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설파민산 니켈-코발트 합금도금 박막 물성에 대한 실험 연구

A Study on Properties of Electrodeposited Nickel-Cobalt Alloy Films from Sulfamate Solution

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키워드

주제분류기계공학

초록

The electrodeposition of Ni-Co alloy from a sulfamate bath was investigated. The cobalt content in the Ni-Co deposits is more influenced by the temperature or stirring effect than the current density in the process parameters. As cobalt contents in the Ni-Co deposited layer increased from 0 wt.% up to 43 wt.%, hardness value of the layer rised from 400 Hv up to 700 Hv and crystal orientation (111) increased. However, (200) and crystal size significantly reduced. The tensile and yield strength also increased, while the modulus of elasticity showed the maximum value of 10.4 N/mm2 at 29 wt.%.

Abstract

The electrodeposition of Ni-Co alloy from a sulfamate bath was investigated. The cobalt content in the Ni-Co deposits is more influenced by the temperature or stirring effect than the current density in the process parameters. As cobalt contents in the Ni-Co deposited layer increased from 0 wt.% up to 43 wt.%, hardness value of the layer rised from 400 Hv up to 700 Hv and crystal orientation (111) increased. However, (200) and crystal size significantly reduced. The tensile and yield strength also increased, while the modulus of elasticity showed the maximum value of 10.4 N/mm2 at 29 wt.%.

참고문헌 (9)

  1. Maria Hagarova, "Microstructure and Properties of Electroplated Ni-Co Alloy Coatings", Int. J. Elecrochem. SCi., 10, pp.9968~9974 (2015)
  2. Liping Wang, "Microstructure and tribological properties of electrodeposited Ni-Co alloy deposits", Applied Surface Science, 242, pp.326~332 (2005)
  3. Babak Bakhit, "Nanocrystalline Ni–Co alloy coatings", J. Coat. Technol. Res, 10(2), pp.285~295 (2013)
  4. C. Liu, "Out-of-plane magnetic actuators with electroplated permalloy for fluid dynamics control", Sens. Actuators, 78, pp.190~197 (1999)
  5. F. E. Rasmussen, "Electroplating and characterization of cobalt–nickel–iron and nickel–iron for magnetic microsystems applications", Sens. Actuators, 92, pp.242~248 (2001)
  6. A. Bianco, "Microstructural characterisation of Ni, Co and Ni Co fine powders for physical sensors", Thermochimica Acta, 269, pp.270 (1995), 117~132
  7. A. N. Correia, "Electrodeposition and characterisation of thin layers of Ni Co alloys obtained from dilute chloride baths", Electrochimica Acta, 45, pp.1733~1740 (2000)
  8. D. Golodmitsky, "The role of anion additives in the electrodeposition of nickel-cobalt alloys from sulfamate electrolyte", Electrochimica Acta, 47, pp.2707~2714 (2002)
  9. Babak Bakhit, "Nanocrystalline Ni-Co alloy Coating", J. Coat. Technol. Res., 10(2), pp.285~295 (2013)

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