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Chromatographic Separation of Gardenia Yellow for Dye-Sensitized Solar Cells

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초록

An experimental study on the chromatographic separation of gardenia yellow,including genipin, geniposide, geniposidic acid, rutin, crocine, corcetin, and chlorogenicacid, was carried out under linear gradient elution mode. The mobile-phase concentrationhad a significant impact on the single component chromatograms. The retention times ofchromatogram are in the following order: geniposidic acid < chlorogenic acid < geniposide< genipin. From the experimental chromatograms, gradient chromatographic separationwith a changing mobile phase as a function of time was required to obtain high-puritygardenia yellow and reduce the elution time.

Abstract

An experimental study on the chromatographic separation of gardenia yellow,including genipin, geniposide, geniposidic acid, rutin, crocine, corcetin, and chlorogenicacid, was carried out under linear gradient elution mode. The mobile-phase concentrationhad a significant impact on the single component chromatograms. The retention times ofchromatogram are in the following order: geniposidic acid < chlorogenic acid < geniposide< genipin. From the experimental chromatograms, gradient chromatographic separationwith a changing mobile phase as a function of time was required to obtain high-puritygardenia yellow and reduce the elution time.

참고문헌 (7)

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  2. Ito S, "Fabrication of dye-sensitized solar cells using natural dye for food pigment: Monascus yellow", Energy & Environ, 3, pp.905~909 (2010)
  3. Senthil TS, "Natural dye (cyanidin 3-O-glucoside) sensitized nanocrystalline TiO2 solar cell fabricated using liquid electrolyte", quasi-solid-state polymer electrolyte, 2011, pp.36, 2484~2488
  4. Chang H, "Dye-sensitized solar cell using natural dyes extracted from spinach and ipomoea, J", Alloys Compd, 495, pp.606~610 (2010)
  5. Jing L, "Development of adsorptive (non-ionic macroporous resins and their used in the purification of pharmacologically-active natural products from plant sources", Nat. Prod, 27, pp.1493~1510 (2010)
  6. Chen JF, "Enrichment and purification of gardenia yellow from Gardenia jasminides var. racicans Makino by column chromatography technique", J. Chromatography B, 43(48), pp.893~894 (2012)
  7. Zhang M, "Cost-efficient and process-efficient separation of geniposide from Gardenia jasminoides Ellis by high-performance counter-current chromatography", Purif. Tech, 89, pp.193~198 (2012)

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