단일 ZnO 나노선의 광전 특성에 대한 에이징 효과
Effect of aging on the optoelectronic properies of a single ZnO nanowire
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본 연구는 단일 ZnO 나노선의 광전 특성에 대한 에이징(aging) 효과에 관한 것이다. 합성 직후의 ZnO 나노선에 대하여 photoluminescence (PL), 광전류 스펙트럼, 전류-전압 특성 및 광응답 특성들을 측정하였고, ZnO 나노선을 3달 동안 공기 중에 노출시킨 후에 위의 실험을 반복하였다. 에이징된 나노선은 합성 직후의 나노선과 비교하여 넓은 영역의 PL 밴드는 약해졌고, 광전류의 크기는 증가하였으며, 광응답 속도는 느려졌다. 본 연구에서 PL를 통해 관찰된 에이징 효과는 나노선 내부에 산소 공극의 수가 감소함으로 인한 것이며, 광전류와 광응답 특성에서 에이징 효과는 나노선 표면 부근에 산소 공극의 형성으로 인한 것이다.
Abstract
The effect of aging on theoptoelectronic properties of a single ZnO nanowire is investigated in this study. The photoluminescence (PL), photocurrent spectrum, current-voltage characteristics, and photoresponse were measured for the as-grown ZnO nanowire and for the same nanowire exposed to air for three months. For the aged nanowire, the broad PL band is weaker, the intensity of the photocurrent is strengthened, and the photoresponse is slower, compared with the as-grown nanowire. It is suggested in this paper that the observed aging effect on the PL is due to the reduction in the number of oxygen vacancies within the nanowire and that the aging effect on the photocurrent and photoresponse originates from the formation of oxygen vacancies near the surface.
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