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High Temperature Oxidation Behavior of Mg-6%Al-1%Zn-1%CaO Alloys

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주제분류기계공학

초록

The magnesium-base AZ61 alloy was cast while adding 1% CaO powder into the melt. It was hot extruded, and oxidized at 550-650oC in air in order to study its microstructure and oxidation behavior. Initially added CaO powder reacted with Al in the melt to Al2Ca particles that aligned along the extrusion direction. The formed Al2Ca particles increased the oxidation resistance through forming the superficial CaO scale at the upper part of the thin MgO oxide scale.

Abstract

The magnesium-base AZ61 alloy was cast while adding 1% CaO powder into the melt. It was hot extruded, and oxidized at 550-650oC in air in order to study its microstructure and oxidation behavior. Initially added CaO powder reacted with Al in the melt to Al2Ca particles that aligned along the extrusion direction. The formed Al2Ca particles increased the oxidation resistance through forming the superficial CaO scale at the upper part of the thin MgO oxide scale.

참고문헌 (9)

  1. Y. H. Kim, "Flame-Resistant Ca-Containing AZ31 Magnesium Alloy Sheets with Good Mechanical Properties Fabricated by a Combination of Strip Casting and High-Ratio Differential Speed Rolling Methods", Metals and Materials International, 21(2), pp.374~381 (2015), 대한금속·재료학회[DOI]
  2. Jing Xiao, "Compressive Behavior and Constitutive Analysis of AZ31B Magnesium Alloy over Wide Range of Strain Rates and Temperatures", Metals and Materials International, 21(5), pp.823~831 (2015), 대한금속·재료학회[DOI]
  3. 원성빈, "CaO 첨가가 AM30 마그네슘 합금의 고온산화에 미치는 영향", 대한금속·재료학회지, 52(3), pp.187~194 (2014), 대한금속·재료학회
  4. F. Czerwinski, "Oxidation characteristics of magnesium alloys", JOM, 64, pp.1477~1483 (2012)
  5. J. K. Lee, "Effect of CaO composition on oxidation and burning behaviors of AM50 Mg alloy", Trans. Nonferr. Metal. Soc. China, 21, pp.s23~s27 (2011)
  6. D. B. Lee, "High temperature oxidation of AZ31+ 0.3 wt.%Ca and. AZ31 + 0.3 wt.%CaO magnesium alloys", Corros. Sci, 70, pp.243~251 (2013)
  7. D. B. Lee, "Effect of CaO and hot extrusion on the oxidation of AZ61 magnesium alloys", Oxid. Met, 85, pp.65~74 (2016)
  8. P. Kofstad, "Nonstoichiometry, Diffusion and electrical conductivity in binary metal oxides", pp.121~ (1972), Wiley-Interscience
  9. 박순용, "CaO첨가가 마그네슘 합금의 고온산화에 미치는 영향", 대한금속·재료학회지, 54(6), pp.390~399 (2016), 대한금속·재료학회[DOI]

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