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Use of Capparis decidua Extract as a Green Inhibitor for Pure Aluminum Corrosion in Acidic Media

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주제분류금속공학

초록

The aim of this paper is to study corrosion inhibition of Aluminum with Capparis decidua extract. The study was performed in a 1.0 M solution of hydrochloric acid (HCl) and was monitored both by measuring mass loss and by using electrochemical and polarization methods. A scanning electron microscopy (SEM) technique was also applied for surface morphology analysis. The results revealed high inhibition efficiency of Capparis decidua extract. Our data also determined that efficiency is governed by temperature and concentration of extract. Optimum (88.2%) inhibitor efficiency was found with maximum extract concentration at 45 oC. The results also showed a slight diminution of aluminum dissolution when the temperature is low. Based on the Langmuir adsorption model, Capparis decidua adsorption on the aluminum surface shows a high regression coefficient value. From the results, the activation enthalpy (ΔH#) and activation entropy (ΔS#) were estimated and discussed. In conclusion, the study clearly shows that Capparis decidua extract acted against aluminum corrosion in acidic media by forming a protective film on top of the aluminum surface.

Abstract

The aim of this paper is to study corrosion inhibition of Aluminum with Capparis decidua extract. The study was performed in a 1.0 M solution of hydrochloric acid (HCl) and was monitored both by measuring mass loss and by using electrochemical and polarization methods. A scanning electron microscopy (SEM) technique was also applied for surface morphology analysis. The results revealed high inhibition efficiency of Capparis decidua extract. Our data also determined that efficiency is governed by temperature and concentration of extract. Optimum (88.2%) inhibitor efficiency was found with maximum extract concentration at 45 oC. The results also showed a slight diminution of aluminum dissolution when the temperature is low. Based on the Langmuir adsorption model, Capparis decidua adsorption on the aluminum surface shows a high regression coefficient value. From the results, the activation enthalpy (ΔH#) and activation entropy (ΔS#) were estimated and discussed. In conclusion, the study clearly shows that Capparis decidua extract acted against aluminum corrosion in acidic media by forming a protective film on top of the aluminum surface.

참고문헌 (40)

  1. D. Costa, "DFT Modeling of Corrosion Inhibition by Organic Molecules: Carboxylates as Inhibitors of Aluminum Corrosion", The Journal of Physical Chemistry C, 120(50), pp.28607~28616 (2016), American Chemical Society (ACS)[DOI]
  2. G. T. Hefter, "Organic Corrosion Inhibitors in Neutral Solutions; Part 1 — Inhibition of Steel, Copper, and Aluminum by Straight Chain Carboxylates", CORROSION, 53(8), pp.657~667 (1997), NACE International[DOI]
  3. Thomas Stimpfling, "Phosphate‐Based Organic Molecules Interleaved with Layered Double Hydroxide: Unraveling the Roles of Host Cations and the Guest‐Inhibiting Effect in Aluminum Corrosion Protection", European Journal of Inorganic Chemistry, 2012(32), pp.5396~5404 (2012), Wiley[DOI]
  4. M. Metikos-Hukovic, "Corrosion protection of aluminium in acidic chloride solutions with nontoxic inhibitors", Journal of Applied Electrochemistry, 28, pp.433~ (1998)
  5. S. Kaya, "Theoretical evaluation of some benzotriazole and phospono derivatives as aluminum corrosion inhibitors: DFT and molecular dynamics simulation approaches", RSC Advances, 6, pp.74550~ (2016)
  6. Serpil Şafak, "Schiffbases as corrosion inhibitor for aluminium in HCl solution", Corrosion Science, 54, pp.251~259 (2012), Elsevier BV[DOI]
  7. Demian I. Njoku, "Natural products for materials protection: Corrosion protection of aluminium in hydrochloric acid by Kola nitida extract", Journal of Molecular Liquids, 219, pp.417~424 (2016), Elsevier BV[DOI]
  8. O. Abiola, "Ecofriendly corrosion inhibitors: The inhibitive action of Delonix Regia extract for the corrosion of aluminium in acidic media", Anti-Corrosion Methods and Materials, 54, pp.54~ (2007)[DOI]
  9. G. Avwiri, "Inhibitive action of Vernonia amygdalina on the corrosion of aluminum alloys in acidic media", Materials Letters, 57, pp.3705~ (2003)
  10. M.A. Deyab, "Corrosion inhibition of aluminum in biodiesel by ethanol extracts of Rosemary leaves", Journal of the Taiwan Institute of Chemical Engineers, 58, pp.536~541 (2016), Elsevier BV[DOI]
  11. A.A. El Hosary, "Corrosion inhibition by naturally occurringsubstances—I. The effect of Hibiscus subdariffa (karkade) extract on the dissolution of Al and Zn", Corrosion Science, 12(12), pp.897~904 (1972), Elsevier BV[DOI]
  12. Olusegun K. Abiola, "Effect of common water contaminants on the corrosion of aluminium alloys in ethylene glycol–water solution", Corrosion Science, 50(1), pp.242~247 (2008), Elsevier BV[DOI]
  13. A.R. Yazdzad, "Inhibition of 3003 aluminum alloy corrosion by propargyl alcohol and tartrate ion and their synergistic effects in 0.5% NaCl solution", Materials Chemistry and Physics, 109(2-3), pp.199~205 (2008), Elsevier BV[DOI]
  14. G Gunasekaran, "Eco friendly inhibitor for corrosion inhibition of mild steel in phosphoric acid medium", Electrochimica Acta, 49(25), pp.4387~4395 (2004), Elsevier BV[DOI]
  15. M. Abu-Dalo, "Exudate Gum from Acacia Trees as Green Corrosion Inhibitor for Mild Steel in Acidic Media", International Journal of Electrochemical Science, 7, pp.9303~ (2012)[DOI]
  16. M. Doche, "Inhibition of Corrosion of Aluminium in NaOH Solution by Leave Extract of Mesembryanthemum nodiflorum", Corrosion Science, 41, pp.805~ (2007)
  17. M. Al-Abdallah, "Corrosion Behavior of Copper in Chloride Media", The Open Corrosion Journal, 2, pp.71~ (2009)[DOI]
  18. N.C. Subramanyam, "Thiourea and substituted thioureas as corrosion inhibitors for aluminium in sodium nitrite solution", Corrosion Science, 34(4), pp.563~571 (1993), Elsevier BV[DOI]
  19. P. Okafor, "Inhibition of mild steel corrosion in acidic medium by Allium sativum extracts", Bulletin of Electrochemistry, 21, pp.347~ (2005)
  20. A.K. Maayta, "Inhibition of acidic corrosion of pure aluminum by some organic compounds", Corrosion Science, 46(5), pp.1129~1140 (2004), Elsevier BV[DOI]
  21. N.A.F. Al‐Rawashdeh, "Cationic surfactant as corrosion inhibitor for aluminum in acidic and basic solutions", Anti-Corrosion Methods and Materials, 52(3), pp.160~166 (2005), Emerald[DOI]
  22. A. A. Rousan, "Magnetic field effects on inhibition of aluminium corrosion by cationic surfactant in acidic solution", Corrosion Engineering, Science and Technology, 41(3), pp.235~239 (2006), Informa UK Limited[DOI]
  23. A. Maayta, "The Inhibiting Effects of Alkyl Benzene Sulphonate and the Magnetic Field on Aluminum Corrosion in Acidic Solution", Jordan Journal of Chemistry, 5, pp.175~ (2010)
  24. RAJA Pandian Bothi, "Inhibitory Effect of Kopsia Singapurensis Extract on the Corrosion Behavior of Mild Steel in AcidMedia", Acta Physico-Chimica Sinica, 26(08), pp.2171~2176 (2010), Acta Physico-Chimica Sinica & University Chemistry Editorial Office, Peking University[DOI]
  25. Emeka E. Oguzie, "Studies on the inhibitive effect of Occimum viridis extract on the acid corrosion of mild steel", Materials Chemistry and Physics, 99(2-3), pp.441~446 (2006), Elsevier BV[DOI]
  26. E. Oguzi, "Corrosion Inhibitive Effect and Adsorption Behaviour of Hibiscus Sabdariffa Extract on Mild Steel in Acidic Media", Port Electrochim Acta, 26, pp.303~ (2008)[DOI]
  27. El-Sayed M. Sherif, "Inhibition of copper corrosion in acidic chloride pickling solutions by 5-(3-aminophenyl)-tetrazole as a corrosion inhibitor", Corrosion Science, 50(12), pp.3439~3445 (2008), Elsevier BV[DOI]
  28. E.E. Oguzie, "Inhibitory mechanism of mild steel corrosion in 2M sulphuric acid solution by methylene blue dye", Materials Chemistry and Physics, 89(2-3), pp.305~311 (2005), Elsevier BV[DOI]
  29. A. Popova, "AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives", Corrosion Science, 45(1), pp.33~58 (2003), Elsevier BV[DOI]
  30. L. Nnanna, "Inhibition effects of some plant extracts on the acid corrosion of aluminium alloy", African Journal of Pure and Applied Chemistry, 4, pp.11~ (2010)
  31. E. Noor, "Temperature effects on the corrosion inhibition of mild steel in acidic solutions by aqueous extract of fenugreek leaves", International Journal of Electrochemical Science, 2, pp.996~ (2007)[DOI]
  32. Guannan Mu, "Synergistic inhibition between tween 60 and NaCl on the corrosion of cold rolled steel in 0.5M sulfuric acid", Corrosion Science, 47(8), pp.1932~1952 (2005), Elsevier BV[DOI]
  33. Sayed S Abd El Rehim, "Corrosion inhibition of aluminum by 1,1(lauryl amido)propyl ammonium chloride in HCl solution", Materials Chemistry and Physics, 70(1), pp.64~72 (2001), Elsevier BV[DOI]
  34. Gamal K. Gomma, "Schiffbases as corrosion inhibitors for aluminium in hydrochloric acid solution", Materials Chemistry and Physics, 39(3), pp.209~213 (1995), Elsevier BV[DOI]
  35. N. Subramanian N, , Indian Journal of Technology, 8, pp.369~ (1970)
  36. S.A. Umoren, "Gum arabic as a potential corrosion inhibitor for aluminium in alkaline medium and its adsorption characteristics", Anti-Corrosion Methods and Materials, 53(5), pp.277~282 (2006), Emerald[DOI]
  37. T. Bataineh, "Sinapis Alba Extract as Green Corrosion Inhibitor for Aluminum in Alkaline Media", International Journal of Electrochemical Science, 9, pp.3543~ (2014)
  38. T. Ibrahim, "Corrosion Inhibition of Mild Steel using Fig Leaves Extract in Hydrochloric Acid Solution", International Journal of Electrochemical Science, 6, pp.6442~ (2011)
  39. A. Ali, "Inhibition of acid Corrosion of Aluminum usingSalvadore persica", Journal of Basic and Environmental Sciences, 1, pp.136~ (2014)
  40. Tareq T. Bataineh, "Corrosion Control of Aluminium Alloy in Alkaline Solution Using Leave Extract of Plumbago Europaea", Jordan Journal of Chemistry, 8(3), pp.169~178 (2013), Yarmouk University[DOI]

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