식물에서 추출한 살충∙살균제가 문화재의 재질에 미치는 영향 - 견직물, 면직물, 저마직물, 한지, 안료분말, 채색편 -
The Effects of Various Vegatable Pesticides on Materials of Cultural Property - Dyed and Undyed Silk Fabrics, Cotton Fabrics and Korean Papers, Undyed Ramie Fabric, Pigments, Painted Plates -
0
조회
0
다운로드
10
인용
0
참고문헌
키워드
초록
문화재의 생물방제를 목적으로 개발되어 시판되고 있는 3종의 식물 추출 천연 살충∙살균제에 대한 문화재의 재질에 미치는 영향을 평가하였다. 평가 대상 재질은 1) 견직물 : 염색하지 않은 견직물, 황벽, 오배자, 오배자(명반 후매염), 오배자(녹반 후매염), 치자, 울금, 도토리, 도토리(녹반 후매염), 자초, 천근, 천근(명반 후매염), 홍화(홍염색), 소목, 소목(명반 선매염, 후매염) 염색 및 쪽, 쪽과 황벽 복염, 쪽과 소목 복염 견직물 2) 면직물 : 염색하지 않은 면직물, 황벽, 오배자, 오배자(명반 후매염), 치자, 도토리, 도토리(녹반 후매염), 자초, 천근, 천근(명반후매염), 홍화(홍염색), 소목, 소목(명반 선매염, 후매염) 염색 및 쪽, 쪽과 소목 복염 면직물, 3) 염색하지 않은 저마직물 4) 한지 : 염색하지 않은 한지, 소목, 쪽, 치자, 홍화(홍염색), 황벽 염색 한지 5) 안료 분말 : 석청, 석록, 연단, 석간주, 주사, 주, 패각호분, 밀타승, 대자, 석황, 쪽, 백토, 연백, 남전 6) 채색편 : 석청, 석록, 연단, 석간주, 주사, 주, 패각호분, 밀타승, 대자, 석황, 쪽, 백토, 연백, 남전이다. 시험은 시료를 습도 55±1%, 온도 20±2℃의 환경에서 약제의 권장 농도의 10배에 9개월간 노출 시킨 후 기준 시료와의 색차와 인장강도를 비교 평가하였다. 약제노출 후 염색을 하지 않은 견직물∙면직물∙저마직물∙한지는 약제에 의한 색상 변화는 거의 일어나지 않았으나, 염색 견직물∙면직물∙한지는 도토리나 천근 염색 직물 등이나 치자 염색 한지를 제외하고는 대부분 일반인도 인식이 가능한 뚜렷한 색상차가 발생하였다. 특히 울금 염색 견직물은 가장 색상차가 뚜렷하였다. 그리고 안료분말이나채색편은 납, 구리, 비소, 수은 함유 안료 및 식물성 안료 등에서 뚜렷한 색상차가 발생하였다. 인장강도는 염색하지않은 견직물은 약제에 거의 변화가 없으며 면직물은 약간 감소하는 경향을 보이나, 염색을 한 견직물이나 면직물은강도의 증가나 감소가 뚜렷하였다. 특히 천근 염색 견직물은 10% 이상의 강도 감소가, 쪽 염색 견직물은 10% 이상의 강도 증가가 일어났으며, 천근과 소목(명반 후매염) 염색 면직물은 10% 이상의 강도 감소 현상이 일어났다.
Abstract
Three kinds of natural pesticides extracted from plants which are being sold in the Korean markets, were estimated effects on materials of art of museum. Tested samples were 1) silk fabrics : undyed, dyed(amur cork tree, gallut, gallut(alum post mordancy), gallut(copperas post mordancy), gardenia, turmeric, acorn, acorn(copperas post mordancy), gromwell, madder, madder(alum post mordancy), safflower, sappanwood, sappanwood(alum pre mordancy, post mordancy), indigo, indigo+amur cork tree, indigo+sappanwood) 2) cotton fabrics : undyed, dyed(amur cork tree, gallut, gallut(alum post mordancy), gardenia, acorn, acorn(copperas post mordancy), gromwell, madder, madder(alum post mordancy), safflower, sappanwood, sappanwood(alum pre mordancy, post mordancy), indigo, indigo+sappanwood) 3) undyed ramie fabric 4) Korean papers : undyed, dyed(sappanwood, indigo, gardenia, amur cork tree, safflower) 5) pigments : azurite, malachite, red lead, litharge, orpiment, hematite, iron oxide, cinnabar, vermilion, indigo, lake indigo, kaolin, lead white, oyster shell white 6) painted plates : azurite, malachite, red lead, litharge, orpiment, hematite, iron oxide, cinnabar, vermilion, indigo, lake indigo, kaolin, lead white, oyster shell white. Conditions of tests were that after samples were exposed to 10 times of promoted concentration for 9 months in relative humidity 55±1% and temperature 20±2℃, they were compared with standards. Items of estimation were color difference(E*) and tenacity. After exposure to pesticides, undyed silk∙cotton∙ramie fabrics and Korean papers were not nearly changed in their colors, but colors of most of dyed samples were clearly changed by pesticides except for partial samples(acorn- and madder-dyed fabrics etc, gardenia-dyed samples). Especially changes of colors of turmeric-dyed silk fabrics were most distinct. And colors of pigments and painted plates containing lead, copper, arsenic, mercury and vegetable pigments, were clearly changed. Tenacities of yarns of undyed silk fabrics were not nearly changed and undyed cotton fabrics were a little reduced as compared with standards. But tenacities of yarns of dyed silk and cotton fabrics were clearly reduced or increased as compared with standards. Especially, madder-dyed silk fabrics were increased 10% or more and indigo-dyed silk fabrics were reduced 10% or less in all pesticides. Also madder- and sappanwood(alum post mordancy)-dyed cotton fabrics were increased 10% or more in all pesticides.
참고문헌 (23)
- H. Mabuchi, "A Review on", 47, pp.103~118 (2003)
- C. Selwits, "Inert Gases in theControl of Museum Insect Pests" (1998), The GettyConservation Institute, Los Angeles
- C. P. Smith, "TheFumigant of the Future International Seminaron Research in Preservation and Conservation" (1991), Columbia University
- H. Tanimura, "The FreezingMethods for Eradiation of Museum Pest Insects- The Safe Method for Both the Human Bodyand Artifacts. Experiment on Japanese Artifactsand the Present State of the Freezing Methodsin Western Countries", 3, pp.555~566 (1995)
- T. J. K. Strang, "Effect of Thermal Methodsof Pest Control on Museum Collections", 3, pp.334~353 (1995)
- R. Kigawa, "A Review on Integrated PestManagement in Museums and RelatedInstitutions : Basic Concepts and Practical Stepsfor Introduction", 47, pp.76~102 (2003)
- 국립민속박물관, "2005년, 2006년 해충모니터링 보고서" (2006)
- 배현숙, "“조선조 사고의 장서관리”", pp.~56 (1978)
- H. Mori, "“On the Damages toAntiques and Art Crafts by Several FumigantsII. Effects of Fumigants uppon Different Kindsof Pigments”", pp.~28 (1955)
- L. A.Zycherman, "A Guide to Museum Pest Control Foundation ofthe American Institute for Conservation ofHistoric and Artistic Works and Association ofSystematics Collections" (1988)
- H. Mori, "“On the Damages toAntiques and Art Crafts by Several FumigantsI. Effects of Fumigants uppon Different Kindsof Metals”", pp.~12 (1955)
- “EthyleneChlorohydrin, "IndianJournal of Pharmaceutical Science", (g. s. gopal), pp.~114 (1979)
- M. T. Baker, "LaboratoryInvestigation of the Vikan", pp.~811 (1990)
- R. Kigawa, "Evaluation of the effects of variouspest controlling reagents on pigments and metals:effects of pesticides, fumigants, carbondioxide and nitrogen", 43, pp.12~21 (1999)
- K. Yamano, "An Introduction of Control of Pestsand Fungi for Cultural Properties Measures ofControl of Pests for Cultural Properties", pp.~84 (1991)
- H. Mori, "“ The Effects of DDVP of Vapor StripePesticide on Metals", pp.~75 (1972), KeioUniversity Hiyoshironbunshu Shizenkagakuhen
- H. Mori, "The Efficacy of Pesticides andFungicides and Effects to Meterials of CulturalProperties Science of Hyougu Tokyo NationalResearch Institute of Cultural Properties", pp.~149 (1977)
- E. Koseto, "The Effects of Formaldehyde onMaterials of Arts" (1997)
- C. Sano, "Changes incolor of Natural Rock Pigments and Lead-containingGlass Pigments Used for JapanesePaintings Induced by Germicide and ItsMechanism", 42, pp.57~62 (2003)
- M. Han, "Studies on Repellent Effects of naturalMedical Herbs Used in Preservation of ObjectsMade from Plant Fibers" (1998)
- 정용재, "천연약재로부터 문화재보존용 방충방균제 개발 연구", 21, pp.5~25 (2001)
- 노현숙, "방충.방균제로 인한 천연염색 한지의 색변화", 6, pp.39~46 (2005)
- Gillian Bott, "Amylase for Starch Removal froma Set of 17th Century Embroidered Panels", 14, pp.23~29 (2007)