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면직물에의 천연 인디고 염색 - 일단계 환원/염색 공정 -

Natural Indigo Dyeing of Cotton Fabric - One-step reduction/dyeing process -

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참고문헌

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초록

The objective of this study is to investigate the characteristics of natural indigo dyeing of cotton fabric. Reduction and dyeing were carried out by one-step process using an infrared dyeing machine at the liquor ratio of 1:100, and subsequently oxidation and washing in water were followed. Dye uptake was increased with the increase of indigo concentration. Over the full range of dyeing tests, the dyeing condition was optimized to 40℃ for 40min. For most of dye concentrations, the cotton fabrics showed mainly PB color. Maximum K/S value was shown at 4g/L of sodium hydrosulfite concentration and the color strength increased with the increase of dye concentration. Value(lightness) decreased with the increase of dye uptake irrespective of mercerization or reduction method, while the mercerized cotton showed two times higher dye uptake than the untreated cotton. Whereas hue of the untreated cotton showed large decrease of P character(5.6~3.5 PB) with the increase of dye uptake, that of the mercerized cotton increased P character(4.7~5.5 PB). Irrespective of mercerization, value and chroma decreased with the increased of dye uptake. In addition, the untreated showed lower chroma than the mercerized cotton. In the case of traditional reduction, hue of the untreated cotton was changed very little with the increase of dye uptake. For hydrosulfite reduction, P character decreased with the increase of dye uptake. The difference of hue value was small with the change of reduction method(hydrosulfite reduction or traditional fermentation). Color character was not influenced by the changed maximum absorption wavelength. Washing fastness showed 4~4/5 shade change rating without any staining. And dry rubbing fastness was good at low color strength. The bacterial reduction ratios of dyed cotton fabric were also increased.

Abstract

The objective of this study is to investigate the characteristics of natural indigo dyeing of cotton fabric. Reduction and dyeing were carried out by one-step process using an infrared dyeing machine at the liquor ratio of 1:100, and subsequently oxidation and washing in water were followed. Dye uptake was increased with the increase of indigo concentration. Over the full range of dyeing tests, the dyeing condition was optimized to 40℃ for 40min. For most of dye concentrations, the cotton fabrics showed mainly PB color. Maximum K/S value was shown at 4g/L of sodium hydrosulfite concentration and the color strength increased with the increase of dye concentration. Value(lightness) decreased with the increase of dye uptake irrespective of mercerization or reduction method, while the mercerized cotton showed two times higher dye uptake than the untreated cotton. Whereas hue of the untreated cotton showed large decrease of P character(5.6~3.5 PB) with the increase of dye uptake, that of the mercerized cotton increased P character(4.7~5.5 PB). Irrespective of mercerization, value and chroma decreased with the increased of dye uptake. In addition, the untreated showed lower chroma than the mercerized cotton. In the case of traditional reduction, hue of the untreated cotton was changed very little with the increase of dye uptake. For hydrosulfite reduction, P character decreased with the increase of dye uptake. The difference of hue value was small with the change of reduction method(hydrosulfite reduction or traditional fermentation). Color character was not influenced by the changed maximum absorption wavelength. Washing fastness showed 4~4/5 shade change rating without any staining. And dry rubbing fastness was good at low color strength. The bacterial reduction ratios of dyed cotton fabric were also increased.

참고문헌 (24)

  1. I.M.Jung, "Dyeing of Silk Fabrics with Natural Indigo Extracted from Polygonum Tinctorium", 박사, pp.1998
  2. J. Y. Kang, "Natural Indigo Dyeing on Protein Fibers", 박사, pp.2001
  3. 박윤점, "쪽 생즙액을 이용한 천연염색에서 염색조건이 견직물의 염색특성에 미치는 영향", 한국자원식물학회지, 18(3), pp.417~8 (2005), 한국자원식물학회
  4. A. S. Kim, "The Study on the Dyeing Properties of Natural Dyeing: Dyeing Properties of Cotton and Silk Fabrics by Color Solution Extracted from Leaf Dyeing of Indigo Plant", Textile Coloration and Finishing, 7, pp.16~24 (1995)
  5. 주정아, "천연 생 쪽잎 추출액을 이용한 셀룰로오스계 섬유의 염색", 한국염색가공학회지, 16(5), pp.19~27 (2004), 한국염색가공학회
  6. A. N. Padden, "An Indigo-reducing Moderate Thermophile from a Woad Vat", Clostridium isatidis sp. nov. Intern, J. Systematic Bacteriology, 49, pp.1025~1031 (1999)
  7. S. K. Nicholson, "The Mechanism of Bacterial Indigo Reduction", Appl. Microbiol. Biotechnol., 68, pp.117~123 (2005)
  8. R. S. Blackburn, "Green Chemistry Methods in Sulfur Dyeing: Application of Various Reducing D-sugars and Analysis of the Importance of Optimum Redox Potential", Environ. Sci. Technol, 38, pp.4034~4039 (2004)
  9. A. Vuorema, "Electrochemical and Sonoelectrochemical Monotoring of Indigo Reduction by Glucose", Dyes and Pigments, 76, pp.542~549 (2008)
  10. A. Roessler, "Electrocatalytic Hydrogenation of Indigo; Process Optimization and Scale-up in a Flow Cell", J. Electrochemical Soc., 150, pp.D1~D5 (2003)
  11. A. Roessler, "Direct Electrochemical Reduction of Indigo", Electrochimica Acta, 47, pp.1989~1995 (2002)
  12. K. G. Stoker, "An Improved Method for the Large-scale Processing of Woad (Isatis tinctoria) for Possible Commercial Production of Woad Indigo", J. Agric. Eng. Res., 71, pp.315~320 (1998)
  13. T. Bechtold, "Process Balance and Product Quality in the Production of Natural Indigo from Polygonum Tinctorium Ait. Applying Low-technology Methods", Bioresource Technology, 81, pp.171~177 (2002)
  14. 신윤숙, "생쪽잎분말의 염색성 및 저장성 (Ⅰ) - 동결건조방법 -", 한국염색가공학회지, 21(1), pp.10~20 (2009), 한국염색가공학회
  15. 신윤숙, "생쪽잎분말의 염색성 및 저장성 (Ⅰ) - 동결건조방법 -", 한국염색가공학회지, 21(1), pp.10~20 (2009), 한국염색가공학회
  16. J. N. Etters, "Equilibrium Sorption Isotherms of Indigo on Cotton Denim Yarn: Effect of pH", Textile Res. J., 61(12), pp.773~776 (1991)
  17. J. H. Xin, "Colour Variation in the Dyeing of Denim Yarn with Indigo", JSDC, 116, pp.260~265 (2000)
  18. M. Gorenšek, "Parameters Influencing Dyeability of Cotton Warp at Dip-dyeing for Jeans", Textile Res. J., 78(6), pp.524~531 (2008)
  19. I. M. Jung, "Effect of Reducing Agent, Sodium Hydrosulfite on the Natural Indigo Dyeing of Silk Fabric", Korean Journal of Sericultural Science, 44(2), pp.93~98 (2002)
  20. Y. J. Jung, "A Study on the Dyeing Properties of Natural Indigo Complex Powder and Synthetic Indigo with Natural Fiber", 한국염색가공학회지, 12(3), pp.16~24 (2000)
  21. E. K. Hwang, "Dyeing on Silk with Vat Dye", Korean J. Seric. Sci, 38(2), pp.168~174 (1996)
  22. A. R. Cho, "A Study on the Natural Fermentation of Natural Indigo Dye", Proc. of Spring Conf. Korean Soc. Clothing Industry, pp.231~234 (2009)
  23. R. S. Blackburn, "The Development of Indigo Reduction Method and Pre-reduced Indigo Products", Color. Technol, 125, pp.193~207 (2009)
  24. K. Iwaki, "Antimicrobial Activity of Polygonum Tinctorium Lour: Extract against Oral Pathogenic Bacteria", J. Nat. Med., 60(2), pp.121~125 (2006)

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