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전해 이온화와 자외선광을 이용한 사파이어 화학기계적 연마의 재료제거 효율 향상에 관한 기초 연구

Basic Study on the Improvement of Material Removal Efficiency of Sapphire CMP Using Electrolytic Ionization and Ultraviolet Light

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주제분류기계공학

초록

Chemical mechanical polishing (CMP) is a key technology used for the global planarization of thin films in semiconductor production and smoothing the surface of substrate materials. CMP is a type of hybrid process using a material removal mechanism that forms a chemically reacted layer on the surface of a material owing to chemical elements included in a slurry and mechanically removes the chemically reacted layer using abrasive particles. Sapphire is known as a material that requires considerable time to remove materials through CMP owing to its high hardness and chemical stability. This study introduces a technology using electrolytic ionization and ultraviolet (UV) light in sapphire CMP and compares it with the existing CMP method from the perspective of the material removal rate (MRR). The technology proposed in the study experimentally confirms that the MRR of sapphire CMP can be increased by approximately 29.9, which is judged as a result of the generation of hydroxyl radicals (·OH) in the slurry. In the future, studies from various perspectives, such as the material removal mechanism and surface chemical reaction analysis of CMP technology using electrolytic ionization and UV, are required, and a tribological approach is also required to understand the mechanical removal of chemically reacted layers.

Abstract

Chemical mechanical polishing (CMP) is a key technology used for the global planarization of thin films in semiconductor production and smoothing the surface of substrate materials. CMP is a type of hybrid process using a material removal mechanism that forms a chemically reacted layer on the surface of a material owing to chemical elements included in a slurry and mechanically removes the chemically reacted layer using abrasive particles. Sapphire is known as a material that requires considerable time to remove materials through CMP owing to its high hardness and chemical stability. This study introduces a technology using electrolytic ionization and ultraviolet (UV) light in sapphire CMP and compares it with the existing CMP method from the perspective of the material removal rate (MRR). The technology proposed in the study experimentally confirms that the MRR of sapphire CMP can be increased by approximately 29.9, which is judged as a result of the generation of hydroxyl radicals (·OH) in the slurry. In the future, studies from various perspectives, such as the material removal mechanism and surface chemical reaction analysis of CMP technology using electrolytic ionization and UV, are required, and a tribological approach is also required to understand the mechanical removal of chemically reacted layers.

참고문헌 (9)

  1. 이현섭, "화학기계적 연마(CMP) 공정에서의 트라이볼로지 연구 동향", 한국트라이볼로지학회지, 34(3), pp.115~122 (2018), 한국트라이볼로지학회[DOI]
  2. Niu, X., "Method of Surface Treatment on Sapphire Substrate", Trans. Nonferrous Met. Soc. China, 16, pp.732~734 (2006)
  3. 박철진, "염화칼륨 농도에 따른 사파이어 기판 CMP에 관한 연구", 한국트라이볼로지학회지, 33(5), pp.228~233 (2017), 한국트라이볼로지학회[DOI]
  4. Yan, W. -X., "Effect of Abrasive Concentration on Chemical Mechanical Polishing of Sapphire", Chin. Phys. Lett, 32(8), pp.088301~ (2015)
  5. Lee, H., "Macroscopic and Microscopic Investigation on Chemical Mechanical Polishing of Sapphire Wafer", J. Nanosci. Nanotechnol, 12, pp.1256~1259 (2012)
  6. Lee, D., "Surface Activation by Electrolytically Ionized Slurry during Cu CMP", ECS J. Solid Sci. Technol, 8(5), pp.P3053~P3057 (2019)
  7. Lu, J., "Synergistic Effect of Photocatalysis and Fenton on Improving the Removal Rate of 4H-SiC during CMP", ECS J. Solid Sci. Technol, 10(4), pp.044001~ (2021)
  8. Luo, J., "Material removal mechanism in chemical mechanical polishing : theory and modeling", IEEE Trans. Semicon. Manufact, 14, pp.112~133 (2001)
  9. Li, W., "A mechanistic understanding of the degradation of trace organic contaminants by UV", hydrogen peroxide, UV, free chlorine for water reuse, pp.Environ. Sci.: Water Res. Technol, 2017[DOI]

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