본문 바로가기
KERD
논문KCI 등재

실리콘 산화물 나노입자의 크기 제어 합성 및 리튬이온전지 음극재로의 적용

Size-controlled synthesis of silicon oxide nanoparticles and the application as anode materials in lithium-ion batteries

정구환|양정윤|석은
한국표면공학회 (The Korean Society of Surface Science and Engineering)|2024.10|한국표면공학회지 (Journal of Surface Science and Engineering)|제57권 제5호|pp. 425-431|DOI 10.5695/JSSE.2024.57.5.425

1

조회

0

다운로드

0

인용

0

참고문헌

키워드

Anode materialLithium ion batteriesMagnesiothermic reduction reactionReduced silicon oxide.
주제분류기계공학

초록

As demand in the electric vehicle market increases, the development of high capacity, high energy density lithium-ion batteries (LIBs) is required. Silicon has a extremely high theoretical capacity of 4200 mAh/g, but low cycle life and structural instability due to high volume expansion during charging and discharging are critical issue to solve. A reduced silicon oxide has also a high theoretical capacity of 2500 mAh/g and recently studied extensively for its low-cost, superior cycle life, and structural stability.

Abstract

As demand in the electric vehicle market increases, the development of high capacity, high energy density lithium-ion batteries (LIBs) is required. Silicon has a extremely high theoretical capacity of 4200 mAh/g, but low cycle life and structural instability due to high volume expansion during charging and discharging are critical issue to solve. A reduced silicon oxide has also a high theoretical capacity of 2500 mAh/g and recently studied extensively for its low-cost, superior cycle life, and structural stability.

참고문헌 (27)

  1. M. Li, "30 years of lithium-ion batteries", Advanced Materials, 30, pp.1800561~ (2018)
  2. P. U. Nzereogu, "Anode materials for lithium-ion batteries : a review", Applied Surface Science Advances, 9, pp.100233~ (2022)
  3. M. H. Hossain, "Advances of lithium-ion batteries anode materials-a review", Chemical Engineering Journal Advances, 16, pp.100569~ (2023)
  4. J. W. Choi, "Promise and reality of post-lithium-ion batteries with high energy densities", Nature Reviews Materials, 1, pp.1~16 (2016)
  5. L. Ji, "Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries", Energy & Environmental Science, 4, pp.2682~2699 (2011)
  6. P. Roy, "Nanostructured anode materials for lithium ion batteries", Journal of Materials Chemistry A, 3, pp.2454~2484 (2015)
  7. N. Mahmood, "Nanostr-uctured anode materials for lithium ion batteries: progress, challenge and perspective", Advanced Energy Materials, 6, pp.1600374~ (2016)
  8. X. Su, "Silicon-based nanomaterials for lithium-ion batteries : a review", Advanced Energy Materials, 4, pp.1300882~ (2014)
  9. S. Chae, "Integration of graphite and silicon anodes for the commercialization of high-energy lithium-ion batteries", Angewandte Chemie International Edition, 59, pp.110~135 (2020)
  10. K. Feng, "Silicon-based anodes for lithiumion batteries : from fundamentals to practical applications", Small, 14, pp.1702737~ (2018)
  11. X. Chen, "Structure design and mechanism analysis of silicon anode for lithium-ion batteries", Science China Materials, 62, pp.1515~1536 (2019)
  12. X. Zuo, "Silicon based lithium-ion battery anodes : a chronicle perspective review", Nano Energy, 31, pp.113~143 (2017)
  13. M. Ashuri, "Silicon as a potential anode material for Li-ion batteries: where size, geometry and structure matter", Nanoscale, 8, pp.74~103 (2016)
  14. W. Qi, "Nanostructured anode materials for lithiumion batteries: principle, recent progress and future perspectives", Journal of Materials Chemistry A, 5, pp.19521~19540 (2017)
  15. J. Wan, "Two dimensional silicon nanowalls for lithium ion batteries", Journal of Materials Chemistry A, 2, pp.6051~6057 (2014)
  16. C. K. Chan, "High-performance lithium battery anodes using silicon nanowires", Nature Nanotechnology, 3, pp.31~35 (2008)
  17. J. W. Kim, "Improvement of silicon powder negative electrodes by copper electroless deposition for lithium secondary batteries", Journal of Power Sources, 147, pp.227~233 (2005)
  18. X. Zhu, "Fundamental mechanisms and promising strategies for the industrial application of SiOx anode", Advanced Functional Materials, 33, pp.2213363~ (2023)
  19. R. Wang, "How to promote the industrial application of SiOx anode prelithiation: capability, accuracy, stability, uniformity, cost, and safety", Advanced Energy Materials, 12, pp.2202342~ (2022)
  20. Z. Liu, "Silicon oxides : a promising family of anode materials for lithium-ion batteries", Chemical Society Reviews, 48, pp.285~309 (2019)
  21. Z. Li, "Research progress of SiOxbased anode materials for lithium-ion batteries", Chemical Engineering Journal, 473, pp.145294~ (2023)
  22. J. Entwistle, "A review of magnesiothermic reduction of silica to porous silicon for lithium-ion battery applications and beyond", Journal of Materials Chemistry A, 6, pp.18329~18730 (2018)
  23. B. G. Gribov, "Preparation of highpurity silicon for solar cells", Inorganic Materials, 39, pp.653~662 (2003)
  24. E. K. Richman, "Ordered mesoporous silicon through magnesium reduction of polymer templated silica thin films", Nano Letters, 8, pp.3075~3079 (2008)
  25. X. Liu, "Scalable synthesis of Si nanostructures by lowtemperature magnesiothermic reduction of silica for application in lithium ion batteries", Nano Energy, 4, pp.31~38 (2014)
  26. Z. Bao, "Chemical reduction of three-dimensional silica microassemblies into microporous silicon replicas", Nature, 446, pp.172~175 (2007)
  27. H. Jia, "Novel three-dimensional mesoporous silicon for high power lithium-ion battery anode material", Advanced Energy Materials, 1, pp.1036~1039 (2011)

관련 논문AI추천

환원 공정을 이용한 실리콘 산화물의 제조 및 리튬 이온 배터리 음극재로의 적용석은, 양정윤, 정구환산업기술연구소 · 산업기술연구2024 · 제44권 제1호실리콘-탄소-그래핀 복합체 제조 및 리튬이온 이차전지 응용김선경, 김찬미, 장한권, 장희동한국입자에어로졸학회 · PARTICLE AND AEROSOL RESEARCH2019 · 제15권 제4호Synthesis of nano-scale silicon powder by magnesiothermic reduction for anodes in lithium-ion batteryJu-Chan Kwon, Sang-Jin Lee청정에너지연구소 · Journal of Ceramic Processing Research2024 · 제25권 제6호에틸벤젠을 이용한 실리콘 산화물 음극재의 효과적인 카본 코팅 전략박성수, 이상렬, 채수종한국표면공학회 · 한국표면공학회지2023 · 제56권 제1호Simple Synthesis of SiOx by High-Energy Ball Milling as a Promising Anode Material for Li-Ion Batteries남승훈, 홍성주한국재료부식학회 · CORROSION SCIENCE AND TECHNOLOGY2022 · 제21권 제6호리튬이온이차전지용 고효율 음극(SiO-Graphite)김기원, 김동훈, 김현수, 김효석, 도칠훈, 문성인, 신혜민, 오대희, 진봉수, 하경화한국전기화학회 · 전기화학회지2008 · 제11권 제1호

이 간행물의 다른 논문 (7건)

플라즈마를 이용한 지속가능한 암모니아 수소 생산 기술김태희, 이한준pp. 355-367수계 아연 이차 전지 아연 음극 안정성 및 안전성 향상 전략박종진, 서경태, 김용태pp. 368-378Investigation of Al-Ag thin films for high-performance SAW devices with low insertion loss and high frequency selectivity박재철pp. 379-385Bipolar High-power Impulse Magnetron Sputtering of Ta-W Alloy Film on the Inner Surface of 2,800 mm Stainless-Steel Tube음성현, 한승희, 임상호, 전경호, 한규원pp. 386-397Influence of ZnO Nanoparticle Size on Mitigating SCC in Stainless Steel 304황세훈, 오세권pp. 398-405
원문 보기