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Production and characterization of Al2O3-Cu composite materials

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Using an intense powder mixture of Al2O3 with different copper contents (1, 5, 10, 20 or 30 mass %) several Al2O3-Cu composite materials were fabricated. The microstructure of the composites was observed by optical and scanning electron microscopy. The observations show a microstructure formed by an Al2O3 ceramic matrix with fine Cu metallic networks. Due to the liquid sintering mechanism, the relative density reached by the samples was higher than 95%, this together with the fine and homogeneous microstructure present in the samples let us obtain composite materials with good values of toughness, hardness, elastic modulus and electrical properties. The incorporation of a ductile metal inside a hard ceramic matrix increments its toughness. The probable toughening mechanism is crack bridging due to the presence of a homogeneous ductile metal networks in the material’s microstructure. The values of density, hardness, elastic modulus and electrical resistance of the composites are directly dependent on the copper content in the matrix, because with an increase in copper content the density of the composites is larger, whereas, the hardness, elastic modulus and electrical resistance are reduced.

Abstract

Using an intense powder mixture of Al2O3 with different copper contents (1, 5, 10, 20 or 30 mass %) several Al2O3-Cu composite materials were fabricated. The microstructure of the composites was observed by optical and scanning electron microscopy. The observations show a microstructure formed by an Al2O3 ceramic matrix with fine Cu metallic networks. Due to the liquid sintering mechanism, the relative density reached by the samples was higher than 95%, this together with the fine and homogeneous microstructure present in the samples let us obtain composite materials with good values of toughness, hardness, elastic modulus and electrical properties. The incorporation of a ductile metal inside a hard ceramic matrix increments its toughness. The probable toughening mechanism is crack bridging due to the presence of a homogeneous ductile metal networks in the material’s microstructure. The values of density, hardness, elastic modulus and electrical resistance of the composites are directly dependent on the copper content in the matrix, because with an increase in copper content the density of the composites is larger, whereas, the hardness, elastic modulus and electrical resistance are reduced.

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