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국내 판매되는 자동차용 엔진오일의 윤활특성 연구

A Study on Lubrication Characteristics of Automotive Engine Oil Merchandised in Domestic

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주제분류기계공학

초록

The effect of oxidation in SAE 5W30 engine oils on friction and wear characteristics was investigated using reciprocating bench tester and shell 4-ball tester. Commercial engine oils were collected and oxidized using the KS M 2021 method modifying the oxidation time. Kinematic viscosity, total acid number(TAN), FT-IR spectrum and total base number(TBN) also measured to examine the chemical change of oils with oxidation. The results showed that TAN was slightly changed and Kinematic viscosity was suddenly increased during the oxidation stage. however, TBN results keep a constant slope after TBN linearly decreased with oxidation time. Spectroscopy results showed that spectrums were orderly increased at 1710cm-1 during the oxidation time. Friction test results showed that oxidation of oils formed unstable friction layers causing higher fluctuating friction. however, the wear resistance was independent of oxidized time due to the different friction characteristics by oxidation. We found several factors in relation to lubrication properties with oxidation time. This factors were Viscosity, TBN, change of FT-IR spectrum, friction coefficient using reciprocating bench tester and wear scar.

Abstract

The effect of oxidation in SAE 5W30 engine oils on friction and wear characteristics was investigated using reciprocating bench tester and shell 4-ball tester. Commercial engine oils were collected and oxidized using the KS M 2021 method modifying the oxidation time. Kinematic viscosity, total acid number(TAN), FT-IR spectrum and total base number(TBN) also measured to examine the chemical change of oils with oxidation. The results showed that TAN was slightly changed and Kinematic viscosity was suddenly increased during the oxidation stage. however, TBN results keep a constant slope after TBN linearly decreased with oxidation time. Spectroscopy results showed that spectrums were orderly increased at 1710cm-1 during the oxidation time. Friction test results showed that oxidation of oils formed unstable friction layers causing higher fluctuating friction. however, the wear resistance was independent of oxidized time due to the different friction characteristics by oxidation. We found several factors in relation to lubrication properties with oxidation time. This factors were Viscosity, TBN, change of FT-IR spectrum, friction coefficient using reciprocating bench tester and wear scar.

참고문헌 (5)

  1. Al-Ghouti, M. A, "Virgin and Recycled Engine Oil Differentiation: A Spectroscopic Study", Journal of Environmental Management, 90, pp.187~195 (2009)
  2. Cerny, J, "Composition and Oxidation Stability of SAE 15W40 Engine Oils", Tribology International, 34, pp.127~134 (2001)
  3. Du, D. C, "Antioxidation Synergism Between ZnDTC and ZnDDP in Mineral Oil", Tribology Letters, 13(1), pp.21~27 (2002)
  4. Hsu, S. M, "Boundary Lubricating Films : Formation and Lubrication Mechanism", Tribology International, 38, pp.305~312 (2005)
  5. McQueen, J. S, "Friction and Wear of Tribofilms Formed by Zinc Dialkyl Dithiophosphate Antiwear Additive in Low Viscosity EngineOils", Tribology International, 38, pp.289~297 (2005)

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