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Characteristics of Cr(III)-based Conversion Coating Solution to Apply Aluminum Alloys for Improving Anti-corrosion Properties

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주제분류재료공학

초록

It is imperative to find environment-friendly coatings as an alternative to the currently used hexavalent chromate conversion coatings for the purpose of improving the anti-corrosion properties of aluminum alloys. Hence, in this study, the corrosion properties of a trivalent chromate conversion coating solution are analyzed and measured. Because of the presence of multiple components in trivalent chromate conversion coating solutions, it is difficult to control plating, attributed to their mutual organic relationship. It is of significance to determine the concentrations of the components present in these coatings; hence, qualitative and quantitative analysis is required. The coating solution contained not only an environment-friendly component chromium(III), but also zirconium, fluorine, sulfur, and potassium, in the coating film. These metals are confirmed to produce a film with improved corrosion resistance to form a thin layer. The excellent corrosion resistance for the trivalent chromate solution is attributed to various inorganic and organic additives.

Abstract

It is imperative to find environment-friendly coatings as an alternative to the currently used hexavalent chromate conversion coatings for the purpose of improving the anti-corrosion properties of aluminum alloys. Hence, in this study, the corrosion properties of a trivalent chromate conversion coating solution are analyzed and measured. Because of the presence of multiple components in trivalent chromate conversion coating solutions, it is difficult to control plating, attributed to their mutual organic relationship. It is of significance to determine the concentrations of the components present in these coatings; hence, qualitative and quantitative analysis is required. The coating solution contained not only an environment-friendly component chromium(III), but also zirconium, fluorine, sulfur, and potassium, in the coating film. These metals are confirmed to produce a film with improved corrosion resistance to form a thin layer. The excellent corrosion resistance for the trivalent chromate solution is attributed to various inorganic and organic additives.

참고문헌 (29)

  1. H. A. Katzman, "Corrosion-Protective chromate coatings on aluminum", Appl. Surf. Sci, 2, pp.416~ (1979)
  2. Y. Totik, "The effect of homogenisation treatment on cold deformations of AA 2014 and AA 6063 alloys", J. Mater. Process. Technol, 147, pp.60~ (2004)
  3. 조병준, "텅스텐 화학적-기계적 연마 공정에서 부식방지막이 증착된 금속 컨디셔너 표면의 전기화학적 특성평가", 마이크로전자 및 패키징학회지, 19(1), pp.61~66 (2012), 한국마이크로전자및패키징학회
  4. 박소연, "전기도금법을 이용한 나노 산화티타늄 니켈 복합도금에 관한 연구", 마이크로전자 및 패키징학회지, 19(4), pp.65~69 (2012), 한국마이크로전자및패키징학회[DOI]
  5. U. S. Public Health Service, "Toxicological profile for chromium", ATSDR, ~ (2012)
  6. S. M. Cohen, "Review: Replacements for Chromium Pretreatments on Aluminum", Corrosion, 51, pp.71~ (1995)
  7. 이철태, "아연도금용 친환경 3가 크로메이트 표면처리기술", 공업화학, 17(5), pp.433~442 (2006), 한국공업화학회
  8. O. Lunder, "Formation and characterisation of Ti-Zr based conversion layers on AA6060 aluminium", Surf. Coat. Technol, 184, pp.278~ (2009)
  9. H. Allachi, "Protection against corrosion in marine environments of AA6060 aluminium alloy by cerium chlorides", J. Alloys. Compd, 491, pp.223~ (2010)
  10. Ashutosh Sharma, "Aluminium Based Brazing Fillers for High Temperature Electronic Packaging Applications", 마이크로전자 및 패키징학회지, 22(4), pp.1~5 (2015), 한국마이크로전자및패키징학회
  11. J. Hu, "Corrosion protection of aluminum borate whisker reinforced AA6061composite by cerium oxide-based conversion coating", Surf. Coat. Technol, 201, pp.3814~ (2006)
  12. 이승진, "Ce0.8Sm0.2O2 Sol-gel Modification on La0.8Sr0.2Mn0.8Cu0.2O3 Cathode for Intermediate Temperature Solid Oxide Fuel Cell", 마이크로전자 및 패키징학회지, 22(4), pp.77~82 (2015), 한국마이크로전자및패키징학회
  13. R. L. Twite, "Review of alternatives to chromate for corrosion protection of aluminum aerospace alloys", Prog. Org. Coat, 33, pp.91~ (1998)
  14. B. Ramezanzadeh, "Corrosion performance of a hot-dip galvanized steel treated by different kinds of conversion coatings", Surf. Coat. Technol, 205, pp.874~ (2010)
  15. T. Bellezze, "Electrochemical study on the corrosion resistance of Cr III-based conversion layers on zinc coatings", Surf. Coat. Technol, 155, pp.221~ (2002)
  16. X. Zhang, "Comparison of the morphology and corrosion performance of Cr(VI)- and Cr(III)-based conversion coatings on zinc", Surf. Coat. Technol, 199, pp.92~ (2005)
  17. P. Campestrini, "Chromate Conversion Coating on Aluminum Alloys: I. Formation Mechanism", J. Electrochem. Soc, 151, pp.B59~ (2004)
  18. P. L. Hagans, "Chromate Conversion Coatings", Surface Engineering, 405 (1994), ASM International
  19. J. Zhao, "Effects of chromate and chromate conversion coatings on corrosion of aluminum alloy 2024-T3", Surf. Coat. Technol, 140, pp.51~ (2001)
  20. P. Campestrini, "Chromate Conversion Coating on Aluminum Alloys III. Corrosion Protection", J. Electrochem. Soc., 151, pp.B370~ (2004)
  21. W. K. Chen, "Growth and characteristics of Cr(III)-based conversion coating on aluminum alloy", J. Taiwan. Inst. Chem. Eng, 43, pp.989~ (2012)
  22. "Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements", ASTM G102-89, ~ (1999)
  23. H. C. Yu, "Investigation of the trivalent-chrome coating on 6063 aluminum alloy", Mater. Lett, 62, pp.2828~ (2008)
  24. Y. S. Kim, "Influences of Chromate Coating Conditions in the Surface Appearance and Corrosion Resistance of Aluminium Alloys for Can-stock", J. Corros Sci. Soc. of Korea, 25(2), pp.180~ (1996)
  25. W. K. Chen, "The effect of chromic sulfate concentration and immersion time on the structures and anticorrosive performance of the Cr(III) conversion coatings on aluminum alloys", Appl. Surf. Sci, 256, pp.4924~ (2010)
  26. T. Y. Chiang, "Corrosion Resistance of 5052 Al-alloy with a Zirconia-Rich Conversion Coating Used in Bipolar Plates in PEMFCs", Int. J. Electrochem. Sci, 9, pp.5850~ (2014)
  27. P. Campestrini, "Chromate Conversion Coating on Aluminum Alloys II: Effect of the Microstructure", J. Electrochem. Soc, 151, pp.B359~ (2004)
  28. Z. Yu, "A study of the composition and structure of chromate conversion coating on aluminum", Appl. Surf. Sci, 62, pp.217~ (1992)
  29. 이철태, "3가 크롬황선염의 크로메이트에 의한 아연도금내식성 증대", 공업화학, 18(3), pp.296~302 (2007), 한국공업화학회

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