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군사목적의 유해화학물질 제거용 보호복 소재 제조를 위한 섬유 후가공 처리

Preparation of Self-detoxifying Textile for Removal of Chemical Warfare Agents

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In this report, nano-sized catalysts were introduced onto fabric surface to eliminate toxic chemicals assisted by physical adsorption. For chemical removal of toxic compounds, a series of zirconium-containing catalysts were synthesized and treated on fabric to catalyze the hydrolysis and oxidation of target molecules. Antimicrobial was also introduced for the research purpose to prove the compatibility of as-synthesized catalysts with other solutions. Zirconium ligated with hydroxyl group and MOF(Metal-Organic Frameworks) were exploited as catalyst for removal of toxic compounds, while zinc complex was used for an antimicrobial to culminate in a chemical shield. Once fabrics were functionalized, fabrics were washed 2 or 5 times for a washing durability test. The amount of catalyst in textile were measured by ICP-MS and weight increasing ratio of fabrics.

Abstract

In this report, nano-sized catalysts were introduced onto fabric surface to eliminate toxic chemicals assisted by physical adsorption. For chemical removal of toxic compounds, a series of zirconium-containing catalysts were synthesized and treated on fabric to catalyze the hydrolysis and oxidation of target molecules. Antimicrobial was also introduced for the research purpose to prove the compatibility of as-synthesized catalysts with other solutions. Zirconium ligated with hydroxyl group and MOF(Metal-Organic Frameworks) were exploited as catalyst for removal of toxic compounds, while zinc complex was used for an antimicrobial to culminate in a chemical shield. Once fabrics were functionalized, fabrics were washed 2 or 5 times for a washing durability test. The amount of catalyst in textile were measured by ICP-MS and weight increasing ratio of fabrics.

참고문헌 (22)

  1. S. Bashkova, "The Effects of Urea Modification andHeat Treatment on the Process ofNO2Removal byWood-Based Activated Carbon", J. of Colloid Interface Science, 333, pp.97~ (2009)
  2. M. Seredych, "Reactive Adsorption of Hydrogen Sulfide onGraphiteOxide", Zr(OH)4Composites, 2011, pp.166, 1032~
  3. A. Ahmadpour, "Pore Size Distribution Analysis of Activated Carbons Prepared fromCoconut ShellUsingMethaneAdsorption Data", J. of Physics and Chemistry of Solids, 74, pp.886~ (2013)
  4. M. Seredych, "Role of Microporosity and Surface Chemistry in Adsorption of 4,6-Dimethyldibenzothiophene on Polymer-DerivedActivated Carbons", Fuel, 89, pp.1499~ (2010)
  5. W. Yuan, "Removal ofHydrogen Sulfide from Biogas on Sludge-Derived Adsorbents", Fuel, 86, pp.2736~ (2007)
  6. J. B. D. Coste, "Metal-Organic Frameworks for Air Purification of Toxic Chemicals", Chemical Reviews, 114, pp.5695~ (2014)
  7. E. Barea, "Toxic Gas Removal-Metal-Organic Frameworks for the Capture andDegradation of ToxicGases andVapours", Chemical Society Reviews, 43, pp.5419~ (2014)
  8. G. W. Peterson, "Detoxification of ChemicalWarfareAgents by CuBTC", J. of PorousMaterials, 21, pp.121~ (2014)
  9. A. Roy, "Degradation of Sarin, DECIP and DECNP over Cu-BTC Metal Organic Framework", J. of PorousMaterials, 20, pp.1103~ (2013)
  10. A. Roy, "Kinetics ofDegradation of Sulfur Mustard and Sarin Simulants on HKUST-1 Metal Organic Framework", Dalton Transactions, 41, pp.12346~ (2012)
  11. C. Montoro, "Capture of Nerve Agents and Mustard Gas Analogues byHydrophobicRobustMOF-5 TypeMetalorganic Frameworks", J. of American Chemical Society, 133, pp.11888~ (2011)
  12. L. Bromberg, "Alkylaminopyridine-modified Aluminum Aminoterephthalate Metalorganic Frameworks as Components of Reactive Self-detoxifying Materials", ACS Applied Materials Interfaces, 4, pp.4595~ (2012)
  13. D. T. Lee, "Catalytic “MOF-Cloth” Formed viaDirected Supramolecular Assembly of UiO-66-NH2 Crystals on Atomic LayerDepositionCoated Textiles forRapidDegradation ofChemicalWarfareAgent", Chemistry ofMaterials, 29, pp.4894~ (2017)
  14. G. W. Peterson, "EngineeringUiO-66-NH2 for ToxicGasRemoval", Industrial and Engineering Chemistry Research, 53, pp.701~ (2014)
  15. E. L. Maya, "Textile", MetalOrganic FrameworkComposites as Self-Detoxifying Filters for Chemical Warfare Agents, 2015, pp.54, 6790~
  16. N. S. Bobbit, "Metal-Organic Frameworks for the Removal of Toxic Industrial Chemicals and Chemical Warfare Agents", Chemical Society Reviews, 46, pp.3357~ (2017)
  17. M. J. Katz, "A Textile Coloration and Finishing, Vol. 31, No. 1Facile Synthesis of UiO-66, UiO-67 and Their Derivatives", Chemical Communications, 49, pp.9449~ (2013)
  18. M. Seredych, "Effects of Surface Features on Adsorption of SO2 on Graphite Oxide", Zr(OH)4Composites, 2010, pp.114, 14552~
  19. T. J. Bandosz, "Reactions of VX, GD, and HD with Zr(OH)4: Near InstantaneousDecontamination ofVX", J. of PhysicalChemistry C, 116, pp.11606~ (2012)
  20. I. V. Schweigert, "Hydrolysis of Dimethyl Methylphosphonate by the Cyclic Tetramer of Zirconium Hydroxide", J. of Physical Chemistry A, 121, pp.7690~ (2017)
  21. A. Roy, "Degradation of Sulfur Mustard and 2-Chloroethyl Ethyl Sulfide on Cu-BTCMetal Organic Framework", Microporous andMesoporousMaterials, 162, pp.207~ (2012)
  22. Development ofChemical ProtectiveClothing Incorporated with Self-Detoxifying Nano-Particles, "Y. Han", Agency for Defense Development, ~, pp.Project No. 411665-912412201-722 (2017)

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