본문 바로가기
KERD
논문KCI 등재

아민화 표면 처리된 면직물의 제독 성능 연구

Detoxification Properties of Surface Aminated Cotton Fabric

0

조회

0

다운로드

2

인용

0

참고문헌

키워드

초록

Pursuing the fabric materials for military chemical warfare protective clothing with the improved detoxification properties, this study investigated the simple and effective cotton treatment method using pad-dry-cure process and 3-aminopropyltrimethoxysilane (APTMS) solution for surface amination. Detoxification properties of the untreated and treated cotton fabrics were evaluated via decontamination of chemical warfare agent simulant, DFP (diisopropylfluorophosphate). The surface aminated cotton fabric increased the rate of the hydrolysis of DFP by the factor of 3 and the decontamination ratio reached 88.2% after 24h. Therefore, the surface amination of the cotton fabric with APTMS can be an effective pathway to prepare the material for protective clothing against chemical warfare agents.

Abstract

Pursuing the fabric materials for military chemical warfare protective clothing with the improved detoxification properties, this study investigated the simple and effective cotton treatment method using pad-dry-cure process and 3-aminopropyltrimethoxysilane (APTMS) solution for surface amination. Detoxification properties of the untreated and treated cotton fabrics were evaluated via decontamination of chemical warfare agent simulant, DFP (diisopropylfluorophosphate). The surface aminated cotton fabric increased the rate of the hydrolysis of DFP by the factor of 3 and the decontamination ratio reached 88.2% after 24h. Therefore, the surface amination of the cotton fabric with APTMS can be an effective pathway to prepare the material for protective clothing against chemical warfare agents.

참고문헌 (19)

  1. K. Ganesan, "Chemical W arfare Agents", Journal of Pharmacy and Bioallied Sciences, 2(3), pp.166~ (2010)
  2. K. Kim, "Destruction and Detection of Chemical Warfare Agents", Chemi cal Reviews, 111(9), pp.3245~ (2011)
  3. F. R. Sidell, "Military Preventive Medicine : Mobilization and Deployment, Volume 1", pp.611~ (1992), Dept. of Defense
  4. M. Boopathi, "A Review on NBC Body Protective Clothing", The Open Textile Journal, 1(1), pp.1~ (2008)
  5. M. Bhuiyan, "Advances and applications of chemical protective clothing sy stem", Journal of Industrial Textiles, 49(1), pp.97~ (2019)
  6. R. T. Delfino, "Organ ophosphorus Compounds as Chemical Warfare Agents: a Re view", Journal of the Brazilian Chemical Society, 20(3), pp.407~ (2009)
  7. 계영식, "유기인 계열 독성화합물 분해를 위한 촉매반응의 최신 연구 동향", 공업화학, 30(5), pp.513~522 (2019), 한국공업화학회[DOI]
  8. 계영식, "Cu(II)-Chitosan Complex의 DFP 분해 반응 연구", 한국군사과학기술학회지, 15(5), pp.699~704 (2012), 한국군사과학기술학회
  9. 계영식, "전이금속촉매를 사용한 DFP 분해 성능 연구", 공업화학, 21(1), pp.1~5 (2010), 한국공업화학회
  10. A. Gugliuzza, "A Review on membrane enginee ring for innovation in wearable fabrics and protective textile s", Journal of Membrane Science, 446, pp.350~ (2013)
  11. 권웅, "키토산 처리 면직물의 군사용 화학 작용제 모사체 분해 연구", 한국염색가공학회지, 32(1), pp.51~56 (2020), 한국염색가공학회[DOI]
  12. S. Kim, "Zirconium Hydroxide-coated Nanofiber Mats for Nerve Agent Decontamination", Chemistry, an Asian Journal, 12(6), pp.698~ (2017)
  13. M. K. Kim, "Deg radation of chemical warfare agents over cotton fabric functi onalized with UiO-66-NH2", RSC Advances, 8(72), pp.41633~ (2018)
  14. S. L. Bartelt-hunt, "A Revie w of Chemical Warfare Agent Simulants for the Study of E nvironmental Behavior", Criticla Reviews in Environmental Sci ence and Technology, 38(2), pp.112~ (2008)
  15. "Nylon-66 Nanofibers", RSC Advances, 7(25), pp.15246~ (2017)
  16. 김윤기, "과산화수소 증기를 이용한 유사화학작용제의 제독", Korean Chemical Engineering Research(HWAHAK KONGHAK), 52(3), pp.360~365 (2014), 한국화학공학회[DOI]
  17. D. B. Dwyer, "Toxic Organophosphate Hydrolysis Using Nanofibe r-Templated UiO-66-NH2 Metal-Organic Framework Polycryst alline Cylinders", Applied Materials and Interfaces, 10(30), pp.25794~ (2018)
  18. T. Yokoi, "Amino-functionalized Mesoporous Silica as Base Catalyst and Adsorbent", Applied Catalyst A: General, 421, pp.14~ (2012)
  19. R. Guo, "Micro wave-Assisted Synthesis of Silver Nanoparticles on Cotton F abric Modified with 3-Aminopropyltrimethoxysilane", Journal of Applied Polymer Science, 130(6), pp.3862~ (2013)

관련 논문AI추천

이 간행물의 다른 논문 (5건)