PEDOT:PSS로 코팅된 PLA 나노섬유 웹의 전기전도성 텍스타일 제조
Fabrication of Electroconductive Textiles Based PLA Nanofiber Web Coatedwith PEDOT:4PSS
1
조회
0
다운로드
2
인용
0
참고문헌
키워드
초록
We proposed a simple process of fabricating electroconductive textiles by coating conductive polymer PEDOT:PSS (Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)) on biocompatible PLA (Poly Lactic Acid) nanofiber web for application to smart healthcare. Electroconductive textiles were obtained by a drop-coating process using different amounts of PEDOT:PSS solutions., DMSO (dimethyl sulfoxide) was then used as an additive in the post-treatment process to improve conductivity. The surface morphology of the specimens was observed by FE-SEM. The chemical structures of the specimens were characterized using FTIR. The electrical properties (linear and sheet resistance) of the specimens were measured. The effect of the bending angles on the electrical properties was also investigated to confirm their applicability as wearable smart textiles. FE-SEM and FTIR analysis confirmed that the deposition of PEDOT:PSS on the PLA nanofiber web surface was successful. The conductivity of the PEDOT:PSS/PLA nanofiber web was enhanced up to 1.5 ml with an increasing amount of PEDOT:PSS solutions, but there was no significant difference at 2.0 ml. The optimum condition of PEDOT:PSS deposition was established to 1.5 ml. Even when the specimen coated with 1.5 ml was bent every 30°, the change in the electrical resistance values was still low within 3.7 Ω. It confirmed that stable electrical performance was maintained and proved the applicability as a flexible textile sensor.
Abstract
We proposed a simple process of fabricating electroconductive textiles by coating conductive polymer PEDOT:PSS (Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)) on biocompatible PLA (Poly Lactic Acid) nanofiber web for application to smart healthcare. Electroconductive textiles were obtained by a drop-coating process using different amounts of PEDOT:PSS solutions., DMSO (dimethyl sulfoxide) was then used as an additive in the post-treatment process to improve conductivity. The surface morphology of the specimens was observed by FE-SEM. The chemical structures of the specimens were characterized using FTIR. The electrical properties (linear and sheet resistance) of the specimens were measured. The effect of the bending angles on the electrical properties was also investigated to confirm their applicability as wearable smart textiles. FE-SEM and FTIR analysis confirmed that the deposition of PEDOT:PSS on the PLA nanofiber web surface was successful. The conductivity of the PEDOT:PSS/PLA nanofiber web was enhanced up to 1.5 ml with an increasing amount of PEDOT:PSS solutions, but there was no significant difference at 2.0 ml. The optimum condition of PEDOT:PSS deposition was established to 1.5 ml. Even when the specimen coated with 1.5 ml was bent every 30°, the change in the electrical resistance values was still low within 3.7 Ω. It confirmed that stable electrical performance was maintained and proved the applicability as a flexible textile sensor.
참고문헌 (21)
- Åkerfeldt, M., "Electrically conductive textile coating with a PEDOT-PSS dispersion and a polyurethane binder", Textile Research Journal, 83(6), pp.618~627 (2013)[DOI]
- Avinc, O., "Overview of poly(lactic acid)(PLA)fibre", Fibre Chemistry, 41(6), pp.391~401 (2009)
- Calvert, P., "Conducting polymer and conducting composite strain sensors on textiles", Molecular Crystals and Liquid Crystals, 484(1), pp.291~657 (2008)[DOI]
- Gotovtsev, P. M., "Electroconductive PEDOT: PSS-based hydrogel prepared by freezing-thawing method", Heliyon, 5(9), pp.e02498~ (2019)[DOI]
- Jang, E. J., "Enhancing the conductivity of PEDOT : PSS", PU nanoweb via dimethyl sulfoxide solvent treatment, 2019, 21~23
- Jang, E. J., "Characterization and exploration of polyurethane nanofiber webs coated with graphene as a strain gauge", Textile Research Journal, 89(23-24), pp.4980~2991 (2019)[DOI]
- Jang, Y. S., "Electrically conducting polymer-Based biomaterials and their biomedical applications and development direction", Polymer Science and Technology, 26(4), pp.305~312 (2015)
- 주문일, "생체신호 습득과 건강 모니터링을 위한스마트 헬스케어 의복 개발", 멀티미디어학회논문지, 19(5), pp.808~817 (2016), 한국멀티미디어학회[DOI]
- Kim, I. H., "Polyurethane nanofiber strain sensors via in situ polymerization of polypyrrole and application to monitoring joint flexion", Smart Materials and Structures, 27(7), pp.075006~ (2018)[DOI]
- 김진희, "솔벤트 도핑과 후처리 공정에 따른 전도성 고분자 PEDOT : PSS의 특성 변화", 공업화학, 26(3), pp.275~279 (2015), 한국공업화학회[DOI]
- 김재현, "심전도용 전극으로의 적용을 위한 폴리피롤 코팅 PVA 나노웹 전기전도성텍스타일의 제조", 한국의류산업학회지, 21(3), pp.363~369 (2019), 한국의류산업학회[DOI]
- Na, S. I., "Polymer PEDOT : PSS-based transparent electrode material technology", The Korean Information Display Society, 11(5), pp.57~63 (2010)
- Olivares, A. J., "Nanostructural modification of PEDOT : PSS for high charge carrier collection in hybrid frontal interface of solar cells", Polymers, 11(6), pp.1034~ (2019)[DOI]
- Pani, D., "Fully textile, PEDOT : PSS based electrodes for wearable ECG monitoring systems", IEEE Transactions on Biomedical Engineering, 63(3), pp.540~549 (2015)[DOI]
- Park, J. Y., "Preparation, properties and applications of electrospun polylactic acid(PLA)fibers containing silver", Journal of Advanced Engineering and Technology, 4(4), pp.491~495 (2011)
- Praharaj Bhatnagar, M., "Synthesis and characterization of poly(3, 4 ethylenedioxythiophene)", poly(lactic acid)nanofibres by electrospinning, 2017, pp.66(3), 359~365
- 노정심, "웨어러블 텍스타일 스트레인 센서 리뷰", 한국의류산업학회지, 18(6), pp.733~745 (2016), 한국의류산업학회
- Ryan, J. D., "Machine-washable PEDOT : PSS dyed silk yarns for electronic textiles", ACS Applied Materials & Interfaces, 9(10), pp.9045~9050 (2017)[DOI]
- Tadesse, M. G., "Electrically conductive highly elastic polyamide", lycra fabric treated with PEDOT : PSS and polyurethane, 2019, pp.54(13), 9591~9602
- Wisitsoraat, A., "Graphene-PEDOT : PSS on screen printed carbon electrode for enzymatic biosensing", Journal of Electroanalytical Chemistry, 704, pp.208~213 (2013)[DOI]
- Yang, S. L., "Thermal and mechanical properties of chemical crosslinked polylactide(PLA)", Polymer Testing, 27(8), pp.957~963 (2008)[DOI]
