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AISI316L 강에 저온 플라즈마침탄 및 DLC 복합 코팅처리 시 처리온도에 따른 표면특성평가

Influence of Treatment Temperature on Surface Characteristics during Low Temperature Plasma Carburizing and DLC duplex treatment of AISI316L Stainless Steel

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초록

A low temperature plasma carburizing process was performed on AISI 316L austenitic stainless steel to achieve an enhancement of the surface hardness without degradation of its corrosion resistance. Attempts were made to investigate the influence of the processing temperatures on the surface hardened layer during low temperature plasma carburizing in order to obtain the optimum processing conditions. The expanded austenite (γ_c) phase, which contains a high saturation of carbon (S phase), was formed on all of the treated surfaces. Precipitates of chromium carbides were detected in the hardened layer (C-enriched layer) only for the specimen treated at 550℃. The hardened layer thickness of γ_c increased up to about 65 ㎛ with increasing treatment temperature. The surface hardness reached about 900 HK_0.05, which is about 4 times higher than that of the untreated sample (250 HK_0.05). A minor loss in corrosion resistance was observed for the specimens treated at temperatures of 300℃~450℃ compared with untreated austenitic stainless steel. In particular, the precipitation of chromium carbides at 550℃ led to a significant decrease in the corrosion resistance. A diamond-like carbon (DLC) film coating was applied to improve the wear and friction properties of the S phase layer. The DLC film showed a low and stable friction coefficient value of about 0.1 compared with that of the carburized surface (about 0.45). The hardness and corrosion resistance of the S phase layer were further improved by the application of such a DLC film.

Abstract

A low temperature plasma carburizing process was performed on AISI 316L austenitic stainless steel to achieve an enhancement of the surface hardness without degradation of its corrosion resistance. Attempts were made to investigate the influence of the processing temperatures on the surface hardened layer during low temperature plasma carburizing in order to obtain the optimum processing conditions. The expanded austenite (γ_c) phase, which contains a high saturation of carbon (S phase), was formed on all of the treated surfaces. Precipitates of chromium carbides were detected in the hardened layer (C-enriched layer) only for the specimen treated at 550℃. The hardened layer thickness of γ_c increased up to about 65 ㎛ with increasing treatment temperature. The surface hardness reached about 900 HK_0.05, which is about 4 times higher than that of the untreated sample (250 HK_0.05). A minor loss in corrosion resistance was observed for the specimens treated at temperatures of 300℃~450℃ compared with untreated austenitic stainless steel. In particular, the precipitation of chromium carbides at 550℃ led to a significant decrease in the corrosion resistance. A diamond-like carbon (DLC) film coating was applied to improve the wear and friction properties of the S phase layer. The DLC film showed a low and stable friction coefficient value of about 0.1 compared with that of the carburized surface (about 0.45). The hardness and corrosion resistance of the S phase layer were further improved by the application of such a DLC film.

참고문헌 (7)

  1. Sedriks, J, "Corrosion of stainless steels" (1996), John Wiley & Sons
  2. Smith,W.F, "Structure and properties of engineering alloy" (1981), McGraw-Hill
  3. Sun,Y., "Enhancement in Corrosion Resistance of Austenitic Stainless Steels by Surface Alloying with Nitrogen and Carbon", Mater. Lett, 59, pp.3410~3413 (2005)
  4. Sun,Y., "Kinetics of Low Temperature Plasma Carburizing of Austenitic Stainless Steels", Mater. Proc. Tech, 168, pp.189~194 (2005)
  5. Sun, Y., "Low Temperature Plasma Carburizing of Austenitic Stainless Steels for Improved Wear and Corrosion Resistance", Surf. Eng, 15(1), pp.49~54 (1999)
  6. Ueda, N, "DLC Film Coating on Plasma-carburized Austenitic Stainless Steel", Surf. Coat Techol, 201, pp.5487~5492 (2007)
  7. 안석환, "0.2% N을 첨가한 수퍼 2상 스테인리스강의 열처리 조건에 따른 특성 평가 - 제3보: 부식특성", 한국해양공학회지, 23(5), pp.85~91 (2009), 한국해양공학회

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