lectrochemical Study on Rhodamine 6G-Indole Based Dye for HOMO and LUMO Energy Levels
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초록
The energy levels are very important to investigate properties of organic dye materials. These values of energy levels can be calculated and compared with absorption spectra, cyclic voltammetric measurement and computer simulative calculation. In this study, absorption and emission changes were observed by complexation between rhodamine 6G based dye and mercury. This is related to spirolactam ring system of rhodamine 6G based dye. According to structural change of this dye, HOMO and LUMO energy levels were investigated and determined by their values with different approaches.
Abstract
The energy levels are very important to investigate properties of organic dye materials. These values of energy levels can be calculated and compared with absorption spectra, cyclic voltammetric measurement and computer simulative calculation. In this study, absorption and emission changes were observed by complexation between rhodamine 6G based dye and mercury. This is related to spirolactam ring system of rhodamine 6G based dye. According to structural change of this dye, HOMO and LUMO energy levels were investigated and determined by their values with different approaches.
참고문헌 (18)
- M. Beija, "Synthesis and Applications of Rhodamine Derivatives as Fluorescent Probes", Chem. Soc. Rev., 38(8), pp.2410~ (2009)
- X. Chen, "Fluorescent Chemosensors Based on Spiroring ‐Opening of Xanthenes and Related Derivatives", Chem. Rev, 112(3), pp.1910~ (2012)
- (M = Sb or Bi), "Spectrochim. Acta Part A", 2008, 215~
- C. N. Ramachadran, "Host‐Guest Interaction in Endohedral Fullerenes", Chem. Physic. Lett., 461, pp.87~ (2008)
- I. Losito, "OPhenylenediamine Electropolymerization by Cyclic Voltammetry Combined Eectrospray Ioization‐Ion Tap Mass Spectrometry", Anal. Chem, 75(19), pp.4988~ (2003)
- C. J. Tonzola, "New n‐Type Organic Semiconductors: Synthesis, Single Crystal Structures, Cyclic Voltammetry, Photophysics, Electron Transport, and Electroluminescence of Series of Diphenylanthrazolines", J. Am. Chem. Soc, 125(44), pp.13548~ (2003)
- H. Kim, "Design and Synthesis of Novel Chemosensor Based on Rhodamine 6G Monitoring Heavy Metal Ions", Supramol. Chem., 25(2), pp.87~ (2013)
- S. P. Wu, "A Highly Selective Turn‐On Fluorescent Chemosensor for Copper(II) Ion", Tetrahedron, 66(51), pp.9655~ (2010)
- M. Beija, "Synthesis and Applications of Rhodamine Derivatives as Fluorescent Probes", Chem. Soc. Rev., 38(8), pp.2410~ (2009)
- Won Young Kang, "Preparation of Polymeric Metal Complex Containing Azo Dye Rotaxane", 한국염색가공학회지, 23(3), pp.163~168 (2011), 한국염색가공학회
- L. Huang, "A New Rhodamine‐ Based Chemosensor Cu2+ and The Study of Its Behaviour in Living Cells", Dalton Trans., 39(34), pp.7894~ (2010)
- D. Wu, "Highly Sensitive Fluorescent Probe or Selective Detection of Hg2+ in DMF Aqueous Media", Inorg. Chem, 46(5), pp.1538~ (2007)
- H. S. Lee, "Measurement of Phy- -sical Properties of Conducting Polymers", Polymer Sci. Technol, 18, pp.488~ (2007)
- 김영성, "Electrochemical Studies on Heptamethine Cyanine Dyes", 한국염색가공학회지, 21(5), pp.35~40 (2009), 한국염색가공학회
- 김영성, "Characteristics of HOMO and LUMO Potentials by Altering Substituents - Computational and Electrochemical Determination -", 한국염색가공학회지, 20(5), pp.41~46 (2008), 한국염색가공학회
- B. Delley, "An All‐Electron Numerical Method for Solving The Local Density Functional for Polyatomic Molecules", J. Chem. Phys, 92(1), pp.508~ (1990)
- B. Delley, "From Molecules to Solids with the DMol3 Approach", J. Chem. Phys., 113(18), pp.7756~ (2000)
- A. D. Boese, "A New Parametrization of Exchange‐Correlation Generalized Gradient Approximation Functionals", J. Chem. Phys., 114(13), pp.5497~ (2001)