PEDOT:PSS/그래핀 코팅된 폴리아미드/폴리우레탄혼방 편직물 기반의 전기전도성 텍스타일 제조
Fabrication of Electroconductive Textiles Based Polyamide/Polyurethan Knitted Fabric Coated with PEDOT:PSS/Non-oxidized Graphene
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초록
We proposed a simple process of creating electroconductive textiles by using PEDOT:PSS(Poly(3,4-eth- ylenedioxythiophene):poly(styrenesulfonate))/non-oxidized graphene to coat polyamide or polyurethane knitted fabric for smart healthcare purposes. Electroconductive textiles were obtained through a coating process that used different amounts of PEDOT:PSS/non-oxidized graphene solutions on polyamide/polyurethane knitted fabric. Subsequently, the surface, electrical, chemical, weight change, and elongation properties were evaluated according to the ratio of PEDOT:PSS/non-oxidized graphene composite(1.3 wt%:1.0 wt%; 1.3 wt%:0.6 wt%; 1.3 wt%:0.3 wt%) and the number of applications(once, twice, or thrice). The specimens’ surface morphology was observed by FE-SEM. Further, their chemical structures were characterized using FTIR and Raman spectroscopy. The electrical properties measurement (sheet resistance) of the specimens, which was conducted by four-point contacts, shows the increase in conductivity with non-oxidized graphene and the number of applications in the composite system. Moreover, a test of the fabrics’ mechan- ical properties shows that PEDOT:PSS/non-oxidized graphene-treated fabrics exhibited less elongation and better ability to recover their original length than untreated samples. Furthermore, the PEDOT:PSS/non-oxidized graphene polyamide/ polyurethane knitted fabric was tested by performing tensile operations 1,000 times with a tensile strength of 20%; Con- sequently, sensors maintained a constant resistance without noticeable damage. This indicates that PEDOT:PSS/non-oxi- dized graphene strain sensors have sufficient durability and conductivity to be used as smart wearable devices.
Abstract
We proposed a simple process of creating electroconductive textiles by using PEDOT:PSS(Poly(3,4-eth- ylenedioxythiophene):poly(styrenesulfonate))/non-oxidized graphene to coat polyamide or polyurethane knitted fabric for smart healthcare purposes. Electroconductive textiles were obtained through a coating process that used different amounts of PEDOT:PSS/non-oxidized graphene solutions on polyamide/polyurethane knitted fabric. Subsequently, the surface, electrical, chemical, weight change, and elongation properties were evaluated according to the ratio of PEDOT:PSS/non-oxidized graphene composite(1.3 wt%:1.0 wt%; 1.3 wt%:0.6 wt%; 1.3 wt%:0.3 wt%) and the number of applications(once, twice, or thrice). The specimens’ surface morphology was observed by FE-SEM. Further, their chemical structures were characterized using FTIR and Raman spectroscopy. The electrical properties measurement (sheet resistance) of the specimens, which was conducted by four-point contacts, shows the increase in conductivity with non-oxidized graphene and the number of applications in the composite system. Moreover, a test of the fabrics’ mechan- ical properties shows that PEDOT:PSS/non-oxidized graphene-treated fabrics exhibited less elongation and better ability to recover their original length than untreated samples. Furthermore, the PEDOT:PSS/non-oxidized graphene polyamide/ polyurethane knitted fabric was tested by performing tensile operations 1,000 times with a tensile strength of 20%; Con- sequently, sensors maintained a constant resistance without noticeable damage. This indicates that PEDOT:PSS/non-oxi- dized graphene strain sensors have sufficient durability and conductivity to be used as smart wearable devices.
참고문헌 (19)
- Gbolahan Joseph Adekoya, "Nanocomposites of PEDOT:PSS with Graphene and its Derivatives for Flexible Electronic Applications: A Review", Macromolecular Materials and Engineering, 306(3), pp.2000716~ (2021), Wiley[DOI]
- ASTM D2594-04Standard test method for stretch properties of knitted fabrics having low power, "American Society of Testing Materials", ASTM International, ~ (2004)
- ASTM D6614-2007standard test method for stretch properties of textile fabrics - CRE Method, "American Society of Testing Materials", ASTM International, ~ (2011)
- Fei-Peng Du, "PEDOT:PSS", graphene quantum dots films with enhanced thermoelectric properties via strong interfacial interaction and phase separation, 2018, pp.8(1), ~[DOI]
- A. C. Ferrari, "Raman Spectrum of Graphene and Graphene Layers", Physical Review Letters, 97(18), pp.187401~ (2006), American Physical Society (APS)[DOI]
- 장은지, "웨어러블 생체신호 모니터링을 위한 스마트텍스타일센서의 분류 및 고찰", 한국의류산업학회지, 21(6), pp.697~707 (2019), 한국의류산업학회[DOI]
- Syed Khasim, "High performance flexible supercapacitors based on secondary doped PEDOT–PSS–graphene nanocomposite films for large area solid state devices", RSC Advances, 10(18), pp.10526~10539 (2020), Royal Society of Chemistry (RSC)[DOI]
- 김승민, "고령사회 스마트 헬스케어를 위한 UX 디자인방안- 사물인터넷 기술을 중심으로", 한국콘텐츠학회 논문지, 18(11), pp.462~474 (2018), 한국콘텐츠학회[DOI]
- Woojin Kim, "Improved Electrical Conductivity of Polyurethane Nanoweb Coated with Graphene Ink through Heat Treatment", Fibers and Polymers, 21(6), pp.1195~1199 (2020), 한국섬유공학회
- Hanna Lee, "Preparation of fabric strain sensor based on graphene for human motion monitoring", Journal of Materials Science, 53(12), pp.9026~9033 (2018), Springer Science and Business Media LLC[DOI]
- Fei Liu, "Electrochemical energy storage applications of “pristine” graphene produced by non-oxidative routes", Science China Technological Sciences, 58(11), pp.1841~1850 (2015), Springer Science and Business Media LLC[DOI]
- Pasha W. Sayyad, "Selective Hg2+ sensor: rGO-blended PEDOT:PSS conducting polymer OFET", Applied Physics A, 127(3), pp.167~ (2021), Springer Science and Business Media LLC[DOI]
- Graziella Trovati, "Characterization of polyurethane resins by FTIR, TGA, and XRD", Journal of Applied Polymer Science, 115(1), pp.263~268 (2010), Wiley[DOI]
- Granch Berhe Tseghai, "Development of a Flex and Stretchy Conductive Cotton Fabric Via Flat Screen Printing of PEDOT:PSS", PDMS Conductive Polymer Composite, 2020, pp.20(6), 1742~[DOI]
- Zifeng Wang, "Polyurethane", Cotton, ACS Applied Materials & Interfaces, pp.2016, 8(37)[DOI]
- World report on ageing and health, "World Health Organization", World Health Organization, ~ (2015)
- Xie, J., "High sensitivity knitted fabric strainsensors", Smart Materials and Structures, 25(10), pp.105008~ (2016)
- Jinhua Xiong, "Liquid Exfoliated Graphene as Dopant for Improving the Thermoelectric Power Factor of Conductive PEDOT:PSS Nanofilm with Hydrazine Treatment", ACS Applied Materials & Interfaces, 7(27), pp.14917~14925 (2015), American Chemical Society (ACS)[DOI]
- Mengliang Zheng, "Removal of Cr(VI) from aqueous solution using magnetite", non-oxidative graphene composites: Synergetic effect of Cr(VI) on dyes removal, 2016, pp.51(18), 2958~2969[DOI]
