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Self assembly directed synthesis of tubular conduction polymer inside th channels of MCM-41

Anantha Iyengar Gopalan|Sang-Ho Kim|최성호|Ali Md Showkat|Kwang-Pill Lee|K Raghava Reddy
한국분석과학회|2006.06|분석과학 (Analytical Science & Technology)|제19권 제3호|pp. 211-217

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참고문헌

키워드

self-assemblyMesoporous silica (MCM-41)poly (diphenylamine)
주제분류화학

초록

Diphenyl amine (DPA) was polymerized inside the channels of the mesoporous silica (MCM-41). MCM-41 (C) and MCM-41 (D) were prepared with cetyltrimethyl ammonium bromide (CTAB) and dodecyltrimethyl ammonium bromide (DTAB), respectively and used as hosts. Initially, the self assembly of DPA inside the pores of MCM-41 was made in β-naphthalene sulfonic acid (NSA) medium and subsequently poly (diphenylamine), PDPA was formed by oxidative polymerization. N2 adsorption-desorption measurements of PDPA loaded MCM-41 (C) and MCM-41 (D) show variations in pore volume and surface area between them. A tubular form of poly (diphenylamine), PDPA was envisaged to form in the pores of MCM-41 and supported by high resolution transmission microscopy. The presence of PDPA inside the channel of MCM-41 was further confirmed by FTIR spectroscopy, thermogravimetric analysis (TGA), X-ray diffraction.

Abstract

Diphenyl amine (DPA) was polymerized inside the channels of the mesoporous silica (MCM-41). MCM-41 (C) and MCM-41 (D) were prepared with cetyltrimethyl ammonium bromide (CTAB) and dodecyltrimethyl ammonium bromide (DTAB), respectively and used as hosts. Initially, the self assembly of DPA inside the pores of MCM-41 was made in β-naphthalene sulfonic acid (NSA) medium and subsequently poly (diphenylamine), PDPA was formed by oxidative polymerization. N2 adsorption-desorption measurements of PDPA loaded MCM-41 (C) and MCM-41 (D) show variations in pore volume and surface area between them. A tubular form of poly (diphenylamine), PDPA was envisaged to form in the pores of MCM-41 and supported by high resolution transmission microscopy. The presence of PDPA inside the channel of MCM-41 was further confirmed by FTIR spectroscopy, thermogravimetric analysis (TGA), X-ray diffraction.

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