AZ31 마그네슘 합금의 고온산화에 미치는 CaO 첨가 영향
Effect of CaO Addition on the High-temperature Oxidation of AZ31 Magnesium Alloys
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Magnesium alloys of AZ31 containing (0.5, 1, 1.5) wt.% of initially added CaO particles were cast in air, and their oxidation behavior was studied at 450-650oC in air. The initially added CaO particles either decomposed to dissolve in the α-Mg matrix or precipitated as Al2Ca along the grain boundaries of the matrix during casting. The ignition temperatures were 565.4oC for AZ31, 608.6oC for AZ31+0.5 wt.%CaO, and 689.7oC for AZ31+1 wt.%CaO. No ignition occurred for AZ31+1.5 wt.%CaO up to 700oC, displaying good oxidation resistance. The CaO-rich oxide scales that formed on the surface of the AZ31+(0.5, 1, 1.5) wt.%CaO alloys improved the oxidation resistance of AZ31 alloys.
Abstract
Magnesium alloys of AZ31 containing (0.5, 1, 1.5) wt.% of initially added CaO particles were cast in air, and their oxidation behavior was studied at 450-650oC in air. The initially added CaO particles either decomposed to dissolve in the α-Mg matrix or precipitated as Al2Ca along the grain boundaries of the matrix during casting. The ignition temperatures were 565.4oC for AZ31, 608.6oC for AZ31+0.5 wt.%CaO, and 689.7oC for AZ31+1 wt.%CaO. No ignition occurred for AZ31+1.5 wt.%CaO up to 700oC, displaying good oxidation resistance. The CaO-rich oxide scales that formed on the surface of the AZ31+(0.5, 1, 1.5) wt.%CaO alloys improved the oxidation resistance of AZ31 alloys.
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