대나무-면 복합직물의 양이온화에 관한 연구
A Study of the Cationization of Bamboo-cotton Blended Fabric
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Cellulose fiber is a material used in various fields. It is the most used type of fiber because of its excellent hygroscopicity and dyeability. Recently, as natural fiber materials have been highlighted due to the influence of eco-friend-liness and well-being, bamboo fiber has become a commonly used eco-friendly fiber. Cellulose fibers are part of the -OH hydroxyl group, which means they are more chemically reactive than synthetic fibers. In this study, the cationization prop-erties of bamboo-cotton blended fabrics cationized using CHPTAC (3-chloro-2-hydroxypropyl trimethyl ammonium chlo-ride) in the PDC (padding-drying-curing) method were investigated. Various characteristics according to cationizationwere studied through elemental analysis, FT-IR (fourier-transform infrared spectroscopy) analysis, X-ray diffraction anal-ysis, TGA (thermogravimetric) analysis, and SEM (scanning electron microscope) analysis. The nitrogen content of thecationized bamboo-cotton blended fabric increased with an increase in the concentration of the cationizing agent CHPTAC,and it was seen to be highly bound to cellulose molecules. As a result of the FT-IR analysis, both 100% pure cotton fabricsand CHPTAC-0 and CHPTAC-150 fabrics were seen to be typical cellulose. As a result of the X-ray diffraction analysis,both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As a resultof the X-ray diffraction analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As the cationization progressed, micropores appeared on the surface of the blended fabric.
Abstract
Cellulose fiber is a material used in various fields. It is the most used type of fiber because of its excellent hygroscopicity and dyeability. Recently, as natural fiber materials have been highlighted due to the influence of eco-friend-liness and well-being, bamboo fiber has become a commonly used eco-friendly fiber. Cellulose fibers are part of the -OH hydroxyl group, which means they are more chemically reactive than synthetic fibers. In this study, the cationization prop-erties of bamboo-cotton blended fabrics cationized using CHPTAC (3-chloro-2-hydroxypropyl trimethyl ammonium chlo-ride) in the PDC (padding-drying-curing) method were investigated. Various characteristics according to cationizationwere studied through elemental analysis, FT-IR (fourier-transform infrared spectroscopy) analysis, X-ray diffraction anal-ysis, TGA (thermogravimetric) analysis, and SEM (scanning electron microscope) analysis. The nitrogen content of thecationized bamboo-cotton blended fabric increased with an increase in the concentration of the cationizing agent CHPTAC,and it was seen to be highly bound to cellulose molecules. As a result of the FT-IR analysis, both 100% pure cotton fabricsand CHPTAC-0 and CHPTAC-150 fabrics were seen to be typical cellulose. As a result of the X-ray diffraction analysis,both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As a resultof the X-ray diffraction analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As the cationization progressed, micropores appeared on the surface of the blended fabric.
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