Preparation and Characterization of Crosslinked Anion Exchange Membrane Using Electron Beam Irradiation
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The novel crosslinked anion exchange membrane with a high ion exchange capacityand stability was fabricated through a room temperature and solid-state radiation processing. Theanion-exchange membrane was prepared by solution casting method at the different compositionsof poly(diallyldimethylammonium chloride) and PVA substituted with methacryloyl group,and subsequently irradiated by electron beam to form 3D-network structure. From the variousanalytical results, the 3D-network crosslinked anion-exchange membrane exhibited not only ahigh ion exchange capacity (>1.7 meq·g-1) but a superior water stability (water uptake ≤ 30%)through a room temperature and quick radiation crosslinking process. Also, the prepared anionexchange membrane had better thermal stability compared to non crosslinked anion exchangemembrane (control).
Abstract
The novel crosslinked anion exchange membrane with a high ion exchange capacityand stability was fabricated through a room temperature and solid-state radiation processing. Theanion-exchange membrane was prepared by solution casting method at the different compositionsof poly(diallyldimethylammonium chloride) and PVA substituted with methacryloyl group,and subsequently irradiated by electron beam to form 3D-network structure. From the variousanalytical results, the 3D-network crosslinked anion-exchange membrane exhibited not only ahigh ion exchange capacity (>1.7 meq·g-1) but a superior water stability (water uptake ≤ 30%)through a room temperature and quick radiation crosslinking process. Also, the prepared anionexchange membrane had better thermal stability compared to non crosslinked anion exchangemembrane (control).
참고문헌 (18)
- Bhattacharya A, "Radiation and industrial polymers", Prog. Polym. Sci, 25, pp.371~401 (2000)
- Choi J-H, "Preparation and charaterization of crosslinked poly(butylene adipate-co-terephthalate)", polyhedral oligomeric silsesquioxane nanocomposite by electron beam irradiation, 2013, pp.82, 100~105
- Clough RL, "High-energy radiation and polymers : A review of commercial processes and emerging application", Nucl. Instrum. Methods Phys. Res. Sect. B, 185, pp.8~33 (2001)
- Hwang I-T, "Electron beam-induced crosslinking of poly(butylene adipate-co-terephthalate)", Nucl. Instrum. Methods Phys. Res., Sect. B, 268, pp.3386~3389 (2010)
- Kariduraganavar MY, "Ion-exchange membranes : preparative methods for electrodialysis and fuel cell applications", Desalination, 197, pp.225~246 (2006)
- Khan MI, "Design of Anion exchange membranes and electrodialysis studies for water desalination", Materials, 9, pp.1~14 (2016)
- Kim H-S, "Electron beam-based fabrication of crosslinked hydrophilic carbon electrodes and their application for capacitive deionization", RSC Adv, 9, pp.9684~9691 (2019)
- Maurya S, "Stability of composite anion exchange membranes with various functional groups and their performance for energy conversion", J. Membr. Sci, 443, pp.28~35 (2013)
- Nasef MM, "Ion Exchange Technology I: Theory and Materials", pp.1~40 (2012), Springer
- Ran J, "Ion exchange membranes : new developments and applications", J. Membr. Sci, 522, pp.267~291 (2017)
- 송주명, "12HPW", meso-SiO2 nanocomposite CSPEEK membranes for proton exchange membrane fuel cells, 2016, pp.36, 132~138[DOI]
- 손준용, "전자선 조사로 제조된 Sulfonated Polystyrene", Trimethylolpropane Ethoxylate Triacrylate(SPS, 폴리머, pp.2016, 40(1)[DOI]
- Strathmann H, "Electrodialysis, a mature technology with a multitude of new applications", Desalination, 264, pp.268~288 (2010)
- Strathmann H, "Ion exchange membranes in the chemical process industry", Ind. Eng. Chem. Res, 52, pp.10364~10379 (2013)
- Varcoe JR, "Anion-exchange membranes in electrochemical energy systems", Energy Environ. Sci, 7, pp.3135~3191 (2014)
- Wang J, "Synthesis and characterization of cross-linked poly (arylene ether ketone) containing pendant quaternary ammonium groups for anion-exchange membranes", J. Membr. Sci., 415-416, pp.205~212 (2012)
- Woo H-S, "EB-crosslinked polymer electrolyte membranes based on highly sulfonated poly(ether ether ketone)and poly(vinylidene fluoride)", triallyl isocyanurate, 2015, pp.15, 781~789
- Zhang J, "Cross-linked poly(vinyl alcohol)", poly(diallyldimethylammonium chloride)as anion-exchange membrane for fuel cell applications, 2013, pp.240, 359~367