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PAN 전구체 섬유의 안정화시 전자선 전류의 영향

Effect of Electron Beam Currents on Stabilization of Polyacrlonitrile Precursor Fiber

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초록

Polyacrylonitrile (PAN) fibers are the most widely used precursor of the materials forcarbon fibers. The conventional process of carbon fibers from PAN precursor fiber includes twostep; stabilization at low temperature and carbonization at high temperature. Compared to thermalstabilization, the stabilization process by electron beam (E-beam) irradiation is a advancedand brief method. However, a stabilization by E-beam irradiation was required a high dose (over5,000 kGy) and spend over 1.5 hr (1.14 MeV, 1 mA). In the present work the main goal is exploringa quick stabilization process by cotrolling E-beam currents. The effect of various E-beam currentson stabilization of PAN precursor fiber was studied by gel fraction test, thermo gravimerticanalysis (TGA), differential scanning calorimetry (DSC), tensile strength, and scanning electronmicroscopy (SEM) images.

Abstract

Polyacrylonitrile (PAN) fibers are the most widely used precursor of the materials forcarbon fibers. The conventional process of carbon fibers from PAN precursor fiber includes twostep; stabilization at low temperature and carbonization at high temperature. Compared to thermalstabilization, the stabilization process by electron beam (E-beam) irradiation is a advancedand brief method. However, a stabilization by E-beam irradiation was required a high dose (over5,000 kGy) and spend over 1.5 hr (1.14 MeV, 1 mA). In the present work the main goal is exploringa quick stabilization process by cotrolling E-beam currents. The effect of various E-beam currentson stabilization of PAN precursor fiber was studied by gel fraction test, thermo gravimerticanalysis (TGA), differential scanning calorimetry (DSC), tensile strength, and scanning electronmicroscopy (SEM) images.

참고문헌 (7)

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  2. Fitzer E, "The influence of oxygen on the chemical reactions during stabilization of PAN as carbon fiber precursor", Carbon, 10, pp.63~69 (1975)
  3. Gupta A, "New aspects in the oxidative stabilization of PAN-based carbonfibers : II", Carbon, 6(35), pp.809~818 (1997)
  4. Jones H, "The effect of radiation on high technology polymers", pp.1~13 (1989), Am. Chem. Soc
  5. Qin O, "Mechanism and kinetics of the stabilization reactions of itaconic acidmodified polyacrylonitrile", Polym. Degrad. Stab, 93, pp.1415~1421 (2008)
  6. Yun JH, "Process optimization for preparing high performance PAN-bas-ed carbon fibers", Bull. Korean. Chem. Soc, 10(30), pp.2253~2258 (2009)
  7. Zhao WW, "Modification of poly(D, L-latic acid)-co-poly(ethylene glycol)copolymer by low energy electron beam(EB)radiation", J. Appl. Polym. Sci, 112, pp.2981~2987 (2010)

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