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블록 공중합체 박막을 이용한 실리콘 나노점의 형성

Fabrication of Si Nano Dots by Using Diblock Copolymer Thin Film

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참고문헌

주제분류재료공학

초록

Abstract

Dense and periodic arrays of holes and Si nano dots were fabricated on silicon substrate. The nanopatterned holes were approximately 15~40 nm wide, 40 nm deep and 40~80 nm apart. To obtain nano-size patterns, self-assembling diblock copolymer were used to produce layer of hexagonaly ordered parallel cylinders of polymethylmethacrylate (PMMA) in polystyrene(PS) matrix. The PMMA cylinders were degraded and removed with acetic acid rinse to produce a PS. 100 -thick Au thin film was deposited by using e-beam evaporator. PS template was removed by lift-off process. Arrays of Au nano dots were transferred by using Fluorine-based reactive ion etching(RIE). Au nano dots were removed by sulfuric acid. Si nano dots size and height were 30~70 nm and 10~20 nm respectively.

참고문헌 (8)

  1. "Block Copolymer Lithography: Periodic Arrays of ~1011 Holes in 1 Square Centimeter", 276, pp.1401~ (1997)
  2. "Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates", 290, pp.2126~ (2000)
  3. "Integration of self-assembled diblock copolymers for semiconductor capacitor fabrication", 79, pp.409~ (2001)
  4. "Large area dense nanoscale patterning of arbitrary surfaces", 79, pp.257~ (2001)
  5. "Perpendicular lamellae induced at the interface of neutral self-assembled monolayers in thin diblock copolymer films", 43, pp.2507~ (2002), Polymer
  6. "Volume Contractions Induced by Crosslinking: A Novel Route to Nanoporous Polymer Films", 15(15), pp.1247~ (2003)
  7. "Optimization of Diblock Copolymer Thin Film Self Assembly", 14(18), pp.1290~ (2002)
  8. "Tungsten Nanodot Arrays Patterned Using Diblock Copolymer Templates", 46(2), pp.856~ (2007)

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