; LRO-317) are used. Based on the salt spray test of 72 h, S-700 and LRO-317 had a superior effect for the corrosion resistance on EGI and HDGI, respectively.

Abstract

Galvanized steel has gone through a chemical process to keep it from corroding. The steel gets coated in layers of zinc because rust will not attack this protective metal. For countless outdoor, marine, or industrial applications, galvanized steel is an essential fabrication component. The reduction of the corrosion rate of zinc is an important topic. In the past, a very popular way to reduce the corrosion rate of zinc was to use chemical conversion layers based on Cr^+6. However, a significant problem that has arisen is that the use of chromium salts is now restricted because of environmental protection legislation. Therefore, it is very important to develop new zinc surface treatments that are environmentally friendly to improve the corrosion resistance of zinc and adhesion with a final organic protective layer. In this study, a Urethane solution (only Urethane 20 wt.%;S-700) and an organic/inorganic solution with Si (Si polysilicate 10 wt.% + Urethane 10 wt.%; LRO-317) are used. Based on the salt spray test of 72 h, S-700 and LRO-317 had a superior effect for the corrosion resistance on EGI and HDGI, respectively.

참고문헌 (18)

  1. 김만, "환경친화성 경질 3가 크롬도금의 연구동향", 한국표면공학회지, 37(3), pp.179~184 (2004), 한국면공학회
  2. 이철태, "아연도금용 친환경 3가 크로메이트 표면처리기술", 공업화학, 17(5), pp.433~442 (2006), 한국공업화학회
  3. 김형준, "고내식성 내지문 EGI 강판 개발", 한국표면공학회지, 26(6), pp.307~315 (1993)
  4. 박영준, "Cr-free 처리 용융아연도금강판의 흑변 및 백청 현상 연구", 포스코 연구논문, 12(1), pp.106~110 (2007)
  5. Cr-free 차세대 나노코팅액 개발에 관한 연구, "이종두", 환경부, ~, pp.환경부(나노코) 연구보고서 (2006)
  6. 이철태, "3가 크롬황선염의 크로메이트에 의한 아연도금내식성 증대", 공업화학, 18(3), pp.296~302 (2007), 한국공업화학회
  7. 조남웅, "크로메이트 초리 대체기술의 개발동향", RIST 연구보고서, 15(1), pp.108~113 (2001)
  8. "ASTM D3359-09, Standard Test Methods for Measuring Adhesion by Tape Test", ~
  9. Bajat, J.B, "The Influence of Zinc Surface Pretreatment on the Adhesion of Epoxy Coating Electrodeposited on Hot-di p Galvanized Steel", Progress in Organic Coating, 58, pp.323~330 (2007)
  10. Duhua Wang, "Sol-gel Coatings on Metals for Corrosion", Progress in Organic Coatings, 64, pp.327~338 (2009)
  11. Deflorian, F, "EIS Study of Organic Coating on Zinc Surface Pretreated with Environmentally Friendly Products", Progress in Organic Coatings, 52, pp.271~279 (2005)
  12. Dobrza´nski, L.A, "Corrosion Resistance of Sintered Duplex Stainless Steels in the Salt Fog Spray Test", Journal of Materials Processing Technology, 192(193), pp.443~448 (2007)
  13. Gillett, M, "Adhesion Characterization of Titanium and Titanium Nitride Thin Coatings on Metals using the Scratch Test", hit. J. Adhesion am, 1995, pp.15, 191~196
  14. "KS D 9502", ~
  15. Steven, J.H, "Migration and Segregation Phenomena of a Silicone Additive in a Multilayer Organic Coating", Progress in Organic Coatings, 54, pp.104~112 (2005)
  16. Szira´ki, L, "Study of the Initial Stage of White Rust Formation on Zinc Single Crystal by EIS, STM", AFM and SEM, Electrochimica Acta, pp.2001, 46[DOI]
  17. Yang, D, "Effects of Lanthanum Addition on Corrosion Resistance of Hotdipped Galvalume Coating", Journal of Rare Earths, 27(1), pp.114~118 (2009)
  18. Zheludkevich, M.L, "Sol-gel Coatings for Corrosion Protection of Metals", J. Mater. Chem, 15, pp.5099~5111 (2005)

관련 논문AI추천

Chromate-free Hybrid Coating for Corrosion Protection of Electrogalvanized Steel Sheets권문재, 김종상, 조두환한국재료부식학회 · CORROSION SCIENCE AND TECHNOLOGY2012 · 제11권 제1호유/무기 하이브리드 코팅액에 의한 냉간압연강판의 열처리 온도에 따른 내식특성김정량, 남기우, 최창민한국해양공학회 · 한국해양공학회지2011 · 제25권 제6호Cr-free 코팅액에 의한 아연도금강판의 건조시간에 따른 내식특성김종순, 남기우, 문창권, 문희준, 서현수, 안석환한국해양공학회 · 한국해양공학회지2010 · 제24권 제5호Cr-free 코팅액에 의한 아연도금강판의 열처리 온도에 따른 내식특성김종순, 남기우, 문창권, 문희준, 서현수, 안석환한국해양공학회 · 한국해양공학회지2010 · 제24권 제5호크롬 프리 친환경 유/무기 하이브리드 코팅액에 의한 냉연강판의 내식특성김정량, 남기우, 최창민한국해양공학회 · 한국해양공학회지2013 · 제27권 제2호Silane계 유무기 하이브리드 적용 합금도금강판 내식성 향상 코팅 기술 개발박병규, 박종원, 이경황, 홍신협한국재료부식학회 · CORROSION SCIENCE AND TECHNOLOGY2013 · 제12권 제6호

이 간행물의 다른 논문 (13건)

감쇠판이 부착된 원기둥의 동유체력 특성조일형pp. 1-7밀집 배열 부이시스템의 파랑에너지 추출 효율 추정최윤락pp. 8-13목포해역 점착성 퇴적물의 침식특성에 대한 실험적 연구황규남, 김만곤, 태동현, 양수현pp. 14-21이중 킬 요트의 저항 특성에 관한 연구김도정, 박제웅, 이유신, 박경훈, 김규선, 정우철pp. 22-26상용 추진기를 사용하는 무인잠수정의 추진성능 추정이종무, 김기훈, 여동진, 이판묵, 최현택pp. 27-31
원문 보기