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농약 숙련도 시험용 농약 표준시료(PTMs) 제조방법 확립 및 적용성 평가

Development of Proficiency Testing Scheme on Pesticide Residues in Crops for Testing Institute

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초록

This paper reports the establishment of a proficiency testing (PT) scheme for pesticide residue in crops using relevant international standards (KS Q ISO 13528 & ISO/IEC 17043). The proficiency testing materials (PTMs) are made from freeze-dried Welsh onion powder spiked with the pesticide Procymidone. The results of the analysis were reported by 25 participating organizations and evaluated via Horwitz standard deviation and zscore. The histogram and box plot of the Procymidone analyses clearly show that 22 (88%) of the 25 participating organizations can be approved as qualified test institutions for Procymidone residue analysis in crops.

Abstract

This paper reports the establishment of a proficiency testing (PT) scheme for pesticide residue in crops using relevant international standards (KS Q ISO 13528 & ISO/IEC 17043). The proficiency testing materials (PTMs) are made from freeze-dried Welsh onion powder spiked with the pesticide Procymidone. The results of the analysis were reported by 25 participating organizations and evaluated via Horwitz standard deviation and zscore. The histogram and box plot of the Procymidone analyses clearly show that 22 (88%) of the 25 participating organizations can be approved as qualified test institutions for Procymidone residue analysis in crops.

참고문헌 (17)

  1. Understanding and acting on scores obtained in proficiency testing schemes, "Analytical Methods Committee", ~, pp.AMC Technical Brief No. 11 (2002)
  2. Analytical Methods Committee, "Test for ‘sufficient homogeneity’ in a reference material", AMC Recommendation No.1, ~ (2004)
  3. The amazing Horwitz function, "Analytical Methods Committee", ~, pp.AMC Technical Brief No.17 (2004)
  4. Analytical Methods Committee, "General and specific fitness functions for proficiency tests and other purposes clarifying an old idea", AMC Recommendation No.2, ~ (2005)
  5. The duplicate method for the estimation of measurement uncertainty arising from sampling, "Analytical Methods Committee", ~, pp.AMC Technical Brief No. 40 (2009)
  6. 홍석영, "토양 숙련도 시험용 금속 표준시료(PTMs) 제조방법 확립 및 적용성 평가", 한국환경분석학회지, 19(2), pp.126~134 (2016), 한국환경분석학회
  7. 김찬섭, "가스크로마토그래피를 이용한 토양 중 프로사이미돈과 클로르피리포스, 메톨라클로르의 잔류분석 숙련도시험", 농약과학회지, 17(2), pp.94~106 (2013), 한국농약과학회[DOI]
  8. C. Micó, "Assessing heavy metal sources in agricultural soils of an European Mediterranean area by multivariate analysis", Chemosphere, 65, pp.863~872 (2006)
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  10. "ISO 13528, Statistical methods for use in proficiency testing interlaboratory comparisons", ~ (2015)
  11. "ISOGuide 35, Reference materials - General and statistical principle for Certification", ~ (2006)
  12. "ISO", IEC 17043 Conformity assessment-General requirements for proficiency testing, 2010
  13. "ISO", IEC Guide 43-2, Proficiency testing by interlaboratory comparisons-Part 2: Selection and use of proficiency testing schemes by laboratory accreditation bodies, 1997
  14. "ISO", IEC 5725-2, Accuracy of measurement methods and results-part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method, 2002
  15. "ISO", CEI, pp.2008, ~
  16. "The international harmonized protocol for the proficiency testing of analytical chemistry laboratories (IUPAC Technical Report)", Pure Appl. Chem, 78, pp.145~196 (2006)
  17. 국립환경과학원, "환경측정분석 정도관리를 위한 표준물질제조 및 보급–토양분석용 중금속 표준물질", ~ (2008)

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