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방사선을 이용한 연료전지막 국내 제조 기술 개발 현황

Current R&D Status of Fuel Cell Membranes by Radiation in Korea

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초록

Since Nafion is very expensive and shows the decreased fuel cell performance over80􀆆􀆆C operating temperature, much work has been carried out in the search for cheaper membranewith high fuel cell performance. Radiation is known to be very useful for the preparation of thepolymer electrolyte membranes since it can be effectively used for the introduction of ion conductingfunctional groups into the commercial film with high mechanical and chemical properties. Here, we summarize the our recent progress in the development of fuel cell membranes by utilizingradiation.

Abstract

Since Nafion is very expensive and shows the decreased fuel cell performance over80􀆆􀆆C operating temperature, much work has been carried out in the search for cheaper membranewith high fuel cell performance. Radiation is known to be very useful for the preparation of thepolymer electrolyte membranes since it can be effectively used for the introduction of ion conductingfunctional groups into the commercial film with high mechanical and chemical properties. Here, we summarize the our recent progress in the development of fuel cell membranes by utilizingradiation.

참고문헌 (21)

  1. Chen J, "Fuel cell performance of polyetheretherketone-based polymer electrolyte membranes prepared by a two-step grafting method", J. Membr. Sci, 319, pp.1~4 (2008)
  2. Fei G, "Influence of the radiation grafting conditions on the cross-sectional distribution of poly(vinylbenzyl chloride)grafted polymer onto poly(tetrafluoroethylene-co-hexafluoropropylene)films", J. Appl. Polym. Sci, 117, pp.2380~2385 (2010)
  3. Fei G, "Preparation and characterization of a poly(vinylbenzyl sulfonic Acid)-grafted FEP membrane", J. Polym. Sci. A, 48, pp.563~569 (2010)
  4. 경비, "Preparation of Poly(vinylbenzyl chloride)-grafted Fluoropolymer Films by Using Radiation Grafting Method", 폴리머, 34(5), pp.464~468 (2010), 한국고분자학회
  5. Fei G, "A study on the characterization of FEP-g-PVBSA membranes as polymer electrolytes for direct methanol fuel cells", High Perform. Polym, 23, pp.555~560 (2011)
  6. Fei G, "Radiolytic preparation of PFA-g-PVBSA membranes as a polymer electrolyte membrane", Nucl. Instrum. Meth. Phys. B, 274, pp.83~86 (2012)
  7. Gubler L, "Radiation grafted membranes for polymer electrolyte fuel cells", Fuel Cells, 5, pp.317~335 (2005)
  8. Gubler L, "Advanced monomer combinations for radiation grafted fuel cell membranes", Electrochem. Commun, 8, pp.1215~1219 (2006)
  9. Sung-A Kang, "Preparation of crosslinked polystyrene-grafted PFA films by a simultaneous irradiation method", Journal of Industrial and Engineering Chemistry, 15(4), pp.516~519 (2009), 한국공업화학회
  10. Kang S, "Radiolytic preparation of poly(styrene sulfonic acid)-grafted poly(tetrafluoroethylene-co-perfluorovinyl vinyl ether)membranes with highly cross-linked networks", Nucl. Instrum. Meth. Phys. B, 268, pp.3458~3463 (2010)
  11. 고범석, "음이온 교환막 제조를 위한 염화비닐벤질 고분자가 그라프트된ETFE 필름의 방사선 합성과 디아민류와의 4차 아민화에 관한 연구", 방사선산업학회지, 5(2), pp.179~184 (2011), (사)한국방사선산업학회
  12. Ko B, "Radiolytic preparation of ETFE and PFA based anion exchange membranes for alkaline fuel cell", Nucl. Instrum. Meth. Phys. B, 269, pp.2509~2513 (2011)
  13. octane pendant groups for fuel cell application, "Polymer", 2012, 4652~4661
  14. 이지홍, "방사선을 이용한 실란 가교구조의 유", 무기 복합 수소이온 교환막 제조 및 연료전지 성능 평가, 2012, pp.36(4), 525~530[DOI]
  15. 이지홍, "방사선 그래프트를 순차적으로 진행하여 제조된 실란 가교구조의 수소이온교환막", 폴리머, 36(6), pp.816~821 (2012), 한국고분자학회[DOI]
  16. 이선영, "전조사법에 의한 PVBC-g-ETFE 필름 제조 시 용매의 영향 평가", 폴리머, 35(6), pp.610~614 (2011), 한국고분자학회
  17. Nasef MM, "Preparation and applications of ion exchange membranes by radiation-induced graft copolymerization of polar monomers onto non-polar films", Prog. Polym. Sci, 29, pp.499~561 (2004)
  18. Shin J, "Simultaneous radiation grafting of vinylbenzyl chloride onto poly(tetrafluoroethylene-co-hexafluoropropylene)films", J. Appl. Polym. Sci, 113, pp.2858~2862 (2009)
  19. 손준용, "Radiation Grafting of Binary Monomers for the Preparation of Organic", Inorganic Hybrid Membrane for Proton Exchange Membrane Fuel Cell Application, 2012, pp.20(9), 912~919[DOI]
  20. Sohn J, "Radiationgrafted proton exchange membranes based on co-grafting from binary monomer mixtures into poly(ethylene-co-tetrafluoroethylene)(ETFE)film", Rad. Phys. Chem, 81, pp.923~926 (2012)
  21. 성해준, "방사선을 이용한 스티렌-TMSPM 공중합체가 그래프트된 ETFE 필름의 제조", 폴리머, 35(5), pp.478~482 (2011), 한국고분자학회

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