경기 남부 폐수처리시설의 노닐페놀, 옥틸페놀 배출특성
Characteristics of Nonylphenol and Octylphenol Discharge fromWastewater Treatment Facilities in Southern Gyeonggi-do
2
조회
0
다운로드
1
인용
0
참고문헌
키워드
초록
This study aimed to evaluate the discharge characteristics of nonylphenol (NP) and octylphenol (OP) in the effluent of wastewater treatment facilities in the southern Gyeonggi-do. The detection rates of NP and OP were found to be 39.3% and 43.1%, respectively, with median values ranging from 1 to 3 μg/L across all industries. The industries that showed a detection rate of 50% or more were car wash, chemical experiment, fabric leather, paper wood, and plating facilities, with rates ranging from 50% to 75%, while other industries had detection rates of 21.7% to 36.8%. In terms of facility size, small-size establishments such as Type 4 and Type 5 showed higher detection rates in the "Na" region where somewhat relaxed standards are applied on a regional basis. This is because the proportion of Type 4 and Type 5 industries, including various concentration distributions of chemical experiments, research facilities, car washes, petrochemical, and plating industries, is higher than 77.7% overall and concentrated at a rate of 55.6% or higher in the “Na” region. Furthermore, the correlation coefficient (R) between NP and OP exhibited moderate association with values of 0.45 and 0.60 for car washes and plating industries, respectively. Chemical experiments, paper and wood, electrical and electronic, and medicine and hospital facilities showed strong association with correlation coefficients of 0.83, 0.82, 0.82, and 0.79, respectively. The findings in this study can be expected to serve as fundamental data for NP and OP in the establishment of water quality pollutants designation and discharge standards (draft) currently being pursued.
Abstract
This study aimed to evaluate the discharge characteristics of nonylphenol (NP) and octylphenol (OP) in the effluent of wastewater treatment facilities in the southern Gyeonggi-do. The detection rates of NP and OP were found to be 39.3% and 43.1%, respectively, with median values ranging from 1 to 3 μg/L across all industries. The industries that showed a detection rate of 50% or more were car wash, chemical experiment, fabric leather, paper wood, and plating facilities, with rates ranging from 50% to 75%, while other industries had detection rates of 21.7% to 36.8%. In terms of facility size, small-size establishments such as Type 4 and Type 5 showed higher detection rates in the "Na" region where somewhat relaxed standards are applied on a regional basis. This is because the proportion of Type 4 and Type 5 industries, including various concentration distributions of chemical experiments, research facilities, car washes, petrochemical, and plating industries, is higher than 77.7% overall and concentrated at a rate of 55.6% or higher in the “Na” region. Furthermore, the correlation coefficient (R) between NP and OP exhibited moderate association with values of 0.45 and 0.60 for car washes and plating industries, respectively. Chemical experiments, paper and wood, electrical and electronic, and medicine and hospital facilities showed strong association with correlation coefficients of 0.83, 0.82, 0.82, and 0.79, respectively. The findings in this study can be expected to serve as fundamental data for NP and OP in the establishment of water quality pollutants designation and discharge standards (draft) currently being pursued.
참고문헌 (33)
- "내분비계장애물질이란?" (2022), 환경부[URL]
- 더러운 빨래(Dirty Laundry), , 2012
- J. Dachs, "Occurrence of estrogenic nonylphenols in the urban and coastal atmosphere of the lower hudson river estuary", Environmental Science & amp; Technology, 33(15), pp.2676~2679 (1999)
- M. Hawrelak, "The Environment fate of the primary degradation products of alkylphenol ethoxylate surfactants in recycled paper sludge", Chemosphere, 39(5), pp.745~752 (1999)
- T. Leatherland, "An environment assessment of alkylphenol ethoxylates and alkylphenols", The Journal of Applied Ecology, pp.890~890 (1995)
- OSPAR Commission, "Nonylphenol", nonylphenolethoxylate, 2001
- 엄정훈, "LC-MS-MS를 이용한 전통 활성슬러지 공정과 생물학적 영양염류 제거 공정의 슬러지 중 NP2EO 및 OP2EO의 분석", 환경분석과 독성보건, 12(3), pp.159~166 (2009), 한국환경분석학회
- 김협, "GC", MS-SIM을 이용한 우리나라 수중 생물시료 중 알킬페놀, 클로로페놀과 비스페놀 A의 분석을 위한 냉동필터법의 응용, 2007, pp.29(6), 689~698[DOI]
- 김협, "기체 크로마토그래피", 질량분석기를 이용한 종이류 중 알킬페놀류, 클로로페놀류 및 비스페놀 A 정량, 2003, pp.18(1), 45~55[DOI]
- D. T. Bennie, "Review of the environmental occurrence of alkylphenols and alkylphenol ethoxylates", Water Quality Research Journal, 34(1), pp.79~122 (1999)
- 김명길, "알킬페놀 화합물의 HeLa cell (HL-60)의 세포독성에 대한 QSAR 연구", 환경독성보건학회지, 18(4), pp.271~276 (2003), 환경독성보건학회
- 식품의약품안전청, "식품 중 알킬페놀류란?", ~ (2007)
- F. S. V. Saal, "A physiologically based approach to the study of bisphenol A and other estrogenic chemicals on the size of reproductive organs, daily sperm production, and behavior", Toxicology and Industrial Health, 14(1-2), pp.239~260 (1998)
- 환경부, "수질오염물질 지정 등에 관한 지침", 환경부훈령 제1558호, ~ (2022)
- "US environmental protection agency" (2022)[URL]
- European environment agency, "Directive 2008", 105 EC of the european parliament and of the council of 16december 2008 on environmental quality standards in the field of water policy; environmental quality standards for priority substances and certain other pollutants - Part A: environmental quality standards (EQS), 2008, pp.92~94
- "일본 환경성 (日本 環境省)" (2022)[URL]
- Canadian Council of Ministers of the Environment, "Canadian environmental quality guidelines; canadian water quality guidelines for the protection of aquatic life-nonylphenol and its ethoxylates", ~ (2002)
- 신규 수질유해물질 적정 처리기술 및 관리방안 연구(II), "국립환경과학원", ~ (2013)
- 수질 및 수생태계 환경기준 개선연구, "환경부", ~ (2017)
- 수질오염물질 지정 및 적정 관리방안 연구, "환경부", ~ (2020)
- 김협, "GC", MS-SIM 방법에 의한 수돗물 중 알킬페놀, 클로로페놀과 비스페놀 A의 ppt 정량, 2003, pp.18(3), 199~208[DOI]
- 김종훈, "GC", MS-SIM에 의한 하수슬러지 중에 포함된 Octylphenol, Nonylphenol, Di-octylphthalate의 정량, 1999, pp.12(3), 248~255
- 김선영, "수영강 하류의 노닐페놀 분포 및 물질수지에 관한 연구", 석사, 생태공학과, pp.2012
- 민혜주, "낙동강 중류수계에서 비스페놀A와 노닐페놀의 분포와 제거특성에 관한 연구", 석사, 환경공학과 환경공학전공, pp.2013
- 이빛나, "서울 거주 산모의 초유 중 노닐페놀 분석을 통한 인체노출평가", 환경독성보건학회지, 23(2), pp.113~117 (2008), 환경독성보건학회
- 2017년 화학물질 배출량 조사결과, "환경부", ~ (2019)
- 김요용, "산업폐수 수질오염물질의 환경기준 적용 해설서", 경기도보건환경연구원, 환경자료, pp.산업폐수 수질오염물질의 환경기준 적용 해설서, 2020[DOI]
- 환경부, "수질오염공정시험기준", ~ (2022)
- 환경부, "수질오염물질 감시항목 검사계획, 붙임1(감시항목 고농도 배출업종)", ~ (2021)
- 노닐페놀 취급제한물질로 지정 추진, "환경부", ~ (2006)
- 유독물질 및 제한물질·금지물질의 지정고시-규제영향분석서, "환경부", ~ (2016)
- 환경부, "중점관리물질의 지정", 환경부 고시제2018-233호, ~ (2018)
