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College Students' Misconception about the Volume Change of Solution during Acid/Base Titration: Partial Molar Volume of Salt

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초록

I investigated Korean college students’ conception about the volume change of solution when they detected the equivalence point during acid/base titration experiment using method of volume measurement. According to this study, most college students had a misconception that the volume increment was due to the formation of water by neutralization during acid/base titration. However, this is not enough to explain the volume change, neglecting contribution of a salt in solution. I calculated the partial molar volume of NaCl formed to explain the volume increment of solution during HCl/NaOH neutralization. Comparing the result of experiment with the calculation of partial molar volume, I elucidated that the main effect of volume increment was due to the partial molar volume of NaCl formed during HCl/NaOH neutralization. Here I propose to introduce college students to the concept of partial molar volume of the salt formed to reduce misconception about the volume change of solution during acid/base neutralization.

Abstract

I investigated Korean college students’ conception about the volume change of solution when they detected the equivalence point during acid/base titration experiment using method of volume measurement. According to this study, most college students had a misconception that the volume increment was due to the formation of water by neutralization during acid/base titration. However, this is not enough to explain the volume change, neglecting contribution of a salt in solution. I calculated the partial molar volume of NaCl formed to explain the volume increment of solution during HCl/NaOH neutralization. Comparing the result of experiment with the calculation of partial molar volume, I elucidated that the main effect of volume increment was due to the partial molar volume of NaCl formed during HCl/NaOH neutralization. Here I propose to introduce college students to the concept of partial molar volume of the salt formed to reduce misconception about the volume change of solution during acid/base neutralization.

참고문헌 (9)

  1. Atkins, P, "Physical chemistry. 7th ed", Oxford University, 182~184 (2002)
  2. Barnum, D. W, "Predicting acid-base titration curves without calculations", Journal of Chemical Education, 76(7), pp.938~941 (1999)
  3. Bromberg, J. P, "Physical chemistry. 2nd ed", pp.232~235 (1984), Allyn and Bacon
  4. Charlesworth, P., "Comparing the titrations of mixed-acid solutions using dropwise and constant-flow techniques", Journal of Chemical Education, 80(11), pp.1311~1313 (2003)
  5. Harris, D. C, "Exploring chemical analysis. 2nd ed", pp.205~211 (2001), W. H. Freeman
  6. Klotz, I. M, "Chemical thermodynamics", pp.193~194 (1950), Prentice-Hall
  7. Lewis, G. N, "Thermodynamics. 2nd ed", pp.205~206 (1961), McGraw-Hill
  8. Loucks, L. F, "Regression methods to extract partial molar volume values in the method of intercepts", Journal of Chemical Education, 76(3), pp.425~427 (1999)
  9. Lunelli, B, "Rapid microdetermination of partial molar and excess molar volumes", Journal of Chemical Education, 79(5), pp.626~628 (2002)

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