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사파이어 화학기계적 연마에서 결정 방향이 재료제거특성에 미치는 영향

Effect of Crystal Orientation on Material Removal Characteristics in Sapphire Chemical Mechanical Polishing

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주제분류기계공학

초록

Sapphire is an anisotropic material with excellent physical and chemical properties and is used as a substrate material in various fields such as LED (light emitting diode), power semiconductor, superconductor, sensor, and optical devices. Sapphire is processed into the final substrate through multi-wire saw, double-side lapping, heat treatment, diamond mechanical polishing, and chemical mechanical polishing. Among these, chemical mechanical polishing is the key process that determines the final surface quality of the substrate. Recent studies have reported that the material removal characteristics during chemical mechanical polishing changes according to the crystal orientations, however, detailed analysis of this phenomenon has not reported. In this work, we carried out chemical mechanical polishing of C(0001), R(1 02), and A(11 0) substrates with different sapphire crystal planes, and analyzed the effect of crystal orientation on the material removal characteristics and their correlations. We measured the material removal rate and frictional force to determine the material removal phenomenon, and performed nano-indentation to evaluate the material characteristics before and after the reaction. Our findings show that the material removal rate and frictional force depend on the crystal orientation, and the chemical reaction between the sapphire substrate and the slurry accelerates the material removal rate during chemical mechanical polishing.

Abstract

Sapphire is an anisotropic material with excellent physical and chemical properties and is used as a substrate material in various fields such as LED (light emitting diode), power semiconductor, superconductor, sensor, and optical devices. Sapphire is processed into the final substrate through multi-wire saw, double-side lapping, heat treatment, diamond mechanical polishing, and chemical mechanical polishing. Among these, chemical mechanical polishing is the key process that determines the final surface quality of the substrate. Recent studies have reported that the material removal characteristics during chemical mechanical polishing changes according to the crystal orientations, however, detailed analysis of this phenomenon has not reported. In this work, we carried out chemical mechanical polishing of C(0001), R(1 02), and A(11 0) substrates with different sapphire crystal planes, and analyzed the effect of crystal orientation on the material removal characteristics and their correlations. We measured the material removal rate and frictional force to determine the material removal phenomenon, and performed nano-indentation to evaluate the material characteristics before and after the reaction. Our findings show that the material removal rate and frictional force depend on the crystal orientation, and the chemical reaction between the sapphire substrate and the slurry accelerates the material removal rate during chemical mechanical polishing.

참고문헌 (11)

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  2. Zhou, P., "Anisotropic Lapping of Single Crystal Sapphire", Advanced Materials Research, 102, pp.502~505 (2010)
  3. Budnikov, A. T., "Anisotropy of sapphire properties associated with chemical mechani-cal polishing with silica", Functional Materials, 17, pp.488~494 (2010)
  4. Wang, Y. G., "On the chemo mechanical polishing for nano-scale surface finish of brittle wafers", Recent Patents on Nanotechnology, 4, pp.70~77 (2010)
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  6. Preston, F. W., "The theory and design of plate glass polishing machines", J. Soc. Glass Tech, 11, pp.214~256 (1927)
  7. 조원석, "사파이어 웨이퍼 DMP에서 마찰력 모니터링을 통한재료 제거 특성에 관한 연구", 한국윤활학회지, 32(2), pp.56~60 (2016), 한국윤활학회[DOI]
  8. Toshiro K. Doi, "Lapping and polishing", Handbook of Ceramic Grinding & Polishing, 354~442 (1999)
  9. Lee, K, Y., "the measurement errors of elastic modulus and hardness due to the different indentation speed", 19, pp.360~364 (2010)
  10. Neeuw, N. H., "Effect of Che-misorption and Physisorption of Water on the Surface Structure and Stability of a-alumina", Journal of the American Ceramic Society, 82, pp.3209~2316 (1999)
  11. Zhou, Y., "AFM and XPS studies on material removal mechanism of sapphire wafer during Chemical Mechanical Polishing (CMP)", Journal of Materials Science : Materials in Electronics, 26, pp.9921~9928 (2015)

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