기포유동층 열분해로에서 고부가가치 화합물 생성을 위한바이오매스 급속열분해
Fast Pyrolysis of Biomass for Generation of Value Added Chemicals in a Bubbling Fluidized Bed Pyrolyzer
2
조회
0
다운로드
1
인용
0
참고문헌
키워드
초록
Biomass pyrolysis is one of the useful thermal treatment process which can generate solid, liquid and gasphase usable product like fuel and chemical feedstock. In general, it is known that process parameter contained temperature had an effect on yield and chemical composition of bio-oil. Effect of temperature and gas velocity( U0/Umf) on the yield of bio-oil has been determined in a bubbling fluidized bed pyrolyzer. Our study also was focused on the change of bio-fuel composition using GC-MS. The yield of bio-oil was decreased with an increase of pyrolysis temperature and gas velocity. Also it should be noted that our study also focused on the composition change of bio-oil using GC-MS. The oil yield decreased as the pyrolysis temperature and gas velocity was raised over 400 and U0/Umf=3.0. The maximum yield of bio-oil was as follows; Quercus Acutissima= 58%, Larix Leptolepis=55% and sewage sludge=56%. And, value added chemicals such as pyrocatechol, guaiacol, syringol and levoglucosan was existed in bio-oil generated from biomass pyrolysis.
Abstract
Biomass pyrolysis is one of the useful thermal treatment process which can generate solid, liquid and gasphase usable product like fuel and chemical feedstock. In general, it is known that process parameter contained temperature had an effect on yield and chemical composition of bio-oil. Effect of temperature and gas velocity( U0/Umf) on the yield of bio-oil has been determined in a bubbling fluidized bed pyrolyzer. Our study also was focused on the change of bio-fuel composition using GC-MS. The yield of bio-oil was decreased with an increase of pyrolysis temperature and gas velocity. Also it should be noted that our study also focused on the composition change of bio-oil using GC-MS. The oil yield decreased as the pyrolysis temperature and gas velocity was raised over 400 and U0/Umf=3.0. The maximum yield of bio-oil was as follows; Quercus Acutissima= 58%, Larix Leptolepis=55% and sewage sludge=56%. And, value added chemicals such as pyrocatechol, guaiacol, syringol and levoglucosan was existed in bio-oil generated from biomass pyrolysis.
참고문헌 (15)
- 산림청, "임업통계연보", 34~ (2004)
- 산업자원부, "에너지 총조사", 1~ (2004)
- 유홍정, "HDPE의 열분해에 의한 액화 특성", 폴리머, 27(1), pp.84~89 (2003), 한국고분자학회
- K. Sipila, , Biomass and Bioenergy, 14(2), pp.103~111 (1998)
- S. Ergun, , Chem. Eng. Prog, 48, pp.89~ (1952)
- A.V. Bridgwater, , Renewable and Sustainable Energy Reviews, 4(1), pp.119~127 (2000)
- P.T. Williams, , Renewable Energy, 7(3), pp.233~250 (1996)
- T. Karayildirim, , Henning Bockhorn Fuel, 85, pp.1498~1508 (2006)
- J. Piskorz, , J. Anal. Appl. Pyrolysis, 46, pp.15~29 (1998)
- Z. Luo, , Biomass and Bioenergy, 26, pp.455~462 (2004)
- A. Vuori, , Ind. Eng. Chem. Res, 26, pp.359~365 (1987)
- C.P. Masuku, , Holzfoschung, 45, pp.181~190 (1991)
- H.E. Jerger, , Ind. Eng. Chem. Process. Des, 24, pp.173~183 (1985)
- D. S. Scott, , J. Piskorz Can. J. Chem. Eng, 62, pp.404~ (1984)
- A. H. Horne, , Fuel, 75, pp.1051~ (1996)
